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INVESTIGATION ON 1/3[111] FRANK LEDGE DISLOCATIONS AT α_2/γINTERFACE IN HOT-DEFORMED Ti-45Al-10Nb ALLOY

J.G WanG , L.C Zhang , G.L. Chenand HQ. Ye(State Key Laboratory for Advanced Metals and Materials , Unborsity of Science and Technology Beijing , Beijing 100083 , China)(Laboratory of Atond Imaging of Solids , Institute of Metal Research , Chinese Academy of Sciences , Shenyang 110015 , China)

金属学报(英文版)

The dislocation ledges at the α2/7 intedece in a hot-dejormed Ti-45Al-10N alloywere analyzed by high-resolution tmnsmission electron microscopy. A new type ofdislocation ledge containing 1/3[111] Frank partial was found. The height of the ledgestDas always three [111]γplanes. The Burpers vectore of these diBlocation ledges weredetermined to be 1/2[110] and 1/2<101] corresponding to the 90 dey. and 30 deg.Shockley partials at noral ledges, i.e. 90 dep. ShockIey Partial dislocation +1/3[111]Frank partial dislocation; and 30 deg. Shockley partial dislocation + 1/3[111] Frankparfial dislocations. The jormation mechanism of this new tare of dislocation ledgewas discussed.

关键词: titanium aluminide , null , null , null

Quantitative Analysis of Non-Crystalline and Crystalline Solids in Blast Furnace Slag

WANG Haifeng , ZHANG Chunxia , QI Yuanhong

钢铁研究学报(英文版)

China is short of water seriously. But granulation of blast furnace slag (BFS) with water has many disadvantages, such as high water consumption and difficulty in heat recycling. So developing a new dry granulation technique to treat BFS is very important. The applicability of BFS directly depends on the content of non-crystalline solids in the slag after treatment. So it is of theoretical and practical significance to analyze the content of non-crystalline solids in the slag quantitatively and simply. Metallographical test is mainly adopted to quantify the non-crystalline in BFS now with the shortages such as making sample complexly, determining difficultly and personally. For the diffraction intensity of non-crystalline is proportionate to the content of non-crystalline in BFS, X-ray diffraction method was adopted to quantify the non-crystalline and the crystalline solids in BFS. The quantificational coefficient between the crystalline and the non-crystalline solids of BFS is 0.70 whose main composition is: w(CaO)38.2%,w(SiO2)35.7%,w(Al2O3)16.3%,w(MgO)8.3%. The relatively error of using X-ray diffraction instrument to quantitative analyse non-crystalline content of BFS is less than 1%.

关键词: Blast Furnace Slag;Non-Crystalline;Crystalline;Quantificational Analysis

FRACTAL NATURE OF A FRACTURE SURFACE IN LAYERED SOLIDS

Chinese Physics Letters

We study the crack propagation in layered solids and find that when there exists an easy-fractured layer, the fractal surface becomes more rough, which is characterized by larger fractal dimensions.

关键词: dimension

Melting and superheating of crystalline solids: From bulk to nanocrystals

Progress in Materials Science

Melting of solids is a common phenomenon in nature. It is also one of the most important phase transformations in materials science and engineering. In recent years, extensive experimental and theoretical investigations in conjunction with computer simulations on melting of solids, with various geometries ranging from bulk forms to nanometer-sized clusters, have greatly enhanced our understanding of the nature of melting. This paper reviewed the up-to-date research results on this classical and cutting-edge topic. Emphasis was made on melting and superheating of nano-sized particles and thin films including thermodynamic and kinetic analyses of the size effect and the interfacial structure effect on melting processes. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: isolated tin nanoparticles;embedded pb nanoparticles;kinetic stability;limit;energy ion-scattering;equation-of-state;small particles;electron-microscopy;molecular-dynamics;al(110) surface;al matrix

Synthesis of nanocrystalline materials from amorphous solids

Advanced Materials

The key to the formation of nanocrystallites from amorphous solids lies in the annealing temperature. This aspect of the preparation of nanocrystalline materials is covered, as are other attractive features of this method, for example, that it can be applied to most alloy and pure element systems, large quantities of nanocrystalline samples can be produced, and the grain size can be controlled. The properties of these materials are also described and it is concluded that more studies on 3D bulk: porosity-free, and clean samples are needed.

关键词: ultrafine grain-structure;alloys;selenium;sizes

Crystallization kinetics of amorphous solids under pressure

Physical Review B

The pressure effect on crystallization kinetics of amorphous solids was investigated by means of thermodynamic analysis. A model was developed to describe the nucleation process under pressure by considering the crystalline/amorphous (c/a) interface that plays a dominant role in the nucleation process. Applying the model to three types of crystallization process, polymorphous (a-Se), primary (Al89La6Ni5), and eutectic (Ni80P20), we found the calculated results can give reasonable explanations for the experimental observations. The calculation suggests that for a-Se and Ni80P20 amorphous alloy, the initial stage of nucleation is a volume expansion process due to the c/a interface formation, resulting in an increase in the nucleation work with an increment of pressure. Hence the crystallization temperature of the amorphous phase rises when a pressure is applied, while for the Al-La-Ni amorphous alloy, the nucleation barrier decreases at higher pressures. The coincidence between the calculation and the experimental results illustrates that the cia interface formation is the governing factor in the crystallization kinetics of the amorphous solids. [S0163-1829(99)03534-1].

关键词: activation volume;nanocrystalline state;metallic glasses;diffusion;alloy;selenium;phase;se;transformations;microstructure

PREPARATION AND REACTIVITIES OF COMPOSITE NANOCRYSTALLINE SOLIDS PREPARED BY MECHANICAL ALLOYING

Journal of Non-Crystalline Solids

The formation of Fe-SiC composite, nanocrystalline solids through ball milling is reported. The effects of mechanical deformation, crystallite size and gaseous elements on the solid state reaction between Fe and SiC are also investigated. The formation of Fe3C after a long milling time is attributed to the kinetics of the reaction between nanocrystalline Fe and SiC.

关键词:

Characterisation of initial atmospheric corrosion carbon steels by field exposure and laboratory simulation

Corrosion Science

The early stages of the evolution of atmospheric corrosion of carbon steels exposed in both a laboratory simulated and a natural atmosphere environment in Shenyang have been observed by in situ scanning electron microscopy. In the case of laboratory cyclic wet-dry tests, even though the chloride content level is very low, filiform corrosion is initiated in the early stage. The filiform corrosion grows in random directions, forming a network of ridges. White nodules nucleate and grow on the ridges during continued corrosion and eventually connect with each other to form the initial corrosion scale. Pits were also found on the surface beneath corrosion products. In the case of a natural atmospheric environment, both filiform corrosion and other localized corrosion, such as pitting and inter-granular attack take place in the initial stage. It is obvious that there is variety of localized corrosion in the initial stage of atmospheric corrosion. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: steel;atmospheric corrosion;initial stage;localized corrosion;in-situ;iron;electrolyte;thickness

Plan-view imaging of oxygen-induced reconstruction on Ag(110) surface. I. The possibility of imaging surface oxygen

Journal of Electron Microscopy

Surface reconstruction on Ag(110) induced by oxygen adsorption was studied by the plan-view imaging technique of high-resolution electron microscopy (HREM). Systematic multislice simulations were carried out to find the optimal experimental conditions for imaging the surface oxygen. It was found theoretically that there exist a series of characteristic values of objective lens defoci and sample thicknesses under which the surface and the bulk can be imaged clearly and simultaneously. These optimal imaging conditions were used to interpret the experimental micrographs. While the basic features of the surface reconstruction of O/Ag(110) in the HREM images are consistent with those revealed by scanning tunnelling microscopy (STM), there are some new features that have not been reported with STM. These phenomena give some evidence to the existence of subsurface oxygen.

关键词: plan-view imaging of surfaces;silver;surface reconstruction;high-resolution electron microscopy;computer simulation;transmission electron-diffraction;copper oxidation;initial-stage;kinematical approximation;ethylene epoxidation;subsurface oxygen;au(001) surface;o chains;microscopy;adsorption

Nanocrystalline metals crystallized from amorphous solids: Nanocrystallization, structure, and properties

Materials Science & Engineering R-Reports

Polycrystalline materials with nanometer-sized grains, termed nanocrystalline materials, can be formed by crystallizing completely amorphous solids under proper heat treatment conditions. The crystallized nanocrystalline materials exhibit some unique structural characteristics and novel properties which are fundamentally different from those of the conventional coarse-grained polycrystalline materials. This article reviews the present state of the art in this field. The current status of research and developments on the nanocrystallization, microstructure and properties of the materials will be summarized. Comparisons of structural characteristics and properties are made between the crystallized nanocrystalline materials and those prepared by other methods. Further considerations of the development and applications of this new class of materials will also be presented.

关键词: nanocrystallization;metals;structural characteristics;hall-petch relation;ni-p alloys;ultrafine grain-structure;positron-annihilation spectroscopy;differential scanning calorimetry;severe plastic-deformation;randomly arranged atoms;insitu tem;observation;free-energy change;thermodynamic properties

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