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NUMERICAL SIMULATION OF ROUND TO OVAL ROLLING PROCESS

Y. W. Wang , Y. L. King , D. H. Yuan , S. G. Liu and Z. Y. Yu 1 ) University of Science and Technology Beijing , Beijing 100083 , China 2) Daye Special Steel Co. , Huangshi 435001 , China

金属学报(英文版)

Three dimensional thermal-mechanical coupled elasto-plastic FEM has been used for simulation of round to oval single pass rolling. The analysis was conducted using MARC/AUTOFORCE1. 2 code. The material is assumed to be elasto-plastic and it obey the Von Mises yield criterion and Prandtl- Reuss rule. Deformation of the workpiece is simulated in a step-by-step manner,updating the coordinates of material points and the property after each step, so that both nonsteady-state and stendy-state deformation can be simulated. The heat transfter between the workpiece, the rolls, and enviroment and the heat generation due to plastic work and friction force, are considered in the analys- is.Predicted the deformation shape of the workpiece, distributions of strains, stresses, strain rates and temperatures, roll-separating force and roll torque are presented.

关键词: bar rolling , null , null , null

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

Studies of the changes of Mn-Y (Y = S, Se, Te) bond lengths R with the Mn composition x in Zn1-xMnxY alloys from optical spectrum data

Journal of Physics and Chemistry of Solids

The changes of Mn-Y (Y = S, Se, Te) bond lengths R with the Mn composition x in the diluted magnetic semiconductors Zn1-xMnxY are calculated from the optical spectra and their pressure shifts. The calculated results suggest that the Mn-Y bond lengths change little with the Mn composition x-much less than expected from lattice parameters as determined by X-ray diffraction. These results are also in good agreement with the observed values obtained from the EXAFS measurements. It appears that for ternary A(1-x)M(x)Y (M denotes the divalent transition-metal ion) alloys the changes of M-Y bond lengths R with the M composition x can be studied from their optical spectrum data. (C) 2000 Elsevier Science Ltd. All rights reserved.

关键词: semiconductors;high pressure;crystal fields;luminescence;light;properties;absorption fine-structure;local-structure;dependence;pressure;exafs

Subsolidus phase relation and crystal structure in the Pr(1+x-y)Ba(2-x-z)Ca(y+z)Cu(3)O(7 +/-delta) system

Applied Physics a-Materials Science & Processing

The Pr(1+x)Ba(2-x)Cu(3)O(7+/-delta) solid solution was investigated by means of X-ray powder diffraction combined with Rietveld analysis. A Pr123 single phase could be synthesized under Pr-rich conditions by sintering at 950 degreesC in air. The solubility range of Pr(1+x)Ba(2-x)Cu(3)O(7+/-delta) solid solution is 0.08 less than or equal to x less than or equal to 0.80. The structure of Pr(1+x)Ba(2-x)Cu(3)O(7+/-delta) for 0.08 less than or equal to x less than or equal to 0.30 is orthorhombic. The structure transforms into tetragonal for 0.30 less than or equal to x less than or equal to 0.80. To form the Pr123 single phase, the Ba sites in the Pr123 structure must have partial Pr ions, and the least amount is x = 0.08. Ba ions cannot occupy the sites of Pr ions. In the Pr123 structure, Ca ions can replace Pr ions; the highest value is x = 0.4 in the PrBa(2-x)Ca(x)Cu(3)O(7+/-delta) system under our experimental conditions. However, Ca ions cannot replace B a ions. The ionic radius plays a more important role than the chemical properties in the substitution between Pr, Ba and Ca ions in the Pr123 structure.

关键词: cu-o system;approximately 950-degrees-c;superconductivity;diagram;pr;growth;nd;prba2cu3o7-delta;praseodymium;property

SOFC阴极材料(La_(0.85)Sr_(0.15))_y(Mn_(1-z)Cr_z)O_3的物理性能和化学稳定性

杨威 , 隋智通

材料研究学报

采用烧结法制备阴极材料(La0.85Sr0.15)y(Mn1z-Crz)O3(y=0.85;1;z=0.1,0.2).研究了多孔锰酸镧与致密ZrO2(8mol%Y2O3)界面的成分变化和显微形貌(La0.85Sr0.15)(Mn0.9Cr0.1)O3呈现高电子电导率、良好的热膨胀系数匹配和化学稳定性而(La0.85Sr0.15)MnO3未起到阻止界面退化的作用在1300~1500℃范围内Mn、La、Zr和Sr发生扩散,其中Mn的扩散明显

关键词: SOFC , lathanum manganite. chemical stability , thermal expansion , conductivity , null

Calculation of EPR parameters g factors for Ce3+ ion in YBa2Cu3O6+x superconductor

International Journal of Modern Physics B

The perturbation formulae of EPR parameters g factors g(x), g(y) and g(z) for the lowest Kramers doublet of 4f(1) ion in orthorhombic symmetry are established. In these formulae, the contributions of the covalency effects, the admixture between J = 7/2 and J = 5/2 states as well as the second-order perturbation (which is not considered in the previous works) via crystal-field and orbital angular momentum interactions are all included. According to these formulae, and by using the superposition model, the g-factors g., g(y) and g(z) for Ce3+ center in YBa2CU3O6+x superconductor are calculated. The results are discussed.

关键词: YBa2Cu3O6+x;EPR;superposition model;Ce3+;crystal-field

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