Yuanbin ZHANG
,
Dengyi REN
材料科学技术（英文）
Carbides in a series of cold-welding weld metals were studied by means of SEM, TEM and EPMA, and the forming mechanism of carbide was proposed according to their distribution and morphology. Due to their different carbide-forming tendency, Nb and Ti could combine with C to form particulate carbide in liquid weld metal and depleted the carbon content in matrix, while V induced the carbide precipitated along grain boundary. But too much Nb or Ti alone resulted in coarse carbide and poor strengthened matrix. When suitable amount of Nb, Ti and V coexisted in weld metal, both uniformly distributed particulate carbide and well strengthened matrix could be achieved. It was proposed that the carbide nucleated on the oxide which dispersed in liquid weld metal, and then grew into multi-layer complex carbide particles by epitaxial growth. At different sites, carbide particles may present as different morphologies.
关键词:
Cold-welding
,
null
,
null
,
null
张麦仓
,
董建新
,
曾燕屏
,
谢锡善
,
罗子健
金属学报
利用热力耦合有限元程序FORMT,对PM René 95合金中等尺寸(外径尺寸约为630 mm)涡轮盘的等温锻造工艺进行了模拟式设计.结果表明,采用TZM钼基合金模具,在1050℃以接近10-3s.的应变速率进行闭式模锻和开式模锻,模具材料均能满足使用要求,且开式模锻设备最大载荷不超过31×103kN;采用K21合金模具,在1000℃以相同条件等温成形,模具材料因变形热效应及边界摩擦引起温升而失效且所需设备吨位相对较大.
关键词:
PM
,
null
,
null
,
null
张麦仓
,
董建新
,
曾燕屏
,
谢锡善
,
罗子健
金属学报
doi:10.3321/j.issn:0412-1961.2002.10.022
利用热力耦合有限元程序FORMT,对PM René 95合金中等尺寸(外径尺寸约为630 mm)涡轮盘的等温锻造工艺进行了模拟式设计.结果表明,采用TZM钼基合金模具,在1050℃以接近10-3s.的应变速率进行闭式模锻和开式模锻,模具材料均能满足使用要求,且开式模锻设备最大载荷不超过31×103kN;采用K21合金模具,在1000℃以相同条件等温成形,模具材料因变形热效应及边界摩擦引起温升而失效且所需设备吨位相对较大.
关键词:
PM René 95合金,等温锻造,热力耦合有限元,模拟式工艺设计
付锐
,
陈希春
,
任昊
,
冯涤
航空材料学报
doi:10.3969/j.issn.1005-5053.2011.3.002
自行设计开发了适合工业化生产高纯净,低偏析,无宏观缺陷铸锭的电渣重熔连续定向凝固技术(ESR-CDS)的设备和工艺,利用该技术成功制备了直径为φ150mm的René88DT合金定向凝周铸锭.采用XRD测试了定向凝固柱状晶的生长取向,结果表明,ESR-CDS René88DT铸锭柱状晶择优生长方向为<100>系晶向;ERS-CDS铸锭与传统ESR铸锭相比,枝晶组织生长方向保持一致,二次枝晶臂均匀细小,元素偏析程度低,且晶间一次析出相呈颗粒状,尺寸细小;等温热压缩实验结果表明,ESR-CDS René88DT合金热压缩试样在1100℃,0.0-50.1s-1应变速率下可达到70%以上压缩变形量并获得均匀细小的动态再结晶组织;ESR-CDS René88DT合金铸锭经等温锻造制备出了φ170mm×73mm的饼坯件,锻压变形量超过70%,饼坯件除上下两端的变形死区外均发生了动态再结晶,晶粒尺寸约50μm.
关键词:
电渣重熔连续定向凝固
,
热变形
,
动态再结晶
李晓
,
董建新
,
张丽娜
,
张麦仓
,
胡尧和
,
谢锡善
,
国为民
金属学报
经不同固溶时效处理的PM René 95合金于650℃分别在蠕变、保载5和90 s疲劳载荷条件下进行了裂纹扩展速率实验.结果表明,相同热处理制度下,疲劳保载时间越长,裂纹扩展速率越高;相同载荷条件下,增加一次高温固溶并缓冷,有利于降低合金的裂纹扩展速率,且固溶温度越高裂纹扩展速率越低;1200℃一次固溶缓冷并于1160℃二次固溶热处理比1140℃一次固溶的裂纹扩展速率约降低一个数量级;基体晶粒尺寸适当加大,强化相粒子γ′c数量增加、形状趋于田字形,有利于降低裂纹扩展速率.
关键词:
René
,
null
,
null
李晓
,
董建新
,
张丽娜
,
张麦仓
,
胡尧和
,
谢锡善
,
国为民
金属学报
doi:10.3321/j.issn:0412-1961.2001.10.012
经不同固溶时效处理的PM René 95合金于650℃分别在蠕变、保载5和90 s疲劳载荷条件下进行了裂纹扩展速率实验.结果表明,相同热处理制度下,疲劳保载时间越长,裂纹扩展速率越高;相同载荷条件下,增加一次高温固溶并缓冷,有利于降低合金的裂纹扩展速率,且固溶温度越高裂纹扩展速率越低;1200℃一次固溶缓冷并于1160℃二次固溶热处理比1140℃一次固溶的裂纹扩展速率约降低一个数量级;基体晶粒尺寸适当加大,强化相粒子γ′c数量增加、形状趋于田字形,有利于降低裂纹扩展速率.
关键词:
René 95粉末高温合金,裂纹扩展速率,热处理
SUN Jian ZHANG Yuanhu HU Gengxiang Shanghai Jiaotong University
,
Shanghai
,
China SUN Jian
,
lecturer
,
Department of Materials Science
,
Shanghai Jiaotong University
,
Shanghai 200030
,
China
金属学报(英文版)
The creep crack propagation in superalloy René80 of two different microstructures,i.e., equiaxed grain structure by conventional casting and columnar grain by directional solidification,was investigated under static load at 1123 K.The creep crack growth rate, da/dt,seems to be correlated with the stress intensity factor,K.The creep crack growth rate in the directionally solidified alloy is lower than that in the conventional cast alloy,owing to the elimination of transverse grain boundaries.The effect of microstructure on creep crack propagation has also been discussed.
关键词:
Superalloy René 80
,
null
,
null
,
null
邝钜炽
稀土
doi:10.3969/j.issn.1004-0277.2006.01.008
能谱成分分析结果表明,加入稀土硝酸盐(REN)后磷化膜内P元素含量增大,Zn元素含量减小,而对磷化膜耐腐蚀性的贡献为P＞Zn.由SEM形貌分析可获知,添加REN后无定形晶体Zn2Fe(PO4)2在磷化膜表面覆盖率有较大幅度提高,从而使得膜的P/(P+H) 比率增大,磷化膜的耐蚀性能提高.机理研究则指出,稀土实质是一个有良好载氧能力的催化剂,具有良好的成核促进作用和阴极去极化作用,在磷化过程中同时发挥了表调剂、促进剂与致密剂的作用,加速了磷化过程,并使膜的耐腐蚀性能提高.
关键词:
稀土硝酸盐(REN)
,
磷化膜
,
形貌分析
,
去极化作用
,
成核促进作用
