X.K. Tao
,
X.Cong
,
R.S. Peng
,
J.Liu and Z.Y. Liu Tianjin Institute of Technology
,
Tianjin 300191
,
China
金属学报(英文版)
This paper investigates the effect of rare earth elements on the kinetic process, microstructure and mechanical properties of vanadization in borax bath. The results show that addition of rare earth elements to vanadizing agent has obvious catalytic effect on the rate of vanadization, which has been enchanced by 30%. The wear and corrosion resistance of vanadium carbide layer were prompted by the addition of rare earth to the agent. Through increasing vanadium potential of the agent, activating the surface of workpieces and decreasing the activation energy of diffusion of carbon, rare earth elements accelerate the rate of vanadization process.
关键词:
rare earth elements
,
null
,
null
何恩全
,
马文会
,
刘荣辉
,
于洁
,
戴永年
稀有金属
doi:10.3969/j.issn.0258-7076.2007.04.019
采用了甘氨酸-硝酸盐法制备了La0.7Sr0.3Cr0.5-yMn0.5-zCo(y+z)O3(y, z=0.1, 0.2)系列阳极材料.借助XRD, SEM对所制备的材料进行了物相和形貌分析.XRD表明利用GNP法制得的粉体在1350 ℃烧结5 h可以形成完整的钙钛矿相;SEM分析可知所得物料颗粒呈球状,尺寸约为1 μm,且没有团聚现象.同时,XRD显示La0.7Sr0.3Cr0.5Mn0.4Co0.1O3和La0.9Sr0.1Ga0.8Mg0.2O3电解质之间具有较好的化学相容性.采用直流四探针法测试了不同组成材料在250～800 ℃温度范围内在空气中的电导率,发现该系列材料在该温度段范围符合小极化子导电机制.另外,利用直流四探针法测试了La0.7Sr0.3Cr0.5Mn0.4Co0.1O3在不同还原气氛下的电导率,在CH4和H2气氛中,La0.7Sr0.3Cr0.5Mn0.4Co0.1O3最大电导率分别达到了4.5和0.42 S·cm-1.
关键词:
钙钛矿
,
阳极
,
电导率
黄曼青
,
周全
,
刘峰
,
黄金角
材料导报
doi:10.11896/j.issn.1005-023X.2016.22.010
研究了0~1.4 T的直流磁场对陶瓷型铸造 Mg-Y-Cu-Zr 合金结晶取向和力学性能的影响。结果表明直流磁场对合金的初生相没有明显影响，但磁场强度大于1.12 T时，合金第二相的分布变得不连续。当磁场强度小于0.84 T时，α-Mg在(002)面的衍射峰逐渐增强，但变化不明显；当磁场强度大于0.84 T 时，α-Mg 基体在(002)、(101)面的衍射峰强度明显减弱，而在(100)晶面衍射峰强度有所增强。磁场处理后，合金的综合力学性能得到了改善；当磁场强度为1.4 T 时，其抗拉强度和伸长率最高，分别为237 MPa 和8.5%，较无磁场处理时分别提高了38.6%和33.4%。
关键词:
直流磁场
,
Mg-Y-Cu-Zr合金
,
结晶取向
,
力学性能
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
D.Eylon
,
S.R.Seagle
材料科学技术（英文）
The state of Ti research, development and industry is reviewed in this article. The fifty-year anniversary of Ti technology commercialization in the USA provides an opportunity for a historical perspective. Incorporation of "information-age" tools into alloy development, processing, and production invigorates the technology. Consolidation, diversification and globalization have been transforming the Ti industry in the recent years.
关键词:
Y.G. Cao
,
X.Y. Sun
金属学报(英文版)
J-integral and crack opening displacement δ(COD) were important parameters for characterization of fractures in engineering materials. The relationship between J-integral and COD has been investigated for a long time and was enerally represented as J = m σyδ, where σy is the yield strength and m is a function of specimen geometry and material properties. To determine the value of m, extensive studies and experiments have been performed. The method that used the fracture-surface topography analysis (FRASTA) for determining J-integral from fracture surfaces of materials was introduced. On the basis of the relationship between COD and fracture surface average profile, the relationship between J-integral and COD was deduced and compared with the generally used equation. The method was experimentally confirmed to be able to provide a new way to determine the relationship between J-integral and COD.
关键词:
FRASTA
,
null
,
null
Journal of Applied Physics
The four optical spectrum bands (or d-d transitions) and six spin Hamiltonian parameters (g factors g(x), g(y), g(z) and hyperfine structure constants A(x), A(y), A(z)) of the rhombic Zr3+ (4d(1)) center in Y3Al5O12 crystal are calculated from the complete diagonalization (of energy matrix) method and the perturbation theory method. The calculated results from both methods are not only close to each other but also in good agreement with the experimental values. It appears that the two microscopic theory methods (which are very close to those used in a 3d(1) system) are effective in the explanations of the optical and electron paramagnetic resonance spectra for a 4d(1) system. From the calculations, the optical spectrum bands are reassigned and the defect structure of the rhombic Zr3+ center in Y3Al5O12 crystal is estimated. (c) 2007 American Institute of Physics.
关键词:
electron-paramagnetic-res;crystal fields;epr;ions;linewidth
