Guanghou WANG(National Lab. of Solid State Microstructures
,
Nanjing University
,
Nanjing 210093
,
China)Fengqi LIU(Center for Advanced Studies in Science and Technology of Microstructures
,
Nanjing 210093
,
China)
材料科学技术（英文）
We have studied structures and properties of nanostructured films prepared with nanometersized lithium fluoride(LiF) clusters by inert gas condensation method, and then characterized by transmission electron microscope, Fourier transform infrared spectra and Raman scattering spectra, etc. Following important results are obtained: Multi-order-like Raman scatterings from LiF clusters are obtained, including the fine structure of the spectra. The observed Raman peaks are discussed in terms of surface optical modes, Lo. To, LA modes and their combination form.As the cluster size decreases, the phonons are confined in nanoscale so that the q vector selection rule is relaxed or even totally free of q conservation, and prohibition at the first- and third-order scatterings in the bulk LiF crystal is relaxed. The sudece modes appear and play an important role in Raman scattering processes. The infrared absorption spectra are obtained with different deposition conditions. When the clusters are in the medium size range from ～7 to 15 nm, most infrared absorption peaks are second-order feature, and no single surface mode emerges. For the smaller clusters, molecular-like vibration is observed whereas the broad band of long wavelength transverse-optical modes appear from 580 to 400 nm-1 for the clusters larger than 19 nm
关键词:
LIANG Yong LI Ruiguo Institute of Metal Research
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Academia Sinica
,
Shenyang 110015
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ChinaInstitute of Corrosion and Protection of Metals
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Aademia Sinica
,
Shenyang
,
110015
,
China
材料科学技术（英文）
Recent advances in laser coating technology including laser cladding,laser surface alloying and laser vapour deposition in China are reviewed in this paper.
关键词:
laser
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null
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null
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null
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null
Materials Characterization
Segregation of yttrium induces the formation of Y0.25Zr0.75O2-x and Y0.5Zr0.5O2-y microdomains, with L1(2)- and L1(0)-like ordered structures, in ZrO2-6mol%Y2O3 ceramics in both the sintered and annealed states. The compositions of precipitates such as (chi L), (chi S), (chi SS), and small precipitates formed inside XL, in Cu-11.88Al-5.06Ni-1.63Mn-0.96Ti (wt.%) shape memory alloys have been determined. Under electron beam irradiation, four types of dynamic behavior of the G.P. zones were observed in the Al-6.58Zn-2.33Mg-2.40Cu (wt.%) alloy. The G.P. zone and "G.P. zone-like" defect structures were also distinguished. Lattice distortion profile in the GaAs/InxGa1-xAs superlattice and two-dimensional lattice distortion around a 60 degrees dislocation core in the InAs(x)P(1-)x/InP superlattice were determined. (C) Elsevier Science Inc., 2000. All rights reserved.
关键词:
shape-memory alloys;zirconia;phase;ti;diffraction;crystal
