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IMPROVEMENT OF MATERIALS WELDABILITY BY SHOCK WAVES

H. N. Chen , D. Li and H. Y. Du Institute of Metal Research , The Chinese Academy of Sciences , Shenyang 110015 , China

金属学报(英文版)

The weldability is an important property to metal materials. Materials weldability becomes worse with the yield strength increasing. The experimental results indicate that the specific shock waves treatment could improve the weldability of steels such as 16MnR, SM 58Q, e.g. increase the notch toughness of coarse grains zone in HAZ and decrease cold cracking sensibility. The work would explore initially the mechanisms of improvement of weldability by shock waves. The further study on the low alloy high strength steel WEL TEN80 indicates that the shock waves may increase the material weldability on this grade of trength.

关键词: shock waves , null , null

Catalytically enhanced dehydrogenation of Li-Mg-N-H hydrogen storage material by transition metal nitrides

Journal of Alloys and Compounds

Motivated by the understanding of dehyrogenation/rehydrogenation reaction mechanisms, we examine the effect of two commercial transition metal nitrides. TaN and TiN, oil the dehydrogenation performance of Li-Mg-N-H system. Both nitrides are catalytically active for accelerating the dehydrogenation reaction of this system. Such catalytic enhancement well persists without hydrogen capacity loss. A catalytic mechanism is proposed Willi reference to the catalytic, model for hydrotreating reactions by transition metal nitrides. (c) 2008 Elsevier B.V. All rights reserved.

关键词: Hydrogen absorbing materials;Nitride materials;molybdenum nitride;system;improvement;catalysts;mechanism;mixtures;hydride;imides;amide;linh2

Corrosion of Y, Fe and Fe-15Y in H_2-H_2S Mixture under 10~(-3) Pa S_2 at 600~800℃

Yan NIU , Weitao WU and Chaoliu ZENG (State Key Lab. for Corrosion and Protection , Institute of Corrosion and Protection of Metals , Chinese Academy of Sciences , Shenyang 110015 , China)F. Gesmundo and F. Viani (Instituto di Chimica , Facolta di Ingegneria , Un

材料科学技术(英文)

The corrosion of an Fe-based alloy containing 15 wt pct Y in H2-H2S mixtures under 10-3 Pa S2 was studied at 600~800℃ in an attempt to find materials with improved sulphidation resistance with respect to pure Fe. The presence of Y has been shown to be beneflcial, but not sufficient to the level expected. In fact, the alloy is able to form at all tested temperatures an external FeS layer, beneath which a zone containing a mixture of the two sulphides is also present. Thus,Fe can still diffuse through this region to form the outer FeS layer with non-negligible rate. The corrosion rate of Fe is considerably reduced by the Y addition. but the alloy corrodes still much more rapidly than Y. The sulphidation kinetics is generally rather irregular for both the pure metals, while the corrosion rate of the alloy decreases with time and tends to become parabolic after an initial period of 12~17 h. The sulphidation behaviour of the alloys is discussed by taking into account the presence of an intermetallic compound Fe17Y2 and the limited solubility of Y in Fe

关键词:

Corrosion of Y, Fe and Fe-15Y in H-2-H2S mixture under 10(-3) Pa S-2 at 600 similar to 800 degrees C

材料科学技术(英文)

The corrosion of an Fe-based alloy containing 15 wt pet Y in H-2-H2S mixtures under 10(-3) Pa S-2 was studied at 600 similar to 800 degrees C in an attempt to find materials with improved sulphidation resistance with respect to pure Fe. The presence of Y has been shown to be beneficial, but not sufficient to the level expected. In fact, the alloy is able to form at all tested temperatures an external FeS layer, beneath which a zone containing a mixture of the two sulphides is also present. Thus, Fe can still diffuse through this region to form the outer FeS layer with non-negligible rate. The corrosion rate of Fe is considerably reduced by the Y addition, but the alloy corrodes still much more rapidly than Y. The sulphidation kinetics is generally rather irregular for both the pure metals, while the corrosion rate of the alloy decreases with time and tends to become parabolic after an initial period of 12 similar to 17 h. The sulphidation behaviour of the alloys is discussed by taking into account the presence of an intermetallic compound Fe17Y2 and the limited solubility of Y in Fe.

关键词: high-temperature sulfidation;most-reactive component;ni-nb alloys;h2-h2s mixtures;behavior;600-degrees-c-800-degrees-c;oxidation

HIGH-RESOLUTION ELECTRON-MICROSCOPY STUDY OF DEFECTS IN AN FCC PHASE FORMED BY INGOT CASTING IN AL-LI-CU-MG ALLOYS

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

An fc.c. phase designated Y has been studied by means of high resolution electron microscopy (HREM) and transmission electron microscopy in Al-Li-Cu-Mg alloys. HREM observation and electron diffraction patterns show the intergrowth of another Franker-Kasper domain (designated D) with the Y phase. The D domain can grow on both the (001) and the (111) planes of the Y phase. The orientation relationships between the D domain and the Y phase are [110]Y//[100]D, (111BAR)Y//(001)D and [110]Y//[100]D, (001)Y//(010)D.

关键词:

A special structure in Al-Mg-Li alloy (01420) weld metal

材料科学技术(英文)

A large quantity of laminated fine grain zones were observed in the Al-Mg-Li alloy weld metal by manual TIG, which was not found in ordinary Al alloy welds. The fine grain zone is formed because of the Al-3(Zr,Ti) particles in the filler metal and the manual filling of filler metal in welding process.

关键词:

大爆炸核合成相关的8Li(d, p)9Li反应截面测量

李志宏 , 柳卫平 , 白希祥 , 郭冰 , 连钢 , 颜胜权 , 王宝祥 , 陆昀 , 曾晟 , 苏俊

原子核物理评论 doi:10.3969/j.issn.1007-4627.2005.01.006

利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.

关键词: 8Li(d,p)9Li反应 , 角分布 , 天体物理S因子 , 渐近归一化系数

MICROSTRUCTURE AND PROPERTIES OF SiC_w/6061Al COMPOSITE The Author is now with Institute of Metal Research,Academia Sinica,China

MA Zongyi YAO Zhongkai Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure

关键词: composite , null , null , null

Improving glass-forming ability of Mg-Cu-Y via substitutional alloying: Effects of Ag versus Ni

Journal of Materials Research

Based on the best bulk metallic glass (BMG) forming alloy in the Mg-Cu-Y ternary system, we introduced Ag (or Ni) to partially substitute for Cu to improve the glass-forming ability (GFA). The objective of this paper is twofold. First, we illustrate in detail a recently developed search strategy, which was proposed but only briefly outlined in our previous publication [H. Ma, L.L. Shi, J. Xu, Y. Li, and E. Ma: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 (2005)]. The protocol to navigate in three-dimensional composition space to land large BMGs is spelled out step-by-step using the pseudo-ternary Mg-(Cu,Ag)-Y as the model system. Second, our ability to locate the best BMG former in the composition tetrahedron allows us to systematically examine, and conclude on, the effects of a given alloying element. The large improvement in glass-forming ability in the Mg-(Cu,Ag)-Y system relative to the based ternary will be contrasted with the reduced glass-forming ability in the Mg-(Cu,Ni)-Y pseudo ternary system. It is demonstrated that the improvement of glass-forming ability requires judicious choice of substitutional alloying elements and concentrations, rather than simple additions of multiple elements assuming the "confusion principle."

关键词: bulk metallic-glass;shaped copper mold;amorphous-alloys;thermal-stability;ternary-system;casting method;p system;diameter;zr;mm

First-principle investigation of 3d transition metal elements in gamma '-Co(3)(Al, W)

Journal of Applied Physics

The alloying effect of 3d transition metal elements on the lattice constants and their site preferences in gamma'-Co(3)(Al, W) are systematically studied based on a supercell model. The lattice constant of the gamma' phase is modified by the addition of 3d transition metal elements, and it increases in the order of Fe < Ni < Mn < Cr < V < Ti. Four types of site preference are identified for these 3d elements in gamma' phase by analyzing the binding energy and the impurity formation energy. Ni, Fe, V, and Ti are recognized to stabilize the gamma' phase. Their distinct alloying effect is further revealed by investigating the impurity-induced charge density difference and the partial density of states. These results are in agreement with the experimental data ever reported. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3319650]

关键词: augmented-wave method;co-base superalloy;electronic-structure;site;preference;ni3al;phase;temperature;stability;magnetism;alloys

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