Xingyuan LUO
,
Jialin SUN
,
Chengji DENG
,
Yanruo HONG
材料科学技术（英文）
It is worth to study the synthesis of β-Sialon from coal gangue, because coal gangue is a waste of coal production and is a high quality kaolin contained carbon which is a perfect raw material of contained reducer itself for synthesis of β-Sialon. The study showed that a high conversion rate of 95% from coal gangue to β-Sialon could be obtained by using process of carbothermal reduction nitridation when strictly controlled the thermodynamic conditions of synthesis. For controlling the synthesis conditions easy, the details of the effects of pco, po2 and T on the conversion rate of β-Sialon were discussed detailedly and the phase diagrams of oxygen pressure vs composition for Si3N4-AlN-Al2O3-SiO2 system at 1350, 1500, and 1600oC were constructed in the paper.
关键词:
β-Sialon
,
null
,
null
,
null
Hong TAO
,
Chengji DENG
,
Lianmeng ZHANG
,
Runzhang YUAN
材料科学技术（英文）
Al/Al2O3 composites of different ratios were hot-press sintered at 575 similar to 640℃ under a pressure of 30 MPa for 2 h in a vacuum furnace. It was found that the relative density of the Al/Al2O3 composites could be increased evidently with the rise of sinter temperature. No reaction occurred between Al and Al2O3 at the sinter temperatures. Under 640℃-30 MPa-2 h experimental condition, Al/Al2O3 system FGM was successfully fabricated, and its density range changed quasi-continuously from 2.887x10(3) kg/m(3) to 3.1909x10(3) kg/m3 within the middle 1.0 mm thickness range.
关键词:
佟媛媛
,
华勤
上海金属
doi:10.3969/j.issn.1001-7208.2010.03.011
运用热分析技术研究了冷却曲线特征值与319铝合金中化学成分之间的关系,并进行回归分析.结果表明,在不考虑工艺因素的情况下,试样的硅含量与α-Al枝晶生长回升温度TαDENG之间的相关性最大,相关系数r为-0.65,以硅含量可预测α-Al枝晶生长回升温度.在浇注过程中,冷却速度与α-Al枝晶生长回升温度TαDENG密切相关,相关系数为r=-0.72.在相同的冷却条件下,铝合金的浇注温度和浇注量对冷却速度有明显的影响,因此,可以通过调整浇注温度和浇注量,控制铝合金的冷却速度,进而也可预测铝合金中α-Al枝晶生长回升温度TαDENG.
关键词:
319铝合金
,
热分析
,
特征值
,
浇注工艺
Journal of Applied Physics
Motivated by the recent experimental fabrication of half-metallic MnSb and CrSb thin films with metastable zinc-blende structure [Aldous et al. Phys. Rev. B 85, 060403(R) (2012); Deng et al. J. Appl. Phys. 99, 093902 (2006)], we investigate the structural, electronic, and magnetic properties of TiSb in both ground-state NiAs and metastable zinc-blende phases by using the first-principles calculations. It is shown that the ground-state NiAs phase is metallic and nonmagnetic, but the metastable zinc-blende phase exhibits half-metallic ferromagnetism with a magnetic moment of 1.00 mu(B) per formula unit. We also reveal that the half-metallicity in bulk ZB TiSb is lost at the Sb-terminated (001) surface due to the appearance of surface states within the gap of the minority-spin channel, but the Ti-terminated (001) surface retains the bulk half-metallicity, which makes ZB TiSb a promising candidate for the possible epitaxial growth of half-metallic thin films or multilayers on semiconductor substrates for spintronic applications. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4739744]
关键词:
room-temperature ferromagnetism;molecular-beam epitaxy;crsb;cras;spintronics;state;mnas
