材料期刊网

Effect of Si3N4 Addition on the Mechanical Properties, Microstruc-tures, and Wear Resistance of Ti-6Al-4V Alloy

Ruihua HU , Montasser M.Dewidar , Hyo-Jin KIM , Jae-Kyoo LIM , null

材料科学技术（英文）

In order to improve the wear resistance of Ti-6Al-4V, different amounts of Si3N4 powder were added into the alloy powder and sintered at 1250℃. Porous titanium alloy with higher wear resistance was successfully fabricated. At sintering temperature, reaction took place and a new hard phase of Ti5Si3 formed. The mechanical properties of the fabricated alloys with different amounts of Si3N4 addition were investigated. The hardness of Ti-6Al-4V, which is the index of wear resistance, was increased by the addition of Si3N4. Amounts of Si3N4 addition have very significant influences on hardness and compressive strength. In present study, titanium alloy with 5 wt pct Si3N4 addition has 62% microhardness and 45% overall bulk hardness increase, respectively. In contrast, it has a 16.4% strength reduction. Wear resistance was evaluated by the weight loss during wear test. A new phase of Ti5Si3 was detected by electron probe microanalyzer (EPMA) and X-ray diffraction (XRD) method. The original Si3N4 decomposed during sintering and transformed into titanium silicide. Porous structure was achieved due to the sintering reaction.

关键词: Ti-6Al-4V , alloy , Wear , Sintering , reaction

EFFECTIVE-MEDIUM THEORY OF PIEZOELECTRIC COMPOSITES

Journal of Applied Physics

Based on the developed multiple-scattering theory [C.-W. Nan and F. S. Jin, Phys. Rev. B 48, 8578 (1993)], an effective-medium theory (EMT) is proposed to treat coupled electromechanical behavior in composite media. The explicit relations for determining effective behavior of piezoelectric composites are derived. To illustrate the technique, numerical results of piezoelectric ceramic/epoxy composites for various particle shapes are presented over the whole range of concentrations. The EMT estimates are shown to be in good agreement with available experimental results. Porous piezoelectric ceramics are also discussed. The EMT predicts a similar critical behavior for heterogeneous piezoelectric materials to recent experiments.

关键词: electromechanical properties;ceramics

MgB2超导块材的非线性磁弛豫性质的研究

李光临 , 宋炜 , 孟立飞 , 冯庆荣 , 高政祥 , 张西祥 , 温戈辉 , 郑荣坤

低温物理学报 doi:10.3969/j.issn.1000-3258.2001.04.014

在32～34K温度和0.5T初始磁场中,MgB2超导块材的磁弛豫性质通过剩余磁化强度M随时间t的变化进行了研究.在初始阶段,M～lnt明显偏离线性,磁通运动接近Zeldov对数模型.足够长的时间后,M～lnt呈现很好的线性,磁通运动符合Anderson-Kim模型.

关键词:

矢量磁位法求解轴对称超导悬浮系统的电流分布

郭仁春 , 王金星

低温物理学报 doi:10.3969/j.issn.1000-3258.2008.01.012

矢量磁位是电磁涡流场常用的分析方法.本文利用矢量电位法建立了NdFeB永磁铁和超导体相互作用的电磁场数学方程.对在求解过程中采用Kim模型,通过伽辽金有限元离散,形成线性方程组,解出超导体电流密度分布.这些分析结果为改进超导悬浮系统提供了理论依据.

关键词: YBCO超导体 , 永磁铁 , 矢量磁位 , 有限元

熔融织构YBCO块材磁通动力学参量的磁光图像研究(Ⅱ)

罗康 , 刘蕴宏 , 谢旭 , 罗志全 , 高政祥 , 肖玲 , 任洪涛 , 焦玉磊 , 郑明辉

低温物理学报 doi:10.3969/j.issn.1000-3258.2000.05.004

由熔融织构YBCO块材表面剩余磁感应强度的磁光图像,推算出局域有效激活能U和电流密度j,进而研究磁通运动的局域效应.在样品的边缘区域,U(j)符合Zeldov对数模型,在样品中心区域,U(j)应该符合Anderson-Kim线性模型.在涡旋线向样品中心运动的前沿区域,可以观察到电流密度随时间先升后降.

关键词:

Interactions between non-screw lattice dislocations and coherent twin boundaries in face-centered cubic metals

Acta Materialia

In a first report [Jin ZH.. Gumbsch P, Ma E, Albe K, Lu K, Hahn H, et al. Scripta Mater 2006;54:1163], interactions between screw dislocation and coherent twin boundary (CTB) were studied via molecular dynamics simulations for three face-centered cubic (fcc) metals, Cu, Ni and Al. To complement those preliminary results, purely stress-driven interactions between 60 degrees non-screw lattice dislocation and CTB are considered in this paper. Depending on the material and the applied strain, slip has been observed to interact with the boundary in different ways. If a 60 degrees dislocation is forced by an external stress into a CTB, it dissociates into different partial dislocations gliding into the twin as well as along the twin boundary. A sessile dislocation lock may be generated at the CTB if the transited slip is incomplete. The details of the interaction are controlled by the material-dependent energy barriers for the formation of Shockley partial dislocations from the site where the lattice dislocation impinges upon the boundary. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: dislocation;slip;twinning;twin grain boundary;molecular dynamics;molecular-dynamics simulation;grain-boundaries;nanocrystalline;materials;cross-slip;rate sensitivity;deformation;copper;strength;aluminum;fcc

Liquid-vapour critical point behaviour: especially crossover from two to three dimensions via a magnetic analogy

Physics and Chemistry of Liquids

Motivation for this Letter comes from two experiments. The first, by Kim and Chan (Phys. Rev. Lett. 53, 170 (1984)), measured a two-dimensional (2D) liquid-vapour critical point exponent. The second studied, via the magnetism of ultrathin metal films, the crossover of the critical exponent beta from 2D to 3D. Here, the analogy between magnetic behaviour near criticality and the corresponding liquid-vapour behaviour is first used to discuss the 2D-3D crossover in the latter case. Finally, the experimentally observed magnetic behaviour near criticality is considered for the ferromagnet CrBr(3) to allow fingerprints of the 3D Ising Hamiltonian to be anticipated.

关键词: critical-point effects;critical exponents;crossover;Ising model;criticality;magnetic equation of state;critical exponents;ising-model;equation;crbr3;state

乙烯基笼型倍半硅氧烷/聚丙烯纳米复合材料热降解动力学

曹新鑫 , 高俊刚 , 杜永刚

高分子材料科学与工程

用热重分析(TGA)法研究了乙烯基笼型倍半硅氧烷(V-POSS)/聚丙烯纳米复合材料的热降解动力学.采用Kim-Park,Flynn-Wall-Ozswa和Friedman三种方法计算了共混物的降解反应活化能,结果说明,当V-POSS加入质量分数分别为4%、8%、12%和16%、升温速率为5℃/min时材料热降解起始温度分别提高了27.1℃、29.3℃、52.6℃和66.9℃,热降解反应活化能Ea提高了10 kJ/mol～50kJ/mol,反应级数n也随V-POSS加入量增多有所提高,材料热稳定性得到了改善.

关键词: 笼型聚倍半硅氧烷 , 聚丙烯 , 热重分析 , 降解动力学

垂直磁场中YBCO薄膜的磁通密度和电流密度分布

李志敏 , 覃孟军 , 姚希贤

低温物理学报 doi:10.3969/j.issn.1000-3258.1999.06.001

通过使用扩展后的Mikheenko等人提出的临界态模型，我们用数值计算方法找出了圆盘状超导薄膜在垂直外磁场中的磁通密度分布和电流密度分布.其中考虑到临界电流密度Jc会随外磁场Ha改变而变化，所以我们采用了Kim型表达式Jc(H)=J0/(1+(|H|/H0)n).计算出的初始磁化曲线和磁滞回线与YBCO薄膜的实验曲线（T=51～77K）符合得很好，说明这个方法在这段温区内比较成功.另外我们也得出并讨论了特征参数J0，H0随温度的变化关系.

关键词:

YBCO薄膜中自旋极化准粒子的注入效应

曹春海 , 杨名 , 张世远 , 杨森祖 , 崔旭高 , 尤立星 , 吉争鸣 , 康琳 , 许伟伟

低温物理学报 doi:10.3969/j.issn.1000-3258.2003.03.002

采用Nd0.7Sr0.3MnO3/SrTiO3/YBa2Cu3O7-δ的异质结构,研究了自旋极化准粒子的注入效应.在56μm宽的YBCO膜条上成功地制备了与超导膜条同样宽度但不同长度的六个注入结区,长度L分别为80μm, 40μm, 20μm, 10μm, 5μm和2μm.80nm厚的YBCO薄膜在16K温度下Jc为2×105A/cm2.Iin=0.5mA的自旋电流注入下,随L从80μm逐渐顺次减小时,注入效率η=ΔJc/ΔJin逐渐增大.而当L≤20μm后,η不再增加,达到几乎相同的值(～6).初步分析认为这与自旋极化准粒子在超导膜内的有效自旋扩散长度有关.异质结构中YBCO薄膜的超导电性以及注入窗口的尺寸对获得大的自旋注入效率十分重要.

关键词: 注入效率 , 自旋准粒子 , 巨磁阻 , 异质材料