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Research Of The Feeding Speed Adopting Cored-Wire Method To Spheroidize Ductile Iron Melt

G.W. Chang , H.X. Wang , X.D.Yue , H.L. Zhang

金属学报(英文版)

For settling the question of feeding speed in applying the cored-wire method to spheroidize ductile iron melt, ANSYS software was applied to simulate the heat transfer and mass transfer, and the melt time of the steel strip in the iron melt was determined by linking the heat transfer and mass transfer, and then the feeding speed was calculated. Conclusions have been drawn that the iron layer was formed on the surface of the cored-wire during the wire-feeding process. The thickness is 0.073 mm when the temperature of the iron melt is 1500℃, the time from formation to remelting of the iron layer is 0.063~s. When the temperature of the iron melt is below 1500$^{\circ}$C, the time taken for the steel strip to melt is rapidly shortened. When the temperature of the iron melt is above 1500℃, the variation amplitude of the steel strip melt change with time is gradually diminished. The melt time of the steel strip is rapidly increased with the increase of the steel strip thickness. When the temperature of the iron melt is 1500℃ and the carbon content is 4 %, the melt time of a steel strip, which has a thickness of 0.5 mm, isthrice that of a steel strip whose thickness is 0.3 mm. The calculation results of the feeding speed are basically in agreement with the applied feeding speed in the factory.

关键词: Ductile iron , null , null , null

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

a-Si:H/a-Si_(1-x)C_x:H 多层膜的电学和光学性质

彭启才 , 周心明 , 蔡伯埙

材料研究学报

采用等离子体辉光放电单室系统制备的a-Si:H/a-Si_(1-x)C_x:H 多层膜结构具有低的暗电导和高的光电导特性,且不同于单层膜,有明显的S-W 效应。随着子层厚度L 减小,多层膜曝光态(B)的暗电导率σdB 较退火态(A)的σdA 减小快,即光诱导衰退程度增大,而光电导无明显变化。本文还测定了此多层膜结构的光能隙E_g,得到随子层厚度减小“蓝移”的结果。用一维单量子阱模型作了讨论,实验值与理论计算符合较好。

关键词: a-Si:H/a-Si_(1-x)C_x:H , superlattice , amorphous semiconductors electrical properties , optical properties , null

XH轧制法轧制H型钢轧制力模型的研究

潘亮 , 程知松 , 范爱琴 , 蔡庆伍 , 郭新文

钢铁

对采用XH轧制法轧制H型钢的轧制力进行分析,以西姆斯公式为基础,采用多元线性回归的方法建立万能轧机轧制H型钢的轧制力数学模型。用编程的方法对数学模型的系数进行求解,给出几种规格的H型钢回归模型的系数,并将计算结果与实测的数据进行对比分析,得到的结果与实测值的误差在6%以内,表明模型具有较高的应用价值。

关键词: H型钢;数学模型;回归分析;轧制力

X-H轧制法轧制H型钢轧制力模型的研究

潘亮 , 程知松 , 范爱琴 , 蔡庆伍 , 郭新文

钢铁

对采用X-H轧制法轧制H型钢的轧制力进行分析,以西姆斯公式为基础,采用多元线性回归的方法建立万能轧机轧制H型钢的轧制力数学模型.用编程的方法对数学模型的系数进行求解,给出几种规格的H型钢回归模型的系数,并将计算结果与实测的数据进行对比分析,得到的结果与实测值的误差在6%以内,表明模型具有较高的应用价值.

关键词: H型钢 , 数学模型 , 回归分析 , 轧制力

Properties of Evaporated Si_(1-x)Sn_x and Si_(1_x)Sn_x:H Amorphous Alloys

M. Vergnat , M.Gerl+ , Laboratoire de Métallurgie Physique et Science des Maériaux (U.R.A.au C.N.R.S.No. 155) , Universite de Nancy 1 , France

材料科学技术(英文)

Amorphous Si_(1-x)Sn_x alloys have been prepared by co-evaporation onto substrates maintained at liquid nitrogen temperature. Their atomic structure is investigated using density measurements, scanning high-energy electron diffraction and Mossbauer spectroscopy. The optical and electrical properties are reported. Then, a method to hydrogenate the films during the evaporation process is described and applied to the preparation of amorphous semiconductors from pure silicon to pure tin. Finally, multilayers of type Si / Si:H / ... or Si:H / Si:D / ... are studied. The modulation of hydrogen is shown by low-angle neutron scattering and measurements of hydrogen diffusivity are presented.

关键词: amorphous alloy , null , null

显微组织对X65~X70管线钢抗H2S性能的影响

张雁 , 蔡庆伍 , 谢广宇

腐蚀学报(英文)

通过扫描电镜(SEM)、透射电镜(TEM)等方法,研究了X65~X70级别管线钢在饱和H2S溶液中的氢致开裂行为,及不同显微组织、位错与析出对氢致开裂(HIC)的作用.结果表明:组织均匀的珠光体/铁素体型X65管线钢和铁素体/针状铁素体型X70管线钢均具有良好的抗H2S腐蚀性能;带状组织是裂纹萌生和扩展的主要途径;合金元素的弥散析出作用可以提高管线钢的抗硫化氢腐蚀性能.

关键词: 管线钢 , null , null

显微组织对X65~X70管线钢抗H2S性能的影响

张雁 , 蔡庆伍 , 谢广宇

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2007.06.004

通过扫描电镜(SEM)、透射电镜(TEM)等方法,研究了X65~X70级别管线钢在饱和H2S溶液中的氢致开裂行为,及不同显微组织、位错与析出对氢致开裂(HIC)的作用.结果表明:组织均匀的珠光体/铁素体型X65管线钢和铁素体/针状铁素体型X70管线钢均具有良好的抗H2S腐蚀性能;带状组织是裂纹萌生和扩展的主要途径;合金元素的弥散析出作用可以提高管线钢的抗硫化氢腐蚀性能.

关键词: 管线钢 , 显微组织 , 带状组织 , 氢致开裂(HIC) , 硫化氢(H2S)

掺铒a-SixC1-x-H薄膜的发光特性

卞留芳 , 张春光 , 陈维德 , 许振嘉 , 屈玉华 , 刁宏伟

中国稀土学报

用等离子体增强化学气相沉积(PECVD) 的方法,以固定的氢气(H2)流量和不同的硅烷(SiH4)和甲烷(CH4)流量比沉积了一系列的氢化非晶SiC(a-SixC1-x-H)膜.用这种宽带隙的a-SixC1-x-H材料作为掺铒的基体材料,通过离子注入的方法得到掺铒的a-SixC1-x-H(a-SixC1-x-H:Er)膜.注入以后的样品经过不同温度的退火.用X射线光电子能谱(XPS)、红外吸收光谱(IR)、拉曼散射谱(Raman)等技术研究不同的SiH4/CH4流量比和退火温度对a-SixC1-x-H:Er发光强度的影响.结果表明,高温退火引起了膜中C的分凝,对铒的发光是不利的.通过低温和室温下铒发光强度的比较,表明这种材料具有较弱的温度猝灭效应.

关键词: Er , SiC , 硅基材料 , 发光 , 稀土

Pd基催化剂上H_2快速选择催化还原NO_x

于青 , 孔凡晓 , 李兰冬 , 武光军 , 关乃佳

催化学报 doi:10.3724/SP.J.1088.2010.91211

首次研究了Pd基催化剂上氢快速选择催化还原NO_x反应(快速H_2-SCR反应).结果表明,Pd/Al_2O_3和Pd/SiO_2催化剂表现出极高的活性,在200℃以上时NO_x转化率可达100%;但Pd/MgO催化剂在整个考察温度范围均没有活性,这表明载体对催化剂快速H_2-SCR活性有决定性作用.与常规H_2-SCR反应相比,快速H_2-SCR反应明显提高了NO_x的消除效率.原位漫反射红外光谱结果表明,快速H_2-SCR反应活性的提高来源于加速生成的氨物种以及后续反应速率的加快.

关键词: 快速选择催化还原 , , , 一氧化氮 , 二氧化氮 ,

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