{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"可调谐二极管激光吸收光谱(TDLAS)技术是利用二极管激光器的波长调谐特性,获得被选定的待测气体特征吸收线的吸收光谱,从而对污染气体进行定性或者定量分析.在大气痕量气体和气体泄漏的监测中,为了提高探测的灵敏度,一般会根据具体情况对激光器采取不同的调制技术如波长调制、振幅调制、频率或者位相调制等,同时和长光程吸收池相结合使用,并辅之以各种噪声压缩技术.TDLAS不仅精度较高,选择性强而且响应速度快,已经广泛用于大气中多种痕量气体的检测以及地面的痕量气体和气体泄漏的检测.报道了最近研制的一套可调谐二极管激光吸收光谱检测大气中甲烷浓度的实验装置,这套装置具有灵敏度高、检测限低(ppb量级)、易于集成为便携式痕量气体检测仪等优点,若激光器的调谐波长范围能覆盖1.3～1.8 μm或者在光路中装配几台窄范围可调谐激光器实现波长扫描范围覆盖1.3～1.8μm,则可同时实现对大气中诸多重要痕量气体如CO2、CH4、CO、CH2O、H2S、NH3、HCI、C2H2等的同步监测.","authors":[{"authorName":"董凤忠","id":"7aa8d93e-3d0d-4a5b-9180-12a1de228a01","originalAuthorName":"董凤忠"},{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"e3d3323a-f285-4134-b8cf-6ef4eaa8d397","originalAuthorName":"阚瑞峰"},{"authorName":"刘文清","id":"421a7ffd-d510-4efb-bcd9-9f3bb99234b4","originalAuthorName":"刘文清"},{"authorName":"刘建国","id":"aad0461e-2d14-4193-9062-54d322de8770","originalAuthorName":"刘建国"},{"authorName":"张玉钧","id":"627c1ecd-0d93-4ead-9d54-d10e1d299711","originalAuthorName":"张玉钧"},{"authorName":"高山虎","id":"fa00dae5-5acb-44c2-9b2e-2f1b91f28526","originalAuthorName":"高山虎"},{"authorName":"王铁栋","id":"21747ca8-44a4-404c-a0bc-2f3971982d14","originalAuthorName":"王铁栋"},{"authorName":"王敏","id":"fa376e09-f18c-44e3-af5b-6d8a1bf4661b","originalAuthorName":"王敏"},{"authorName":"陈东","id":"8ac54f57-26e0-452a-bd6f-2b655c868c1d","originalAuthorName":"陈东"},{"authorName":"魏庆农","id":"996696ee-355f-4a69-8755-ef2825564813","originalAuthorName":"魏庆农"}],"doi":"10.3969/j.issn.1007-5461.2005.03.002","fpage":"315","id":"263b6401-fddd-4feb-9870-008dd4214630","issue":"3","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"cec88f6e-fccf-417d-a449-9ffb2952845a","keyword":"光谱学","originalKeyword":"光谱学"},{"id":"96bcd4af-1236-4a2e-9936-67623edcdee3","keyword":"可调谐二极管激光","originalKeyword":"可调谐二极管激光"},{"id":"5e82dd6f-a935-4bbd-acfa-acb9325ef285","keyword":"怀特池","originalKeyword":"怀特池"},{"id":"f35a24b8-232b-4354-a863-f2f11a1e861d","keyword":"甲烷","originalKeyword":"甲烷"},{"id":"cbfb571d-bb79-4226-bb5d-d3e211ea3424","keyword":"大气质量监测","originalKeyword":"大气质量监测"}],"language":"zh","publisherId":"lzdzxb200503002","title":"可调谐二极管激光吸收光谱技术及其在大气质量监测中的应用","volume":"22","year":"2005"},{"abstractinfo":"甲烷是天然气和矿井瓦斯等多种气体燃料的主要成分,由于其易燃易爆的特性,瓦斯爆炸一直困扰着天然气站和煤矿的安全生产.可调谐半导体激光光谱(TDLAS)技术是近年来发展起来的一种新型的气体检测方法.它具有灵敏度高、精度高、选择性强、响应快速等突出特点.波长调制光谱(WMS)技术是TDLAS技术中一种重要技术.利用WMS技术检测在大气压下、浓度从0.04%至10%的甲烷气体的二次谐波(2f)信号,并证明了在该浓度范围内2f信号幅值正比于甲烷的浓度,为工业中甲烷气体的浓度监测提供了一种新的检测方法,并为集成甲烷监测仪器提供了理论及实验的依据.","authors":[{"authorName":"高山虎","id":"cc130299-7f1b-431c-83c2-aa298d5b8b87","originalAuthorName":"高山虎"},{"authorName":"刘文清","id":"d3721630-07cf-45a0-af1d-0d3e2fdb30c5","originalAuthorName":"刘文清"},{"authorName":"刘建国","id":"b1c88941-77b1-4a8b-b75c-f64ea56da4f4","originalAuthorName":"刘建国"},{"authorName":"张玉钧","id":"a513c217-877e-4433-9b40-8f3944667f7d","originalAuthorName":"张玉钧"},{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"9ada6fc5-e726-41ac-8794-bf93116d26b6","originalAuthorName":"阚瑞峰"},{"authorName":"王敏","id":"28a80f16-3127-43b9-860a-a71dee3ac9c3","originalAuthorName":"王敏"},{"authorName":"涂兴华","id":"90d9cba4-1276-4c56-a5b7-dc44511d12f5","originalAuthorName":"涂兴华"},{"authorName":"王铁栋","id":"5714a51d-999b-4868-a085-4c9a67a78e15","originalAuthorName":"王铁栋"}],"doi":"10.3969/j.issn.1007-5461.2006.03.023","fpage":"388","id":"5c682c87-b987-4913-bebf-e40d11541510","issue":"3","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"311b2eca-7db5-4d4b-b500-e4717ed2ccd7","keyword":"光谱学","originalKeyword":"光谱学"},{"id":"423478fc-bca3-47f4-8d29-d813a1e214de","keyword":"可调谐半导体激光光谱","originalKeyword":"可调谐半导体激光光谱"},{"id":"2b29fb9e-cb94-4f83-9414-74f5a9648167","keyword":"波长调制光谱","originalKeyword":"波长调制光谱"},{"id":"25d63724-f373-438e-bdf9-31da5c45e230","keyword":"二次谐波检测","originalKeyword":"二次谐波检测"}],"language":"zh","publisherId":"lzdzxb200603023","title":"可调谐半导体激光吸收光谱学测量甲烷的研究","volume":"23","year":"2006"},{"abstractinfo":"室温工作的连续可调谐相干光源在痕量气体检测技术中有着重要的应用价值,非线性差频方法是获得室温工作的中红外相干光源的有效途径,是对传统激光光源的重要补充.报道了一种基于差频方法的室温工作宽调谐中红外激光光谱系统,使用两台近红外半导体激光器作为种子光源,采用PPLN晶体作为非线性混频器件,结合准相位匹配技术实现了3.2～3.7μm中红外相干光源输出,最大差频输出功率约为1μW,对CH4基频吸收谱线的光谱检测表明,系统能够满足在中红外光谱区对气体成分进行高分辨、高灵敏、快速吸收检测的需要.","authors":[{"authorName":"陈东","id":"9ea7845a-e763-4b15-b1e6-b5126010ebf9","originalAuthorName":"陈东"},{"authorName":"刘文清","id":"875a3c1b-7948-4935-aac7-e5081ed853fc","originalAuthorName":"刘文清"},{"authorName":"张玉钧","id":"e4c5f978-c5f9-466b-bff3-59a3207aec3b","originalAuthorName":"张玉钧"},{"authorName":"刘建国","id":"883ab5e2-f7e2-42ad-9d6a-53f83440e210","originalAuthorName":"刘建国"},{"authorName":"崔小娟","id":"1486a09e-6de8-4036-bf3e-fb6610b56a2e","originalAuthorName":"崔小娟"},{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"fa88b4ad-648b-4a3d-9d53-0f1774fb88de","originalAuthorName":"阚瑞峰"},{"authorName":"王敏","id":"a04d261e-f2be-4879-8f34-7ae1d4ed160c","originalAuthorName":"王敏"},{"authorName":"夏慧","id":"c3c3d80c-e346-4064-894a-99ff15ebbccf","originalAuthorName":"夏慧"},{"authorName":"崔益本","id":"e2f38452-da07-488c-8c3c-2f46cbd886e2","originalAuthorName":"崔益本"}],"doi":"10.3969/j.issn.1007-5461.2008.01.002","fpage":"7","id":"bd308b0e-cfdd-419c-a5e3-25d2d52017bb","issue":"1","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"a8afd794-0563-459f-a981-d5ddc06ca164","keyword":"光谱学","originalKeyword":"光谱学"},{"id":"a47cfa7e-f10b-4726-800e-e6e3b03bcf68","keyword":"中红外","originalKeyword":"中红外"},{"id":"0df005a1-2fd2-44cc-9abd-8010a88dc416","keyword":"差频","originalKeyword":"差频"},{"id":"e2115c3a-3848-4257-827f-0443eb680a5a","keyword":"准相位匹配","originalKeyword":"准相位匹配"},{"id":"38355ea5-d33b-4c7d-b023-cff36b42d25d","keyword":"外腔调谐半导体激光器","originalKeyword":"外腔调谐半导体激光器"}],"language":"zh","publisherId":"lzdzxb200801002","title":"外腔调谐激光泵浦的差频中红外宽调谐激光光谱系统","volume":"25","year":"2008"},{"abstractinfo":"介绍了一种半导体激光器驱动系统,主要包括温度稳定控制电路、电流稳定控制电路和保护电路,给出了具体的参考电路.通过同时对激光器的工作电流及其温度进行精密控制,使得激光器能稳定工作.保护电路能在激光器工作过程中对其进行充分保护,防止激光器因误操作或其它因素发生损坏.实验表明,该驱动控制的激光器在恒温(室温)下工作80 min输出波长漂移不超过0.6 pm.外界环境温度10℃～50℃范围内,激光器输出波长漂移不超过16 pm.适用于对激光器稳定要求高的场合.","authors":[{"authorName":"曾利忠","id":"da30a2da-d883-47f2-89a8-05560300ba9e","originalAuthorName":"曾利忠"},{"authorName":"陆亦怀","id":"0eb1d90e-bbbd-4c44-b95e-ad23015e7b52","originalAuthorName":"陆亦怀"},{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"9b3e4ed2-a104-4a1d-9d22-3c1b30dc19f3","originalAuthorName":"阚瑞峰"},{"authorName":"王煜","id":"171eedf8-6e68-4440-b7fd-1a14826efee8","originalAuthorName":"王煜"},{"authorName":"姚路","id":"77350dab-539b-4a91-9874-56d57ee90d16","originalAuthorName":"姚路"},{"authorName":"许振宇","id":"a40c9c23-8bb0-4ca4-9f61-7ab07cf2bc52","originalAuthorName":"许振宇"},{"authorName":"阮俊","id":"8b867778-f5f0-493a-bbfd-63e7e5e4cca1","originalAuthorName":"阮俊"},{"authorName":"袁松","id":"f86729c3-573f-4304-8f4c-c99193d68e45","originalAuthorName":"袁松"},{"authorName":"张乐","id":"de5a1bb4-5b77-473a-aca5-d10049a38ae1","originalAuthorName":"张乐"}],"doi":"10.3969/j.issn.1007-5461.2014.05.009","fpage":"569","id":"b18fd369-2f0f-4b81-8f89-a08d26feab71","issue":"5","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"d2b1ac14-7f7a-47f3-8f7d-ff8ae033c144","keyword":"光电子学","originalKeyword":"光电子学"},{"id":"50cb3fbf-0c3e-47c3-bac3-4cdc7f359551","keyword":"可调谐半导体激光器","originalKeyword":"可调谐半导体激光器"},{"id":"79792a34-9112-46d4-a617-143976c54ad6","keyword":"驱动控制","originalKeyword":"驱动控制"},{"id":"6279099e-7a14-470a-a25b-afabefc2834c","keyword":"低温漂","originalKeyword":"低温漂"}],"language":"zh","publisherId":"lzdzxb201405009","title":"高稳定低温漂半导体激光器驱动的电子学设计","volume":"31","year":"2014"},{"abstractinfo":"为既能广泛用于稳定分子的研究又能用于瞬变物种研究的气相紫外光电子能谱仪设计了数据采集系统,应用Windows支持下的Visual C++6.0编程技术,编制了具有友好界面、操作简便的数据采集系统软件.数据采集系统利用Butterworth低通数字滤波器对采集到的数据进行处理,来消除高频的噪声提高信噪比.","authors":[{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"adb71c2d-5d5a-43d1-ae8d-d860869b2276","originalAuthorName":"阚瑞峰"},{"authorName":"车会娟","id":"ae224a8c-8372-4b88-b7b4-b05bce6201de","originalAuthorName":"车会娟"},{"authorName":"李益民","id":"d95c144d-71c3-4153-8c28-064b865d687e","originalAuthorName":"李益民"},{"authorName":"李海洋","id":"e581b5ed-55af-4557-927c-e0f8e069cdb2","originalAuthorName":"李海洋"},{"authorName":"王殿勋","id":"43f900d3-d5f5-4063-9fbd-cca1cda3158d","originalAuthorName":"王殿勋"}],"doi":"10.3969/j.issn.1007-5461.2003.06.007","fpage":"671","id":"38f68f36-07b8-447a-9e2a-976f83957d0e","issue":"6","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报   "},"keywords":[{"id":"fc23c827-adec-4b3c-bf60-b555f1a25ca9","keyword":"光电子能谱仪","originalKeyword":"光电子能谱仪"},{"id":"ad925bce-96fb-4f0a-9509-3e52d04a9bae","keyword":"数字滤波","originalKeyword":"数字滤波"},{"id":"efa7850a-d2b6-4ac2-b0e5-912ad46728cc","keyword":"数据采集(A/D)卡","originalKeyword":"数据采集(A/D)卡"},{"id":"4e84c0e2-f93c-427a-8799-13c04695aec4","keyword":"信噪比","originalKeyword":"信噪比"}],"language":"zh","publisherId":"lzdzxb200306007","title":"数字滤波技术在气相紫外光电子能谱仪数据采集中的应用","volume":"20","year":"2003"},{"abstractinfo":"建立了一套用于产生瞬变物种的脉冲放电超声分子束装置, 并以N2气为例, 对脉冲放电电压、相对于脉冲阀的时间延迟、放电频率以及气压等因素对发光特性的影响等进行了研究, 从转动谱线轮廓估算出分子束可将转动温度冷却在30 K以下. ","authors":[{"authorName":"张树东","id":"c811b370-e381-4ec4-b00b-2e47a88c2ae5","originalAuthorName":"张树东"},{"authorName":"罗晓林","id":"9ce89035-4924-42db-b3fe-3698bb667dad","originalAuthorName":"罗晓林"},{"authorName":"<span style=\"color:red\">阚</span><span style=\"color:red\">瑞</span><span style=\"color:red\">峰</span>","id":"44393825-0929-4ccf-b99c-6bf07ab9ec0f","originalAuthorName":"阚瑞峰"},{"authorName":"孔祥蕾","id":"96dcebb6-63e3-4a2b-96dd-09ae4a174f1a","originalAuthorName":"孔祥蕾"},{"authorName":"张伟","id":"32636270-d2f5-443d-be14-4e7e5ac48d32","originalAuthorName":"张伟"},{"authorName":"李海洋","id":"63ce2ee4-32b7-4b5a-8cb3-fa92c203891d","originalAuthorName":"李海洋"}],"doi":"10.3969/j.issn.1007-4627.2002.z1.033","fpage":"110","id":"47a4b892-4222-4f86-abeb-8f16fdb1d162","issue":"z1","journal":{"abbrevTitle":"YZHWLPL","coverImgSrc":"journal/img/cover/YZHWLPL.jpg","id":"78","issnPpub":"1007-4627","publisherId":"YZHWLPL","title":"原子核物理评论   "},"keywords":[{"id":"2e00b855-b9f9-4ccc-b483-0bfef2d2e41e","keyword":"脉冲分子束","originalKeyword":"脉冲分子束"},{"id":"0aee5376-1de1-4acf-ad80-f540b72fd72b","keyword":"超声冷却","originalKeyword":"超声冷却"},{"id":"d15f0033-1ed3-4352-b332-ffe1146d3f61","keyword":"发光特性","originalKeyword":"发光特性"}],"language":"zh","publisherId":"yzhwlpl2002z1033","title":"一个产生瞬变物种的脉冲放电/激光溅射分子束装置","volume":"19","year":"2002"},{"abstractinfo":"本研究采用静电喷雾法,以壳聚糖为基质材料,康普<span style=\"color:red\">瑞</span>丁为模型药物制备微球.实验中采用AcOH/H2O和AcOH/H2O/EtOH两种溶剂,分析了微球形貌和粒径分布的影响因素,并且对CS-CA4微球的缓释性能进行了测定.结果表明,壳聚糖浓度、溶剂配比及乙醇和康普<span style=\"color:red\">瑞</span>丁的加入会使壳聚糖微球呈球状、中间塌陷的类球状、棒状等不同形貌,微球粒径存在较大差异;通过AcOH/H2O/EtOH复合溶剂将疏水性药物康普<span style=\"color:red\">瑞</span>丁载入壳聚糖微球,制备出的壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球分散性好,粒径分布均匀,平均粒径仅为0.27μm;使用戊二醛蒸汽交联48h的微球缓释效果明显.","authors":[{"authorName":"马骊娜","id":"1199ac48-a9e3-4a3e-bb00-419a65ff9d7c","originalAuthorName":"马骊娜"},{"authorName":"方大为","id":"75d9368e-192b-4a88-9bec-9695b9fa8044","originalAuthorName":"方大为"},{"authorName":"王克敏","id":"c738f1c1-d104-410d-9f54-55b3dca5dc2e","originalAuthorName":"王克敏"},{"authorName":"聂俊","id":"a11a1f53-3fd7-45b4-9dec-4aff409c0f7b","originalAuthorName":"聂俊"},{"authorName":"马贵平","id":"ccd2cd48-646b-4ffd-95c6-9d59f1efb92a","originalAuthorName":"马贵平"}],"doi":"10.14136/j.cnki.issn 1673-2812.2015.06.023","fpage":"889","id":"e2dd295a-8366-4fe2-816d-1bd9aea9ed57","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"c0915753-d339-4bb7-84b4-fb27eec6936d","keyword":"静电喷雾","originalKeyword":"静电喷雾"},{"id":"84fb1809-9c50-47b3-b2b4-73df58a6cf63","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"242c9cf4-d5d8-4798-86a4-712f75491661","keyword":"康普<span style=\"color:red\">瑞</span>丁","originalKeyword":"康普瑞丁"},{"id":"7bcabc05-f355-4742-9b0c-d0599dbafa0a","keyword":"微球","originalKeyword":"微球"}],"language":"zh","publisherId":"clkxygc201506023","title":"静电喷雾法制备壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球","volume":"33","year":"2015"},{"abstractinfo":"在模拟人体生理条件下(pH=7.40),采用荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用.采用2种方法计算不同温度下其结合常数K<,A>、结合位点数n,同时对2种计算方法进行了比较;并根据热力学参数确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间的作用力类型.根据Forster非辐射能量转移原理,确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白相互结合时供能体-受能体间的作用距离和能量转移效率,并用同步荧光光谱研究了双醋<span style=\"color:red\">瑞</span>因对人血清白蛋白构象的影响.结果表明,双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间主要是以静态猝灭为主;结合距离r=2.88 nm,能量转移效率E=0.273 8,二者主要凭借氢键和范德华力进行结合.","authors":[{"authorName":"吕茜茜","id":"f12bfcef-2194-44f2-af18-bffaf338c1f1","originalAuthorName":"吕茜茜"},{"authorName":"高苏亚","id":"a30644da-e49a-4d36-afc7-e716115ce091","originalAuthorName":"高苏亚"},{"authorName":"夏冬辉","id":"d73ff043-6fa7-4f8d-a484-08e90b5cb087","originalAuthorName":"夏冬辉"},{"authorName":"李华","id":"64609acd-7353-4cf0-9b35-d68a7b42f516","originalAuthorName":"李华"}],"doi":"10.3724/SP.J.1095.2011.00497","fpage":"836","id":"c91df298-e5b8-4f97-a2e9-feb360f7f935","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"28c96fc8-c4c6-4273-a94a-5ba9464e0eba","keyword":"双醋<span style=\"color:red\">瑞</span>因","originalKeyword":"双醋瑞因"},{"id":"f2d384ae-ff9a-425a-840a-8f406b7729eb","keyword":"人血清白蛋白","originalKeyword":"人血清白蛋白"},{"id":"316e2743-ed10-4b2a-8872-69ab0668a364","keyword":"荧光光谱法","originalKeyword":"荧光光谱法"},{"id":"5a82aeaa-fe8e-49cc-972a-8fca5dd7381e","keyword":"相互作用","originalKeyword":"相互作用"}],"language":"zh","publisherId":"yyhx201107018","title":"荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用","volume":"28","year":"2011"},{"abstractinfo":"以具有22个不同种类手性中心的新型大环抗生素伊<span style=\"color:red\">瑞</span>霉素为手性选择器,基于环氧基团高反应活性的特征,将伊<span style=\"color:red\">瑞</span>霉素用一步法键合到甲基丙烯酸酯整体柱表面制备伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱.通过对制备条件进行优化,证实该制备方法可在较宽的pH范围(6.0～9.0)内进行,方法简单易行,反应条件温和.应用制备的手性毛细管整体柱在毛细管电色谱模式下,对5种手性氨基酸对映体和手性药物罗格列酮对映体进行拆分,均得到了基线分离,说明伊<span style=\"color:red\">瑞</span>霉素手性固定相具有较强的手性拆分能力.在优化的色谱条件下,6种对映体的分析时间均小于4 min,分析速度快.通过对有机调节剂、缓冲液pH值和缓冲盐浓度等分离条件进行系统考察,初步探讨了该手性毛细管整体柱对不同溶质的手性识别机理.","authors":[{"authorName":"雷雯","id":"f3112f13-31b3-48d4-8a3d-24941a9b5feb","originalAuthorName":"雷雯"},{"authorName":"张凌怡","id":"e0071825-4b94-4a3f-ba04-ba62050f2187","originalAuthorName":"张凌怡"},{"authorName":"万莉","id":"75b5c03d-49e1-4f6e-a59e-e4904e4e2b5f","originalAuthorName":"万莉"},{"authorName":"朱亚仙","id":"4f006e92-817c-4597-842f-7f801bd9dcb9","originalAuthorName":"朱亚仙"},{"authorName":"覃飒飒","id":"954f8ad8-ce48-40e5-bda6-e494c7fc375b","originalAuthorName":"覃飒飒"},{"authorName":"张维冰","id":"62dc267b-d4f0-467d-81ef-ecdbb1d66fda","originalAuthorName":"张维冰"}],"doi":"10.3724/SP.J.1123.2010.00977","fpage":"977","id":"8b0818de-0a05-43be-89a8-9aae5bf1adf3","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"ebde9186-14bb-48bb-a7b9-c54bb9bbfd44","keyword":"伊<span style=\"color:red\">瑞</span>霉素","originalKeyword":"伊瑞霉素"},{"id":"1f065bbb-c191-4889-88ec-8826a836e5d8","keyword":"大环抗生素","originalKeyword":"大环抗生素"},{"id":"f6bb8cb7-1144-4376-85ef-a81fdb8986f4","keyword":"手性整体固定相","originalKeyword":"手性整体固定相"},{"id":"303d37f9-7cd6-4218-8d88-b02ce6b5b5d8","keyword":"毛细管电色谱","originalKeyword":"毛细管电色谱"},{"id":"b90b4039-836a-4782-8b57-34e66b7c89e1","keyword":"对映体","originalKeyword":"对映体"}],"language":"zh","publisherId":"sp201010013","title":"伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱的制备与对映体分离","volume":"28","year":"2010"},{"abstractinfo":"用受迫振动法测量了夹角为60°和129.5°的铝双晶的内耗,都观测到一个温度内耗<span style=\"color:red\">峰</span>,峰巅温度是200℃左右(频率1Hz)激活能为0.88eV对于这个内耗<span style=\"color:red\">峰</span>的机制做了初步解释。","authors":[{"authorName":"关幸生","id":"8e7fa0a7-4b2b-43eb-ab0e-385b95cbfd10","originalAuthorName":"关幸生"},{"authorName":"葛庭燧","id":"67b972cc-f4c0-4797-9aed-85c45cb1ce80","originalAuthorName":"葛庭燧"}],"categoryName":"|","doi":"","fpage":"1","id":"2aff307d-21f5-4a68-a5ac-0b1cd08864dc","issue":"8","journal":{"abbrevTitle":"JSXB","coverImgSrc":"journal/img/cover/JSXB.jpg","id":"48","issnPpub":"0412-1961","publisherId":"JSXB","title":"金属学报"},"keywords":[{"id":"ed61f5ab-f338-42d9-b668-0b6a379c39fe","keyword":"铝双晶","originalKeyword":"铝双晶"},{"id":"36aafee6-63d2-4133-8924-6e4a2ec321a9","keyword":"grain boundary internal friction peak","originalKeyword":"grain boundary internal friction peak"},{"id":"10d06012-bca3-4f68-aa60-0d4f370bb37a","keyword":"activation enegry","originalKeyword":"activation enegry"}],"language":"zh","publisherId":"0412-1961_1993_8_5","title":"铝双晶晶界的内耗<span style=\"color:red\">峰</span>","volume":"29","year":"1993"}],"totalpage":653,"totalrecord":6528}