Xiangcheng SUN
,
Mingchuan YANG
,
Feng YE
,
Xiukui SUN and Wenduo WEI(State Key Lab. for RSA
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)Yingda YU and Dehai PING(Lab. of Atomic Imaging of Solids
,
Institute of Metal Resea
材料科学技术(英文)
Mixed Al+AlN nanoparticles were synthesized by an active plasma-metal reaction method. Mean particle size of the mixed Al+AlN nanoparticles is about 30-50 nm. Defects were found in some AlN particles. Moreover, the AlN ratio and its particle size in mixed Al+AIN nanoparticles obtained in different atmospheres (N2+Ar) increase with increasing N2 particle pressure, and the specific sudece areas of the mixed Al+AlN nanoparticles increase with the AlN ratio. The surface degradation of the Al+AlN exposed to air is estimated by the infrared absorption spectra
关键词:
WANG Haifeng
,
ZHANG Chunxia
,
QI Yuanhong
钢铁研究学报(英文版)
China is short of water seriously. But granulation of blast furnace slag (BFS) with water has many disadvantages, such as high water consumption and difficulty in heat recycling. So developing a new dry granulation technique to treat BFS is very important. The applicability of BFS directly depends on the content of non-crystalline solids in the slag after treatment. So it is of theoretical and practical significance to analyze the content of non-crystalline solids in the slag quantitatively and simply. Metallographical test is mainly adopted to quantify the non-crystalline in BFS now with the shortages such as making sample complexly, determining difficultly and personally. For the diffraction intensity of non-crystalline is proportionate to the content of non-crystalline in BFS, X-ray diffraction method was adopted to quantify the non-crystalline and the crystalline solids in BFS. The quantificational coefficient between the crystalline and the non-crystalline solids of BFS is 0.70 whose main composition is: w(CaO)38.2%,w(SiO2)35.7%,w(Al2O3)16.3%,w(MgO)8.3%. The relatively error of using X-ray diffraction instrument to quantitative analyse non-crystalline content of BFS is less than 1%.
关键词:
Blast Furnace Slag;Non-Crystalline;Crystalline;Quantificational Analysis
Chinese Physics Letters
We study the crack propagation in layered solids and find that when there exists an easy-fractured layer, the fractal surface becomes more rough, which is characterized by larger fractal dimensions.
关键词:
dimension
Advanced Materials
The key to the formation of nanocrystallites from amorphous solids lies in the annealing temperature. This aspect of the preparation of nanocrystalline materials is covered, as are other attractive features of this method, for example, that it can be applied to most alloy and pure element systems, large quantities of nanocrystalline samples can be produced, and the grain size can be controlled. The properties of these materials are also described and it is concluded that more studies on 3D bulk: porosity-free, and clean samples are needed.
关键词:
ultrafine grain-structure;alloys;selenium;sizes
Physical Review B
The pressure effect on crystallization kinetics of amorphous solids was investigated by means of thermodynamic analysis. A model was developed to describe the nucleation process under pressure by considering the crystalline/amorphous (c/a) interface that plays a dominant role in the nucleation process. Applying the model to three types of crystallization process, polymorphous (a-Se), primary (Al89La6Ni5), and eutectic (Ni80P20), we found the calculated results can give reasonable explanations for the experimental observations. The calculation suggests that for a-Se and Ni80P20 amorphous alloy, the initial stage of nucleation is a volume expansion process due to the c/a interface formation, resulting in an increase in the nucleation work with an increment of pressure. Hence the crystallization temperature of the amorphous phase rises when a pressure is applied, while for the Al-La-Ni amorphous alloy, the nucleation barrier decreases at higher pressures. The coincidence between the calculation and the experimental results illustrates that the cia interface formation is the governing factor in the crystallization kinetics of the amorphous solids. [S0163-1829(99)03534-1].
关键词:
activation volume;nanocrystalline state;metallic glasses;diffusion;alloy;selenium;phase;se;transformations;microstructure
Journal of Physics-Condensed Matter
This research purposes to investigate the atomic and electronic structures of the Al/TiC(001) interface with lattice misfit using the ab initio pseudopotential approach. A detailed analysis of the relaxed atomic structure reveals that the atoms over the initial unfavourable sites relax to the favourable sites along the lateral plane. The properties of the semicoherent interface can be taken as averages over the different coherent sites. In addition, the interface atoms in relatively favourable regions are dragged near to the interface, while those in unfavourable regions are pushed away from the interface. Therefore, a large war-ping near the interface is made perpendicular to the lateral plane. The calculated adhesions explain the different wetting results from the viewpoint of structural transition. The subsequent analysis of electronic properties demonstrates that adhesions dominate mainly via the strong Al-C covalent bond.
关键词:
first-principles;1st principles;adhesion;surfaces;misfit;1st-principles;wettability;al