Dongxiu YU
,
Jiang CHENG
材料科学技术（英文）
Combined nitric acid oxidation method and polyaniline (PANI)-coated method were applied to modify the surface properties of short carbon fibers (SCF). The electrical and mechanical properties of acrylic coatings with 50 wt pct PANI-coated carbon fiber were investigated by using scanning electron microscope (SEM), UVVis spectrophotometer, four-probe method and the coaxial cable method. The results of the pH measurement and XPS (X-ray photoelectron spectroscopy) patterns showed that the oxygen functional groups, such as -OH and -COOH, were attached on the carbon fiber surfaces after oxidation treatment. The XPS analysis of PANI-coated oxidized SCF (PAOSCF) revealed that PANI may bond on the surface of oxidized SCF with chemical bonds. SEM images and surface roughness analyses showed that PANI-coated layer changed the surface morphology. Compared with SCF/acrylic coating, the surface resistivity of PAOSCF/acrylic coating decreased from17.1 to 5.3 Ω/sq and the shielding efficiency (SE) value increased from 1.54 to 23.3 dB.
关键词:
carbon fibers
,
聚苯胺
,
表面处理
,
分散稳定性
,
屏蔽效
Ailan QU
,
Xiufang WEN
,
Pihui PI
,
Jiang CHENG
,
Zhuoru YANG
材料科学技术（英文）
Fluoropolymer and different kinds of silica particles were used for controlling surface chemistry and morphology, respectively. A superhydrophobic surface originated from strawberry-like or quincunx-shaped composite silica particles was obtained. The dual size particles are obtained by utilizing the graft of different modified silica particles with epoxy functional group and amine functional group. This makes the surface of film form a composite interface to have irregular binary structure which plays an essential role in trapping air between the substrate surface and the liquid droplets to be necessary for high contact angle and low contact angle hysteresis. The maximum contact angle for water on the hybrid film is about 174±2° and the contact angle hysteresis is less than 2°. The surface morphologies, roughness and the wettability on the surface of films containing different structural silica particles were compared. It was shown that the hierarchical irregularly structure with a low roughness factor and high air-trapped ratio is indispensable for superhydrophobic surface. Although this structural surfaces based on composite silica particles play a vital role in governing the surface wettability, it is necessary to combine with a low surface energy to make the surface superhydrophobic.
关键词:
Superhydrophobicity
,
双微观结构
,
纳米复合粒子
,
含氟硅
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
程开甲
,
程漱玉
稀有金属材料与工程
应用Cheng-Born能带对称破缺理论和TFDC(Thomas-Fermi-Dirac-Cheng)电子理论研究了薄膜层内电子的特性.对金属铂上的TiO2膜层来说,TFDC理论指出电子(或空穴)将由金属与膜的间界面一侧迁移到另一侧.根据Cheng-Born对称破缺理论,当能带中只有很少的电子时,则只有极少的角区中存在电子,动量空间即产生对称破缺,从而导致超导电性,并由热力学估算出薄膜超导体的转变温度.结果显示薄膜超导体的转变温度至少比块材超导体的转变温度高一个量级.作者还设计了一个研究薄膜超导电性的实验.
关键词:
超导电性
,
薄膜
,
对称破缺
,
TFDC
李翔宇
,
赵霄龙
,
郭向勇
,
曹力强
材料导报
在Cheng-Vachon模型的基础上提出了一种针对由连续相和分散相组成的两相复合材料的新导热系数模型.通过引入一个新的参数,即分散相的修正体积含量来改进Cheng-Vachon模型不适用于分散相体积含量较大的缺点.使用新的导热系数模型预测泡沫混凝土的导热系数,与实验结果的对比表明,新的模型可以准确预测泡沫混凝土的导热系数.
关键词:
泡沫混凝土
,
复合材料
,
导热系数
,
无机材料
倪永中
,
徐鸿
材料科学与工程学报
本文提出了一种基于粒子群算法和有限元方法的弹塑性本构方程参数的确定方法,并在此基础上开发了参数自动优化系统CMPI(Constitutive Material Parameter Identification).通过使最小二乘形式的目标函数达到极小值,实现参数的动态寻优;模型参数作为粒子群优化模块的输入,采用应变(应力)控制方法,调用材料非线性有限元模块计算特定参数时的应力(应变)响应,并计算与实验数据的误差,从而实现优化过程.CMPI目前适用于A-F类模型(Chaboehe、Ohno-Wang、Jiang-Sehitoglu)的参数优化,以此为基础,不难扩展到其他材料模型.
关键词:
粒子群
,
材料非线性
,
有限元
,
Ohno-Wang 模型
王姗姗
,
祝要民
,
任凤章
,
赵士阳
,
田保红
材料科学与工程学报
直流电沉积法在Fe基体上制备Ni膜和在Cu基体上制备Ag膜,利用悬臂梁法在线测量了膜中的平均应力,并计算了膜内分布应力,且对膜内平均应力的实验结果与Thomas-Feimi-Dirac-Cheng(TFDC)电子模型理论估算结果进行了对比.结果表明,Fe基体上Ni膜的平均应力和分布应力均为拉应力,而Cu基体上Ag膜的平均应力和分布应力均为压应力.两种膜的内应力均由界面应力引起.对于相同的基体和镀膜,膜内平均内应力的理论估算值与实验值较接近.
关键词:
薄膜
,
内应力
,
悬臂梁法
,
电子理论
