{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用改进的柠檬酸络合法合成了Ce-Al-O两相氧化物,并运用X射线衍射、X射线光电子<span style=\"color:red\">能</span>谱、27A1魔角核磁、N2吸附-脱附和储氧量测定等手段对样品进行了表征.结果表明,两相共生时CeO2和γ-Al2O3间发生了强相互作用,相互调变了彼此的存在状态和微观结构,抑制了两物相晶粒的长大,从而提高了γ-Al2O3的高温水热老化稳定性,并使Ce-A1-O体系两相氧化物的储氧能力比单相的纳米CeO2提高了2～3倍,即使在高温水热处理后样品仍保持很高的储氧性能.","authors":[{"authorName":"李斌","id":"794b714f-d5f1-4d44-b524-28d00f9c8f05","originalAuthorName":"李斌"},{"authorName":"<span style=\"color:red\">李</span>士杰","id":"0406abf8-b707-4ea0-aead-6f2fcf241e4c","originalAuthorName":"李士杰"},{"authorName":"王颖霞","id":"b79a9eb0-6861-491d-9905-156aac14d96a","originalAuthorName":"王颖霞"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"d287caa9-0a78-4a89-9ff5-fe001ae19f44","originalAuthorName":"李能"},{"authorName":"张婉静","id":"765f6aa1-ec24-400a-a4ab-b99d94fb3de4","originalAuthorName":"张婉静"},{"authorName":"林炳雄","id":"d18fb83c-dbf4-44bb-81ad-cf71b28de79e","originalAuthorName":"林炳雄"}],"doi":"10.1016/S1872-2067(09)60067-X","fpage":"528","id":"75aefdb1-26f1-45cb-a530-fe0d8c7138f7","issue":"5","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"5b6f34a6-18a3-4395-8744-fdc667bef7cc","keyword":"氧化铈","originalKeyword":"氧化铈"},{"id":"3e172e84-9271-4fcd-a926-a9566c99fd88","keyword":"氧化铝","originalKeyword":"氧化铝"},{"id":"811ebb25-9738-4f5c-a536-2974bd611d52","keyword":"两相共生共存","originalKeyword":"两相共生共存"},{"id":"f7637c19-71e8-43dd-96c9-d150c07b20c7","keyword":"强相互作用","originalKeyword":"强相互作用"},{"id":"30a9a07e-b973-464c-b72b-35232db7cb11","keyword":"晶格畸变","originalKeyword":"晶格畸变"},{"id":"17897ad2-1bd4-4b11-aa70-ce05df6f57e7","keyword":"水热稳定性","originalKeyword":"水热稳定性"},{"id":"df38d8b1-18ff-408f-abed-d1bfa253d4cb","keyword":"储氧能力","originalKeyword":"储氧能力"}],"language":"zh","publisherId":"cuihuaxb201005007","title":"CeO2和γ-Al2O3混合氧化物的共生共存效应","volume":"31","year":"2010"},{"abstractinfo":"利用GH4169合金粉末进行激光快速成形实验,制备出GH4169合金块状试样,并进行固溶时效热处理.利用扫描电镜(SEM)及<span style=\"color:red\">能</span>谱分析(EDS)等方法分别对激光成形沉积态及固溶时效态试样进行显微组织及元素偏析分析,并测试显微硬度、室温及高温拉伸性能.结果表明:沉积态微观组织为生长方向不一的细长柱状树枝晶,组织细小致密;经过固溶时效热处理后晶粒得到细化,晶粒内部仍保留枝晶亚结构;固溶时效态试样较沉积态显微硬度及抗拉强度大幅提高,塑性有所下降,但整体优于锻件技术标准.断口形貌表现为韧性穿晶断裂方式.","authors":[{"authorName":"杜博睿","id":"f3264473-ca4f-4125-8220-a3fe2cf5741f","originalAuthorName":"杜博睿"},{"authorName":"张学军","id":"db5cfb30-110b-497c-a6f8-29fa5ca16d1a","originalAuthorName":"张学军"},{"authorName":"郭绍庆","id":"507562f5-1fda-4736-af5f-006dee9c1d93","originalAuthorName":"郭绍庆"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"60419ec5-b9ae-4c60-a5b9-981c023f86b8","originalAuthorName":"李能"},{"authorName":"孙兵兵","id":"9ae1142b-a51e-4d0f-b587-b96f3c98153f","originalAuthorName":"孙兵兵"},{"authorName":"唐思熠","id":"e0c03d3a-43d3-437f-92a3-f608516f6d30","originalAuthorName":"唐思熠"}],"doi":"10.11868/j.issn.1001-4381.2014.001258","fpage":"27","id":"5eeff213-2850-41b1-96f0-f4078e4e631c","issue":"1","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"55fb31fd-7ac8-49fe-8944-d48e624e6472","keyword":"激光快速成形","originalKeyword":"激光快速成形"},{"id":"e8a8efe7-f02e-4480-b34d-b844c8fffe5e","keyword":"GH4169","originalKeyword":"GH4169"},{"id":"fba5ef5d-e428-4b74-b15b-2365d11c38cb","keyword":"显微组织","originalKeyword":"显微组织"},{"id":"5ee94c09-b02e-486f-adf5-022e57910326","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"clgc201701005","title":"激光快速成形GH4169合金显微组织与力学性能","volume":"45","year":"2017"},{"abstractinfo":"对0Cr15Ni5Cu4Nb沉淀硬化不锈钢焊接接头进行四种不同时效热处理,并研究了时效热处理对焊接接头力学性能的影响.结果表明,随着时效热处理温度提高或时效时间的延长,接头的冲击韧度、伸长率和断面收缩率增加,抗拉强度和屈服强度下降,接头断口形貌由准解理向韧窝过渡.550℃/4h时效处理后的焊接接头具有比较好的综合性能,抗拉强度为1071MPa,冲击韧度为283 J/cm2,均不低于母材的95％.","authors":[{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"40cdaf5f-e3db-4098-948f-2b0741302eb0","originalAuthorName":"李能"},{"authorName":"郭绍庆","id":"e5ec94ec-1801-484f-9611-6cdd9103c2a0","originalAuthorName":"郭绍庆"},{"authorName":"周标","id":"86145056-9cf3-4902-af17-405e3c7c22cd","originalAuthorName":"周标"},{"authorName":"孙兵兵","id":"c4c8022b-521a-4b40-af4e-54c74c27ed5b","originalAuthorName":"孙兵兵"},{"authorName":"张学军","id":"d53cee53-2020-47e7-acf3-ad3ff11e76ca","originalAuthorName":"张学军"},{"authorName":"张文扬","id":"c3d9267f-1ebe-406b-8899-d26095e3e85b","originalAuthorName":"张文扬"},{"authorName":"唐思熠","id":"0d3c91b0-66c3-46ed-a388-49778fad5801","originalAuthorName":"唐思熠"}],"doi":"10.3969/j.issn.1005-5053.2012.4.007","fpage":"38","id":"a0a23e64-3e54-4039-8e8b-3933ed4282be","issue":"4","journal":{"abbrevTitle":"HKCLXB","coverImgSrc":"journal/img/cover/HKCLXB.jpg","id":"41","issnPpub":"1005-5053","publisherId":"HKCLXB","title":"航空材料学报"},"keywords":[{"id":"28867787-ff4c-42b3-a672-6966fba94d72","keyword":"马氏体沉淀硬化不锈钢","originalKeyword":"马氏体沉淀硬化不锈钢"},{"id":"e3fc18a9-eeb0-475c-9663-188a93f4d410","keyword":"焊接接头","originalKeyword":"焊接接头"},{"id":"9bba9b73-c55c-42eb-bf08-1fd0b2b42059","keyword":"时效热处理","originalKeyword":"时效热处理"},{"id":"1e5cd81b-f697-454b-942e-f9df604ef715","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"hkclxb201204007","title":"时效处理对0Cr15Ni5Cu4Nb钢焊接接头力学性能的影响","volume":"32","year":"2012"},{"abstractinfo":"本文首先简要介绍了3D打印技术的基本原理及分类,然后重点介绍了有关金属材料3D打印的几种方法:电子束熔化成形(EBM)、激光选区熔化成形(SLM)、激光快速成形技术(LDMD).简述了金属材料3D打印的应用领域及国内外发展情况及研究现状.文章最后结合国内外金属材料3D打印的研究现状,指出金属材料3D打印需要在打印用粉末、金属3D打印设备、3D打印零件无损检测方法、3D打印零件的失效行为和寿命预测等方面进行重点研究,并建立3D打印零件的无损检测标准规范以及3D打印材料全面力学性能数据库.","authors":[{"authorName":"张学军","id":"66a5ad19-5f7a-4d97-9208-584cc928699b","originalAuthorName":"张学军"},{"authorName":"唐思熠","id":"f6934dee-f501-4980-b6c0-d89920b89ac8","originalAuthorName":"唐思熠"},{"authorName":"肇恒跃","id":"2fca9adb-8667-470f-adb5-c5cc29c5deae","originalAuthorName":"肇恒跃"},{"authorName":"郭绍庆","id":"3914adc0-5870-433a-a5c3-918b22cf88dd","originalAuthorName":"郭绍庆"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"9ed899a0-e8c5-4a38-8b90-fbad204fda7c","originalAuthorName":"李能"},{"authorName":"孙兵兵","id":"3355c4bd-616c-40f5-8907-c8b86711ef6f","originalAuthorName":"孙兵兵"},{"authorName":"陈冰清","id":"e31c15da-d8f2-45d0-bb32-8cf5bf480ab2","originalAuthorName":"陈冰清"}],"doi":"10.11868/j.issn.1001-4381.2016.02.019","fpage":"122","id":"101da83a-03c4-43d5-8baf-75d71df08997","issue":"2","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"1552c8e1-0178-4cd8-b206-f4f4f67df090","keyword":"3D打印","originalKeyword":"3D打印"},{"id":"d4ae4403-a61e-4aa4-8c88-a1fd18c3af4b","keyword":"增材制造","originalKeyword":"增材制造"},{"id":"08488c78-f6c9-4699-8061-ba3a959be5a6","keyword":"金属材料","originalKeyword":"金属材料"}],"language":"zh","publisherId":"clgc201602019","title":"3D打印技术研究现状和关键技术","volume":"44","year":"2016"},{"abstractinfo":"采用XMH-160型线性摩擦焊机焊接TC4钛合金板材,观察了焊接接头形貌及焊缝组织,测试了焊接接头的力学性能.结果表明,TC4钛合金适于采用线性摩擦焊接,焊接接头的室温拉伸性能、冲击韧性和高周疲劳性能不低于母材.其线性摩擦焊接头大致可以分为焊缝区和塑性变形区两个区域,焊缝区域原始组织被破碎,晶粒细小；塑性变形区域原始片层组织被压扁拉长,与焊接振动方向呈近平行的流线状.","authors":[{"authorName":"张学军","id":"882036ac-6c35-423e-a574-a68d7b6241d9","originalAuthorName":"张学军"},{"authorName":"马铁军","id":"76a1f8ef-6a02-4bb1-ad2a-8e9f69643782","originalAuthorName":"马铁军"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"832c32b5-1346-4f77-aa84-a85012b5b264","originalAuthorName":"李能"},{"authorName":"刘文慧","id":"e8304e3a-aa89-4dd8-9408-872c84cd6ced","originalAuthorName":"刘文慧"}],"doi":"10.3969/j.issn.1009-9964.2012.04.008","fpage":"26","id":"72e6110e-665a-4a22-9323-b246f1308350","issue":"4","journal":{"abbrevTitle":"TGYJZ","coverImgSrc":"journal/img/cover/TGYJZ.jpg","id":"60","issnPpub":"1009-9964","publisherId":"TGYJZ","title":"钛工业进展"},"keywords":[{"id":"3fc4d1a0-4871-41e3-84a1-474fa0a7763e","keyword":"钛合金","originalKeyword":"钛合金"},{"id":"5523f91d-40e7-4e00-832e-1d2daa4f7c71","keyword":"线性摩擦焊","originalKeyword":"线性摩擦焊"},{"id":"44cf1c59-f96a-4b1b-a8e3-3d44a8afbdad","keyword":"组织","originalKeyword":"组织"},{"id":"da709ae3-ffcf-4327-8622-9e2cebfb3e8e","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"tgyjz201204008","title":"TC4钛合金线性摩擦焊接头组织及性能研究","volume":"29","year":"2012"},{"abstractinfo":"用XRD,N2吸附,NH3-TPD和Py-IR等手段对REHY分子筛进行了表征,并通过多晶XRD法测定了稀土离子在Y分子筛骨架外的分布. 结果表明,在含水条件下,定位于Y型分子筛β笼SⅠ′位的RE3+与骨架氧及定位于SⅡ′位的H2O配位,稳定了分子筛的骨架,减少了分子筛酸性中的最强酸部分;定位的RE3+通过极化定位的配位水,增加了分子筛的中强酸,减缓了RE3+取代H+所引起的酸量下降. 从结构测定可推测出,在FCC催化剂中Y型分子筛上RE3+的最佳量应为每个晶胞含11个稀土离子,并完全定位于β笼的SⅠ′位.","authors":[{"authorName":"李斌","id":"18919631-8063-4851-97d7-61fd5cdf0304","originalAuthorName":"李斌"},{"authorName":"<span style=\"color:red\">李</span>士杰","id":"ff0192c4-7256-41d9-85c1-fbb6101146f9","originalAuthorName":"李士杰"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"154b7182-a358-4347-83db-997df959a210","originalAuthorName":"李能"},{"authorName":"刘从华","id":"4fa515eb-3679-4b26-8844-5471e729fb0a","originalAuthorName":"刘从华"},{"authorName":"高雄厚","id":"9284a070-71b4-4388-9382-175664167286","originalAuthorName":"高雄厚"},{"authorName":"庞新梅","id":"d46eb979-e862-472b-a00a-2d204c67ce40","originalAuthorName":"庞新梅"}],"doi":"","fpage":"301","id":"75e51b4d-9815-484e-b80a-c0d134314c4f","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"2657e3e5-7f05-42de-9006-5f1af11cc51b","keyword":"流化催化裂化催化剂","originalKeyword":"流化催化裂化催化剂"},{"id":"5defb2d2-2fbc-4066-aab4-3b157532eb03","keyword":"稀土","originalKeyword":"稀土"},{"id":"1d2d70cb-1d3c-4bda-b52b-e8e437b1daa1","keyword":"HY分子筛","originalKeyword":"HY分子筛"},{"id":"d4d65ea2-512f-46a4-96be-12917549a914","keyword":"酸性","originalKeyword":"酸性"},{"id":"cf5c1a68-4e95-4b75-ab98-1c668b3953c6","keyword":"结构","originalKeyword":"结构"},{"id":"744478bc-3bca-402d-b260-87361759e4ea","keyword":"稀土离子位置","originalKeyword":"稀土离子位置"}],"language":"zh","publisherId":"cuihuaxb200504011","title":"FCC催化剂中REHY分子筛的结构与酸性","volume":"26","year":"2005"},{"abstractinfo":"以柠檬酸络合法制备了CuCrO2和CuCr2O4两相共生的Cu-Cr-O催化剂体系. 由于两相共生而相互作用,两相组成的样品中,样品颗粒较小,比表面积增大,催化CO-O2反应的活性提高. 当样品中n(Cu)/n(Cr)=0.7时,两相含量最为接近,显示出最高的催化活性. CO-O2反应过程中,气相中的CO与样品表面的氧原子作用. 在两相共生而相互作用的过程中,CuCrO2和CuCr2O4的体相结构没有变化. 各样品催化活性的不同是由其表面性质的差异引起的. TPR和XPS分析结果表明: 两相共生而相互作用,修饰了样品的表面性质,使样品表面含有更多的活性氧,提高了样品的催化活性.","authors":[{"authorName":"赵峰","id":"dfb87473-e449-4a9d-8df2-a17bfeeb0568","originalAuthorName":"赵峰"},{"authorName":"<span style=\"color:red\">李</span>国英","id":"7004d336-8ef5-4ce6-b66f-fe4a0bd238da","originalAuthorName":"李国英"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"6197b967-b2f9-43e4-8fc0-620d5d52220f","originalAuthorName":"李能"},{"authorName":"刘英骏","id":"32e00938-8d47-4b97-8ad0-69389554d3c1","originalAuthorName":"刘英骏"},{"authorName":"林炳雄","id":"1c2cc34d-8c1f-497b-9f3c-fbaac1a1b885","originalAuthorName":"林炳雄"}],"doi":"","fpage":"11","id":"de9a0671-b2dd-481c-9443-8ec61164fed1","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"a67b7553-f4cc-4660-8408-7af4f898f432","keyword":"一氧化碳","originalKeyword":"一氧化碳"},{"id":"8c6f00ab-1513-4ad7-83bb-0314590390a3","keyword":"燃烧反应","originalKeyword":"燃烧反应"},{"id":"99ba951d-d4ea-42ad-b62a-bf5949747518","keyword":"铜","originalKeyword":"铜"},{"id":"2024c249-6fb2-419d-a1fa-331915c6644d","keyword":"铬","originalKeyword":"铬"},{"id":"152437c3-fbe6-4ce7-b7d4-34efd4f8dd8e","keyword":"复合氧化物","originalKeyword":"复合氧化物"},{"id":"4f0c5902-10af-405d-acbb-f41fa3a10eba","keyword":"程序升温还原","originalKeyword":"程序升温还原"},{"id":"1cd69733-c8b4-4f05-a8c8-c8d1584442a6","keyword":"两相相互作用","originalKeyword":"两相相互作用"},{"id":"f4e3008b-d240-46d2-a313-360f614c88f2","keyword":"金属载体强相互作用","originalKeyword":"金属载体强相互作用"}],"language":"zh","publisherId":"cuihuaxb200301005","title":"CuCrO2和CuCr2O4间相互作用对体系结构及催化性能的影响","volume":"24","year":"2003"},{"abstractinfo":"以浸渍法制备了α-Al2O3负载的含钯La0.9Sr0.1CoO3-δ钙钛矿样品,探讨了水热老化对样品催化CO-NO反应性能的影响,并以XRD,TPR和XPS等对样品在水热老化前后的结构进行了表征. 结果表明,钯的引入方式直接影响样品的水热性能. 掺钯样品(LaSrCoPd)具有良好的水热性能,经水热老化后,其催化活性显著提高,显示出最好的催化性能; 样品中钯离子位于钙钛矿晶相内,形成α-Al2O3负载的La0.9Sr0.1Co0.95Pd0.05O3-δ. La0.9Sr0.1CoO3-δ/α-Al2O3负载钯的样品(Pd/LaSrCo)具有最高的初活性,但经水热老化后,其催化活性明显降低. 在水热老化过程中,La0.9Sr0.1CoO3-δ钙钛矿的结构稳定,但含钯钙钛矿晶相中的钯离子迁移聚集成独立的PdO颗粒,较小的PdO颗粒聚集成较大的颗粒. 水热老化后,Pd/LaSrCo样品表面裸露的钯原子数目减少,导致其催化活性降低; 而LaSrCoPd样品表面裸露的钯原子数目增多,导致其催化活性升高.","authors":[{"authorName":"赵峰","id":"bc7586a0-e84d-4508-9362-75241396526f","originalAuthorName":"赵峰"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"e334c891-6c51-4abd-a212-d355b1977fc2","originalAuthorName":"李能"},{"authorName":"<span style=\"color:red\">李</span>国英","id":"86f04a0d-95ba-4717-a711-633d901dafee","originalAuthorName":"李国英"},{"authorName":"刘希尧","id":"f1945b6d-d644-4fc9-9f52-871f8abad920","originalAuthorName":"刘希尧"},{"authorName":"<span style=\"color:red\">李</span>士杰","id":"3792267c-d157-4dea-b724-d292385ecceb","originalAuthorName":"李士杰"},{"authorName":"林炳雄","id":"fe57e969-8085-48de-9898-c718228db572","originalAuthorName":"林炳雄"}],"doi":"","fpage":"525","id":"dec96396-d086-45a9-86fa-cf017d6d7fb0","issue":"7","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"035cfec3-c179-45c6-a53c-a10127952af5","keyword":"钙钛矿","originalKeyword":"钙钛矿"},{"id":"53f8d2db-69d5-4ede-bffb-ab87ab14a9f2","keyword":"钯","originalKeyword":"钯"},{"id":"9023e90a-afae-4f6b-b13f-ec64c2a3d339","keyword":"水热老化","originalKeyword":"水热老化"},{"id":"ce2c9423-ac5d-4b08-9738-319bc4a1a28e","keyword":"催化活性","originalKeyword":"催化活性"},{"id":"f13d2f87-67db-4346-b144-36b8b37e4523","keyword":"一氧化碳","originalKeyword":"一氧化碳"},{"id":"bd112bd2-e0c8-497c-b4cc-9b600ea9ca4a","keyword":"一氧化氮","originalKeyword":"一氧化氮"}],"language":"zh","publisherId":"cuihuaxb200307011","title":"水热老化对含钯La0.9Sr0.1CoO3-δ/α-Al2O3催化性能的影响","volume":"24","year":"2003"},{"abstractinfo":"采用XRD,NH3-TPD,FT-IR和MAS NMR等表征技术和甲醇脱水探针反应研究了含氟复合模板剂体系对Hβ沸石酸性的影响.与单四乙基溴化铵模板剂体系相比,含氟复合模板剂中的氟离子使铝更易于进入β沸石骨架,提高了沸石的总酸量、B酸/L酸比及强酸/弱酸比,使沸石表现出强的B酸酸性.","authors":[{"authorName":"祁晓岚","id":"3560e2c6-719a-4f04-a530-2e58fcbdfa00","originalAuthorName":"祁晓岚"},{"authorName":"<span style=\"color:red\">李</span>士杰","id":"5da4d75d-140b-45a4-918e-58712825b668","originalAuthorName":"李士杰"},{"authorName":"李斌","id":"2b6673e3-9aca-4cd1-8080-6d8ef329b74c","originalAuthorName":"李斌"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"66300584-a4e5-4aa4-a10f-644759af094d","originalAuthorName":"李能"},{"authorName":"刘希尧","id":"c2e4acec-97df-44e8-91fd-6f9f4b3dfb22","originalAuthorName":"刘希尧"},{"authorName":"林炳雄","id":"81f4a911-74ae-4760-baf4-ecdf6cfb5ffa","originalAuthorName":"林炳雄"}],"doi":"","fpage":"163","id":"e1fedb40-eb68-4dbe-9075-f5162db723dd","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"e7d308a3-8c5d-405a-9c5a-493e0166cce7","keyword":"β沸石","originalKeyword":"β沸石"},{"id":"fb0bd5b0-67fd-4514-9390-b513cdcd8cf0","keyword":"氟离子","originalKeyword":"氟离子"},{"id":"2a76e76b-4a25-464d-a5cd-1fb5e8399700","keyword":"酸性","originalKeyword":"酸性"},{"id":"06057162-4942-4f6f-b010-60c69b086894","keyword":"复合模板剂","originalKeyword":"复合模板剂"},{"id":"a5873fde-9051-42ed-80ec-ca2714329ae0","keyword":"甲醇","originalKeyword":"甲醇"},{"id":"cb6b87fe-b7a5-4f6a-94ca-86f19e10def2","keyword":"脱水","originalKeyword":"脱水"}],"language":"zh","publisherId":"cuihuaxb200402019","title":"含氟复合模板剂体系对Hβ沸石酸性的影响","volume":"25","year":"2004"},{"abstractinfo":"通过多晶XRD利用Rietveld方法测定和精修了浸渍法制备的Mo/ZSM-5催化剂样品的物相和晶体结构. 结果表明,Mo物种在ZSM-5分子筛中以3种形式存在. 一种是以[Mo5O12]6+形式存在于ZSM-5分子筛的孔道内,每个分子筛晶胞中平均含0.4个[Mo5O12]6+单元. 这些单元覆盖了分子筛孔道内的部分B酸中心,使其B酸量及总酸量减少,但使L酸量增加; [Mo5O12]6+团中Mo的含量约占Mo/ZSM-5催化剂质量的3.03%. 其余的两种Mo物种分别以α-MoO3晶相和无定形氧化钼形式存在,修饰分子筛的外表面.","authors":[{"authorName":"李斌","id":"6c7e2c4a-deb1-4cab-ae3b-396d5befbc86","originalAuthorName":"李斌"},{"authorName":"陈会英","id":"79c62d78-1fe7-46e4-800d-ac32c6b7f29a","originalAuthorName":"陈会英"},{"authorName":"<span style=\"color:red\">李</span>士杰","id":"a26c28b1-23bd-44e2-8b8c-a2192d329e31","originalAuthorName":"李士杰"},{"authorName":"<span style=\"color:red\">李</span><span style=\"color:red\">能</span>","id":"2468d357-a7d9-441c-8e3d-d0df41c6db40","originalAuthorName":"李能"},{"authorName":"包信和","id":"6e2562d3-c7b9-4985-a186-94e75d3fdd58","originalAuthorName":"包信和"},{"authorName":"林炳雄","id":"0ba788ed-877a-4900-8fe6-51be05a8ccb1","originalAuthorName":"林炳雄"}],"doi":"","fpage":"769","id":"e3df8a4a-3d10-4022-9dba-473e9057b30e","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"c1e0ce83-6dae-48b3-b387-a18fe52b8a5f","keyword":"钼","originalKeyword":"钼"},{"id":"2249f1b1-6812-457c-9d0e-0f74ca2524c5","keyword":"ZSM-5分子筛","originalKeyword":"ZSM-5分子筛"},{"id":"a1069994-ea2c-4352-928c-e4d932b19d45","keyword":"浸渍法","originalKeyword":"浸渍法"},{"id":"c2e15e2a-9155-40d8-80da-5f62fa95cad1","keyword":"分布状态","originalKeyword":"分布状态"}],"language":"zh","publisherId":"cuihuaxb200509011","title":"浸渍法制备的Mo/ZSM-5催化剂中Mo的分布状态","volume":"26","year":"2005"}],"totalpage":2235,"totalrecord":22347}