Chinese Physics Letters
The quantitative analysis of zinc isopropyl-isooctyl-dithiophosphate (T204) mixed with lube base oil from Korea with viscosity index 70 (T204-Korea70) is presented by using terahertz time-domain spectroscopy (THz-TDS). Compared with the middle-infrared spectra of zinc n-butyl-isooctyl-dithiophosphate (T202) and T204, THz spectra of T202 and T204 show the weak broad absorption bands. Then, the absorption coefficients of the T204-Korea70 system follow Beer's law at the concentration from 0.124 to 4.024%. The experimental absorption spectra of T204-Korea70 agree with the calculated ones based on the standard absorption coefficients of T204 and Korea70. The quantitative analysis enables a strategy to monitor the formulation of lubricating oil in real time.
关键词:
infrared-spectroscopy;dielectric-properties;zddp;water
詹茂盛
,
方义
,
王瑛
,
范荣峥
航空材料学报
doi:10.3969/j.issn.1005-5053.2000.04.010
在40℃和80℃环境中,分别对Bayer-PC、Japan-PC、Korea-PC三种聚碳酸酯缺口冲击试样进行了热空气老化和热水老化实验研究.在0~400h老化时间内,研究了这三种PC的热空气老化和热水老化对冲击强度和断面形貌的影响,讨论了PC热空气老化和热水老化机理.结果表明:老化前,Japan-PC、Korea-PC和Bayer-PC冲击强度分别为95kJ/m2、83 kJ/m2和55 kJ/m2;在40℃和80℃热空气老化后,三种PC冲击强度均有所下降,其中80℃热空气老化引起的降幅最大,热空气老化400h后的冲击强度顺序为Japan-PC>Korea-PC>Bayer-PC,在40℃热水老化后,三种PC的冲击强度几乎不受老化时间影响;在80℃热水老化后,三种PC冲击强度均有所下降,其中Bayer-PC降幅最小,Japan-PC次之,Korea-PC最大,但PC的平衡冲击强度大小与热空气老化的情况相同.由扫描电镜对冲击断面形貌观察可知,未老化的三种PC均以剪切屈服破坏机理为主,老化后的三种PC主要以银纹集中破坏机理为主.
关键词:
聚碳酸酯
,
热空气老化
,
热水老化
,
破坏形貌