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CORROSION PROTECTION OF Al CATHODES IN ZINC ELECTROLYSIS

F. Lu and WJ. van Ooij( Beijing Institute of Aeronautical Materials , P.O. Box 81-5 , Beijing 100095 , China)( Department of Materials Science and Engineering , University of Cincinnati , Cincinnati , OH 45221-0012 , U.S.A.)

金属学报(英文版)

Zn-Al couple's galvanic coeeosion was a serious problem in acdic ainc sulfate solution .In this paper, a new pretreatment or a coating for Al was developed and tested to protect the Al effectively form corrosion when connected to pure Zinc at electroplating potential,and exposed to an acdic sulfate solution.Corrosion measurement techniques(Galvanic corrosion and DC)were used to investigate galvanic corrosion between Al cathode and Zn anode.It was found out that Al alloy purity and electroplating potential have a large effect on galvanic corrsion between Zn-Al couples.EIS,salt spray test and immersion test were performed to evaluate the method for Al cathodes in zinc electrolyte,BTSE silane pretreatment and polyurethane coating displayed better corrosion protection.Calculation showed the Al dissolution rate is small enough for Al cathode to be used in zinc plants.BTSE treatment or BTSE plus polyurethane coating has the best corrosion performance,and willprotect the Al cathode effectively in zinc electrolysis

关键词: Al-Zn couple , null

Structural Applications of NiAl

R.Darolia(GE Aircraft Engines , 1 Neumann Way , Cincinnati , OH 45215 , USA)

材料科学技术(英文)

Alloys based on NiAl offer significant payoffs as structural materials in gas turbine applications due to a unique range of physical and mechanical properties These properties include high melting temperature. low density. high thermal conductivity. and excellent environmental resistance Very significant improvements in the strength and ductility of NiAl single crystals have been achieved through alloying. Tensile strength and stress rupture properties which compete with current Ni-base Superalloys have been achieved through precipitation of an ordered L21 Heusler phase in NiAl single crystals Room temperature tensile ductility as high as 6% has been produced in NiAl single crystals containing less than 0.5% (atomic) of Fe. Ga or Mo. However. a single alloy with both room temperature ductility and sufficient high temperature strength has not yet been developed. While activity to develop on alloy with both high temperature strength and room temperature ductility continues. the Current approach also emphasizes design and test methodologies which can accept a material with limited ductility and damage tolerance More work is required on measuring and understanding strain rate sensitivity and impact behaviour While several significant challenges still remain. excellent progress has been made in many areas, and the prognosis for using NiAl alloys as high temperature structural materials is promising

关键词:

RECENT DEVELOPMENTS IN NiAl TECHNOLOGY FOR TURBINE AIRFOILS

R.Darolia (GE Aircraft Engines , 1 Neumann Way , Cincinnati , Ohio 45215)

金属学报(英文版)

NiAl alloys offer significant payoffs as structural materials in gas turbine applications due to high melting temperature low density,high thermal conductivity and excellent environmental resistance.Significant improvements in the material properties and processing have been achieved. The current approach also emphasizes design and test methodologies which can accept a material with limited ductility and damage tolerance. NiAl alloys have been successfully manufactured into a variety of turbine components. A high pressure turbine vane is currently being engine tested.

关键词: : nickel aluminide; NiAl; single crystal; strength;ductility; toughness

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