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~(199)Sn AND ~(57)Fe MOSSBAUER SPECTROSCOPIC STUDY OF THE MECHANICALLY ALLOYED Fe-Sn ALLOYS

Y.Z. Yang , Y.L. Zhu , Q.S. Li , X.M. Ma , Y.D. Dong and Y.Z. Chuang (Department of Materials Science and Engineering , Guangdong University of Technologyt Guangzhou 510090 , China)(Depotment of Materials Science and Engineering , Shanghai University , Shanghai 200072 , China)(Institute of Metal Research , The Chinese Academy of Sciences , Shenyang 110015 , China)

金属学报(英文版)

Nanocrystalline supersaturated solid solutions (Sa in Fe) with Sn content less than 50 at. %,and FeSn2 and Fe1.3Sn intermetallic compounds have been prepared by mechanical alloying of Fe and Sn mixture powders with composition of Fe1-xSnx (x≤0.5).The atomic alloying the formation and microstructure, especially the coordination environments, of the resultant alloys have been studied by X-ray diffraction, 57Fe and 119Sn Mossbauer Spectroscopy and diffrrential scanning calorimetry. The Fe and Sn coordination environments and the composition dependence of the hyperfine parameters on the Fe and Sn content have been fully discussed with respect to the solid dissolution alloying, grain refinement, and distortion caused or induced by mechanical alloying.

关键词: mechanical alloying , null , null

Guangzhou Institute of Energy Conversion,The Chinese Academy of Sciences,Guangzhou 510070,China

B.W. Wang , H. Shen

金属学报(英文版)

Ni-Cr System solar selective thin solid films were prepared by d.c. magnetron reactivesputtering under the atmosphere of O2 and N2. Ni-Cr alloy was chosen as targetmaterial and copper sheets as substrate. Using SEM, Spectrophotometer and Talystepto analyze the relations between the selective characteristic and the structure, theformation and the thickness of the thin films. The aim is to obtain good solar selectivethin films with high absorptance and low emittance, which is applied to flat plate solarheat collectors.

关键词: solar selective thin film , null , null , null

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