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AGE STRENGTHENING OF DIFFUSION WELDED JOINT OF Al_2O_(3p)/6061Al COMPOSITE

J. T. Niu , Y. H. Tian , B. Y. Li , J. J. Xu , L.M. Liu (National Key Laboratory of Advanced welding Production Technology , HIT , Harbin 150001 , China)

金属学报(英文版)

Tensile strength of diffusion welded joint of aluminum matrix composite is very low due to its poor weld- ability.In this paper, solution and age treatments were conducted on the welded joint of Al2O3p/ 6061Al composite subjected to diffusion welding using Gleeble 1500 machine, and ensile strength and microstructure of welded joint aged at175℃ were measured and analyzed respectively, Results showed that aging precipitation of welded joint is promoted effectively because of redistribution of reinforcement and a few number of dislocations in the matrix of weld zone resulting from welding pressure,and hence tensile strength of welded joint is increased significantly after aging treatment.

关键词: aluminum matrix composite , null , null

Preparation of Li-B alloy and study of its microstructure and discharge characteristics

Zhijian LIU , Zhiyou LI , Wei DUAN , Xuanhui QU , Baiyun HUANG , Siqi ZHANG

材料科学技术(英文)

A LI-B alloy has been prepared using a pretreated amorphous B powder and pure Li ingot as starting materials by continually slow addition of B powder and intensified stirring in the process of melting. The microstructure and the discharge characteristic of the materials have been investigated. Results show that the problem of temperature control in synthesis would be modified by means of continual addition of B powder, the Li7B6 would be more finery distributed in the metal Li by means of intensified stirring. The discharge characteristic of the Li-B alloy using amorphous B as starting materials is almost the same with that of using crystalline B.

关键词:

Enhancement of upconversion emission in Y(3)Al(5)O(12):Er(3+) induced by Li(+) doping at interstitial sites

Chemical Physics Letters

The influence of site occupancy of Li(+), including substitutional and interstitial sites, on the upconversion emissions of Er(3+) doped Y(3)Al(5)O(12) powders is reported. The intensity of green emission increases slightly when the Li(+) occupies substitutional site, but when the Li(+) enters into interstitial site it enhances drastically accompanied with a change of emission spectra. These phenomena originate from the increase, induced by interstitial Li(+), in the lifetime of (4)I(11/2) level, the ratio of radiation rate in green emission and the absorptivity at 980 nm. (C) 2010 Elsevier B.V. All rights reserved.

关键词: y2o3 nanocrystals;er3+;photoluminescence;ions

Li-B合金的制备及反应机制研究

许小静 , 段柏华 , 曲选辉 , 罗远辉

稀有金属材料与工程

通过对合成装置的温控、散热、搅拌桨叶片等进行有效改进,获得了300 g/炉的制备规模,制备出的合金性能均匀一致,其密度及抗拉强度分别为0.870 g/cm3,12.61 Mpa.同时,根据反应合成现象及XRD结果,分析了Li-B合金的反应机制及其动力学过程.

关键词: 热电池 , Li-B合金 , 阳极材料 , 制备 , 反应机制

Li+掺杂对Y2SiO5∶Pr3+上转换发光性能影响

刘成 , 杨毅 , 韩正玉 , 武晓雅 , 翁景霞 , 林璐

中国稀土学报 doi:10.11785/S1000-4343.20130408

采用溶胶-凝胶法制备Li+掺杂改性的Y2SiO5:Pr3+上转换发光材料,考察了Li+掺杂对样品晶型及发光性能的影响.采用XRD,DSC-TGA,FS对所制备的材料进行表征,结果表明Li+掺入浓度在7%~ 8%(摩尔分数)之间会引起Y2SiO5晶体类型由X型转变为X2型,且Li+掺入后样品转晶型温度由950℃降至800℃;样品经800℃煅烧处理后以X1型Y2SiO5为主相,850℃煅烧处理后以X2型Y2SiO5为主相;Li+掺入同时会提高Y2SiO5:Pr3+材料的上转换发光强度,Li+最佳掺杂浓度为10%,对于双掺杂pr3+,Li+:Y2SiO5体系中pr3+最佳掺杂浓度为1.2%.

关键词: 溶胶-凝胶法 , 上转换 , 晶相转变 , 锂掺杂 , 稀土

Y 对8090Al-Li 合金拉伸性能和断裂行为的影响

桂全红 , 马禄铭 , 蒋晓军 , 梁国军 , 李依依

材料研究学报

研究了两种不同Y 含量对8090Al-Li 合金拉伸性能及断裂行为的影响。实验表明:加入0.1wt-%Y 可在不降低强度的情况下提高合金的塑性,加入0.5wt-%Y 可在不降低塑性的情况下提高合金的强度。在峰值时效条件下,不加Y 的合金断裂为穿晶韧窝型和沿晶塑性混合方式,并伴有沿晶二次裂纹,加0.1%Y 不改变合金断裂模式,但使沿晶成分减少;加0.5%Y 合金则发生快速剪切断裂。本文从晶粒结构角度对断裂行为提出了解释。

关键词: A—Li 合金 , rare earth element Y , tensile properties , intergranular fracture , transgranular fracture

添加Y对Mg-3.5%Li合金冲击变形行为的影响

沙桂英 , 刘翠云 , 刘腾 , 孙晓光 , 李根

材料工程 doi:10.3969/j.issn.1001-4381.2010.07.014

利用Hopkinson压杆技术对Mg-3.5%Li及Mg-3.5%Li-0.77%Y合金在不同应变率下进行了冲击压缩实验,分析了两种合金的动态应力-应变行为及其应变率效应.结果表明,随应变率提高,Mg-3.5%Li合金的应力-应变行为表现出应变率强化效应与应变率弱化效应的双重特性.添加稀土元素Y后,合金有所强化,但其应力-应变行为仍具有应变率弱化效应,随应变率提高产生的微裂纹引起的内部损伤是导致合金应变率弱化效应的主要原因.

关键词: Mg-Li合金 , Mg-Li-Y合金 , 应变率 , 微裂纹

热电池阳极Li-B合金放电前后的微观特征

刘志坚 , 段伟 , 黄英华 , 李志友 , 曲选辉

功能材料

使用扫描电子显微境对放电前后的Li-B合金的微观特征进行了观察,对影响Li-B合金放电稳定性的主要因素进行了分析.结果表明,轧制后的Li-B合金为塑性好的Li包裹脆性的LiB粒子,在520℃放电后Li-B合金与电解质界面依然完整,在大电流(200mA/cm)短时间(12min)放充电后,金属锂被LiB和电解质分割,表现在断口上金属锂为细丝状.

关键词: 热电池 , Li-B合金 , 阳极

Mechanism of upconversion emission enhancement in Y(3)Al(5)O(12):Er(3+)/Li(+) powders

稀土学报(英文版)

Er(3+) and Li(+) codoped Y(3)Al(5)O(12) (YAG) powders were prepared for a systematic investigation of their upconversion emissions. X-ray diffraction (XRD), upconversion emission spectra, pump power dependence, FT-IR spectra and decay time were studied to characterize the samples. With Li+ doping, the upconversion emission intensity of Er(3+) doped YAG powders was obviously enhanced, accompanied with an increase in the ratio of green to red intensity. The enhancement of emission intensity could be attributed to two mechanisms: one was the distortion of local crystal field around Er(3+), and the other was the decrease in the amount of CO(3)(2-) and OH(-) groups. Our results revealed that the latter was the dominant mechanism of the upconversion intensity enhancement in the YAG:Er(3+)/Li(+) powders.

关键词: luminescence;optical materials and properties;sol-gel preparation;nanomaterials;rare earths;nanocrystals;nanophosphors;li+

Mg-12Li-3Gd-3Y-0.6Zr镁合金的均匀化研究

冯剑 , 黄金亮 , 贾玉鑫

兵器材料科学与工程

为改善铸态Mg-12Li-3Gd-3Y-0.6Zr合金的力学特性,对铸锭进行均匀退火处理。采用金相显微镜、SEM、XRD、显微硬度测试和拉伸力学特性测试,观察和研究了试验合金的微观组织和力学特性。结果表明:最佳的均匀化退火工艺为500℃×8 h,均匀化退火后合金的抗拉强度由铸态的114 MPa提高到133 MPa。第二相形态及分布的改变是Mg-12Li-3Gd-3Y-0.6Zr合金力学特性改变的主要原因。

关键词: 镁锂合金 , 均匀化 , 微观组织 , 力学特性

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