{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span><span style=\"color:red\">四乙烯基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(Vi-D4)为有机<span style=\"color:red\">硅</span>单体,在乳液体系中开环聚合得到有机<span style=\"color:red\">硅</span>中间体,采用种子乳液聚合工艺,与丙烯酸单体共聚得到高<span style=\"color:red\">硅</span>含量的<span style=\"color:red\">硅</span>丙乳液.研究了体系的pH、加料方式、乳化剂的用量、引发剂的用量对乳液聚合稳定性的影响,发现Vi-D4在pH =3下开环聚合,引发剂用量为单体总量的0.4％,且其配比为3∶2,乳化剂的用量为3％,控制丙烯酸有机<span style=\"color:red\">硅</span>中间体的滴加时间分别为2h和3h制得的乳液稳定性高.","authors":[{"authorName":"杨震","id":"0e13c8f2-3fb2-44e6-b876-df19a5420b12","originalAuthorName":"杨震"},{"authorName":"卿宁","id":"ce8a3b94-fc55-4f09-ab1c-c8de29e284af","originalAuthorName":"卿宁"}],"doi":"10.3969/j.issn.0253-4312.2012.03.008","fpage":"32","id":"4fafdf54-3546-4a90-8b7c-e4cd3cdee3cf","issue":"3","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"c65a5e07-2071-4587-9d67-203670803e25","keyword":"<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span><span style=\"color:red\">四乙烯基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"四甲基四乙烯基环四硅氧烷"},{"id":"b0cee92f-9e7c-4bd0-9bd2-777a8698e27b","keyword":"聚合稳定性","originalKeyword":"聚合稳定性"},{"id":"aed89af0-c5a6-4bde-88b9-3188643cd726","keyword":"<span style=\"color:red\">硅</span>丙乳液","originalKeyword":"硅丙乳液"},{"id":"83f6daea-869f-4dda-8b9c-1d76c1892c8b","keyword":"高<span style=\"color:red\">硅</span>含量","originalKeyword":"高硅含量"}],"language":"zh","publisherId":"tlgy201203008","title":"高<span style=\"color:red\">硅</span>含量<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>甲<span style=\"color:red\">乙烯基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>改性丙烯酸酯乳液的聚合稳定性","volume":"42","year":"2012"},{"abstractinfo":"以八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(D4)为主链剂,<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>二<span style=\"color:red\">乙烯基</span>二<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(MM)为封端剂,用碱催化平衡法合成<span style=\"color:red\">乙烯基</span>聚二<span style=\"color:red\">甲基硅氧烷</span>(V-PDMS),探讨了影响合成反应及产物分子量、<span style=\"color:red\">乙烯基</span>含量(Vi%)的主要因素,并对合成的V-PDMS进行精制处理.","authors":[{"authorName":"胡友慧","id":"065075a0-31d6-4d43-8656-831e0f45b834","originalAuthorName":"胡友慧"},{"authorName":"许新社","id":"8e4f5665-f8a0-4bce-81c4-afd7e51f661f","originalAuthorName":"许新社"}],"doi":"","fpage":"67","id":"fcd5cc8d-d74b-4a6a-915b-fc06931a0c85","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4a5fd6ea-14db-47f3-b7a3-62c00f2280c8","keyword":"<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>二<span style=\"color:red\">乙烯基</span>二<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"四甲基二乙烯基二硅氧烷"},{"id":"9cdb9cf2-f4d0-406f-bd98-1af50ce67992","keyword":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"八甲基环四硅氧烷"},{"id":"7dab883f-6436-41e7-a444-4a1ad89ee297","keyword":"聚<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"聚硅氧烷"},{"id":"3e1b9587-f22e-443c-b0ac-14ed184616ac","keyword":"纯化","originalKeyword":"纯化"}],"language":"zh","publisherId":"gfzclkxygc200003019","title":"<span style=\"color:red\">乙烯基</span>聚二<span style=\"color:red\">甲基硅氧烷</span>的合成与纯化","volume":"16","year":"2000"},{"abstractinfo":"以十二烷基苯磺酸为催化剂,在八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(D4)的O/W型微乳液中,进行阳离子开环聚合,得到有机<span style=\"color:red\">硅</span>聚合物微乳液. 研究了聚合物乳胶粒的成核机理. 结果表明,聚合过程生成了比<span style=\"color:red\">环</span>单体微滴更小的新粒子,体系经历了粒子的双峰分布后,最终得到远小于初始<span style=\"color:red\">环</span>单体微滴尺寸、单峰分布的有机<span style=\"color:red\">硅</span>微乳液. 可以认为,成核的主要场所不是<span style=\"color:red\">环</span>单体珠滴,而是D4开环生成的端羟基齐聚物在水相成核,类似于自由<span style=\"color:red\">基</span>乳液聚合的均相成核机理. 聚合温度对乳胶粒平均粒径影响不大,但影响最终聚合物微乳液的粒径分布,在80 ℃时所得聚合物乳胶粒的粒径分布较窄. 相同反应温度下生成的聚合物的平衡分子量低于常规乳液聚合,且温度对分子量的影响不如常规乳液聚合明显. 改变乳化剂与助乳化剂的质量比,可以改变<span style=\"color:red\">环</span>单体微乳液的微滴尺寸,进而改变聚合物微乳液的乳胶粒粒径.","authors":[{"authorName":"许湧深","id":"51740861-49c0-489d-96b6-450bbd7efbbe","originalAuthorName":"许湧深"},{"authorName":"戴建华","id":"263f2d85-36c1-43a1-b304-baed87ebc78e","originalAuthorName":"戴建华"},{"authorName":"赵宁","id":"b4579299-73e7-4f44-88e4-93ac73706cdc","originalAuthorName":"赵宁"}],"doi":"10.3969/j.issn.1000-0518.2005.02.007","fpage":"148","id":"f5343e86-4e54-4e7d-857c-64937931c4e5","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"2b2fcf4e-3d08-4b55-81b9-e37fdc376a3e","keyword":"聚<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"聚硅氧烷"},{"id":"ab70b766-30ea-4a95-a7aa-838f74a2eb19","keyword":"微乳液聚合","originalKeyword":"微乳液聚合"},{"id":"c0c7ebab-f33b-4f30-a797-58c8c5b59f51","keyword":"成核机理","originalKeyword":"成核机理"}],"language":"zh","publisherId":"yyhx200502007","title":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的微乳液聚合","volume":"22","year":"2005"},{"abstractinfo":"采用乳液离子开环聚合手段制备了聚有机<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>乳液.考察了聚合过程中乳化剂和催化剂的种类、用量对八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(D4)的转化率及聚合过程中粒子大小变化的影响,并用气相色谱、气相色谱-质谱联用手段分析了聚合过程中单体及副产物含量的变化情况.实验结果表明,当使用非离子型乳化荆时,D4不能开环聚合;而当使用离子型乳化剂时,可有效实现开环聚合;不同类型的乳化剂和催化剂呈现不同的聚合特点;在D4的阴、阳离子催化开环聚合过程中,均发生back-biting现象,但后者更为显著.","authors":[{"authorName":"林明涛","id":"4097a8d0-b2b6-4690-8502-82a03791645f","originalAuthorName":"林明涛"},{"authorName":"庞久寅","id":"fc5272ae-7327-46fb-8563-70b498dbc5ec","originalAuthorName":"庞久寅"},{"authorName":"储富祥","id":"e8e41e4a-9b59-4617-b803-6ec90e582886","originalAuthorName":"储富祥"},{"authorName":"王春鹏","id":"783ea541-ce36-4b1e-879b-77da734d6911","originalAuthorName":"王春鹏"}],"doi":"","fpage":"20","id":"daaad424-fc98-435d-a377-44572df52071","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b4b6f031-b39b-4842-9174-d20d286d95a6","keyword":"乳液聚合","originalKeyword":"乳液聚合"},{"id":"6a11fc32-56e3-42df-956d-00a8cd8ef6cb","keyword":"离子开环聚合","originalKeyword":"离子开环聚合"},{"id":"09650845-a2b0-4b5f-8676-1dd3ae9b0461","keyword":"聚有机<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"聚有机硅氧烷"}],"language":"zh","publisherId":"gfzclkxygc200906006","title":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的乳液离子开环聚合反应","volume":"25","year":"2009"},{"abstractinfo":"采用偏光显微镜研究了八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>一氯代物(D4Cl)/十六烷基三<span style=\"color:red\">甲基</span>溴化铵(CTAB)/乙二醇/水4组分微乳液的相行为,绘制了该体系在80 ℃下的拟三元相图;采用粒度分析研究了八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>一氯代物在上述体系中的微乳液聚合成核机理,对其微乳液在水体系中的消泡性能进行了研究. 结果表明,该微乳聚合主要发生在水相,体系中的<span style=\"color:red\">环</span>单体微滴主要提供开环的端羟基<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的齐聚物;氯<span style=\"color:red\">甲基</span>的引入增大了<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的极性,从而增加了微乳液的消泡性能.","authors":[{"authorName":"戚桂斌","id":"7c21f50e-2761-4768-95bb-2a988b6d9a66","originalAuthorName":"戚桂斌"},{"authorName":"贝逸翎","id":"2e7a651e-9688-4449-9434-5c0dfc80625f","originalAuthorName":"贝逸翎"},{"authorName":"刘庆阳","id":"5d575585-6c62-4e97-8286-e17c281b1117","originalAuthorName":"刘庆阳"},{"authorName":"王爱琴","id":"634897a4-2344-4674-af6a-e36b4085208c","originalAuthorName":"王爱琴"}],"doi":"10.3969/j.issn.1000-0518.2009.01.028","fpage":"122","id":"0a793805-762e-4634-85e3-8be2ae6e2fa0","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ebab7bb5-b812-481a-9080-23aaa9b621b4","keyword":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>一氯代物","originalKeyword":"八甲基环四硅氧烷一氯代物"},{"id":"fe2302e4-c2a9-4207-ba4e-621f30bd9e81","keyword":"有机<span style=\"color:red\">硅</span>微乳液","originalKeyword":"有机硅微乳液"},{"id":"692d6031-2928-4239-a99b-1d2bdf2ea3a4","keyword":"微乳液聚合","originalKeyword":"微乳液聚合"},{"id":"20af05fa-dadd-4c33-9778-ad1fa27e1b84","keyword":"消泡性能","originalKeyword":"消泡性能"}],"language":"zh","publisherId":"yyhx200901028","title":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>一氯代物微乳液聚合及其消泡性能","volume":"26","year":"2009"},{"abstractinfo":"以八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>为单体,十八烷基三<span style=\"color:red\">甲基</span>氯化铵与异构十三醇聚<span style=\"color:red\">氧</span><span style=\"color:red\">乙烯</span>醚为复合乳化剂,于80℃开环聚合制备有机<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>微乳液.考察了非离子乳化剂、阳离子乳化剂、乳化剂配比和乳化荆用量对微乳液的粒径、粒径多分散指数(PDI)、透光率以及微乳液稳定性的影响.实验结果表明,非离子乳化剂有利于提高微乳液的相对稳定性并且使粒径分布更窄;阳离子乳化剂能够使乳液的粒径变小;随着阳离子乳化荆与非离子乳化剂的质量比增加,乳液粒径先减小后稳定;随着复合乳化剂用量的增加,乳液粒径变小,透光率增加,电解质相对稳定性上升而碱的相对稳定性却随之下降.","authors":[{"authorName":"孙淳宁","id":"fd8c457b-40b5-46cb-9025-235b0d179d56","originalAuthorName":"孙淳宁"},{"authorName":"沈敏敏","id":"96fc60a5-6abf-4ff2-b673-fa278b3865e9","originalAuthorName":"沈敏敏"},{"authorName":"莫建强","id":"ace2c16c-16e1-4d4a-8f4d-c7b7c80b070b","originalAuthorName":"莫建强"},{"authorName":"邓莲丽","id":"09ba5e1a-fec2-4a55-a7b0-4e146d6a29ce","originalAuthorName":"邓莲丽"},{"authorName":"周宝文","id":"075e0503-8af8-4d3f-b5b0-f15f21916acb","originalAuthorName":"周宝文"}],"doi":"","fpage":"1","id":"5c86c187-26d1-4d22-ad17-caff59352d6c","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"dc21db60-4255-41b9-a9e6-32191996c696","keyword":"八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"八甲基环四硅氧烷"},{"id":"93e88647-c0ba-4c9a-96ca-c4bddc4a0c0e","keyword":"复合乳化剂","originalKeyword":"复合乳化剂"},{"id":"efafcd33-eb83-4c77-b8ee-11dda4b72431","keyword":"微乳液","originalKeyword":"微乳液"},{"id":"6063b118-fb12-4cc8-8303-e85d82999b24","keyword":"粒径多分散指数","originalKeyword":"粒径多分散指数"},{"id":"3ed71346-a4fa-4f2f-9b0b-976b8143cf77","keyword":"稳定性","originalKeyword":"稳定性"}],"language":"zh","publisherId":"gfzclkxygc201401001","title":"复合乳化剂对八<span style=\"color:red\">甲基</span><span style=\"color:red\">环</span><span style=\"color:red\">四</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>微乳液聚合的影响","volume":"30","year":"2014"},{"abstractinfo":"采用一步法以二<span style=\"color:red\">甲基</span>二氯硅烷、<span style=\"color:red\">四</span>氢呋喃和金属镁粉为原料,在碘乙烷和单质碘催化下合成二-(4-羟基丁基)<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>二<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>.产物温合物减压过滤,以除去镁盐.滤液无需蒸馏提纯,而直接水解,干燥,减压蒸馏,收集71℃/1333Pa馏份.还探讨和优化合成条件:<span style=\"color:red\">四</span>氢呋喃与二<span style=\"color:red\">甲基</span>二氯硅烷之摩尔比应大于3.5;Grignard反应停止后应继续加热回流1小时;蒸馏时系统压力为1333Pa.","authors":[{"authorName":"游革新","id":"18b3e304-3a30-4f1a-ad74-4fea584adcb6","originalAuthorName":"游革新"},{"authorName":"赵耀明","id":"f0f53e1e-2a4e-4679-8a73-401ef23e464c","originalAuthorName":"赵耀明"},{"authorName":"刘海敏","id":"d86775a5-42c4-4648-ab7f-bd7a7134535c","originalAuthorName":"刘海敏"},{"authorName":"严玉蓉","id":"f1c0de76-b33a-4322-bcc9-28cde699c620","originalAuthorName":"严玉蓉"},{"authorName":"谭锡荣","id":"bcb8b6ba-eb9f-46a3-b51f-416c797eacee","originalAuthorName":"谭锡荣"}],"doi":"10.3969/j.issn.1671-5381.2003.03.003","fpage":"6","id":"918330b6-78f0-4a89-8d26-1b68a0ec766d","issue":"3","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"54481ade-7dc7-4917-902f-e0ae474db126","keyword":"<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"硅氧烷"},{"id":"7fdd0f68-ac0f-409d-8b16-b3c449d0edb2","keyword":"二-(4-羟基丁基)<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>二<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"二-(4-羟基丁基)四甲基二硅氧烷"}],"language":"zh","publisherId":"hccllhyyy200303003","title":"二-(4-羟基丁基)<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>二<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的合成研究","volume":"32","year":"2003"},{"abstractinfo":"合成了3个含<span style=\"color:red\">硅</span><span style=\"color:red\">四</span>烃<span style=\"color:red\">基</span>二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>化合物,并通过乙酸与异戊醇的反应和丁醛与乙二醇的反应,考察了它们在酯化反应和缩醛化反应中的催化活性,讨论了催化剂用量、反应时间和溶剂等因素对催化反应的影响.结果表明,与二氯代<span style=\"color:red\">四</span>丁基二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>相比,3种含<span style=\"color:red\">硅</span><span style=\"color:red\">四</span>烃<span style=\"color:red\">基</span>二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>在酯化反应和缩醛化反应中均表现出类似的高催化活性;催化剂[ClBu2SnOSn(CH2SiMe3)2Cl]2用量为反应物料质量的1.5%时,乙酸异戊酯的产率为91.8%,丁醛缩乙二醇的产率为94.2%.在<span style=\"color:red\">四</span>烃<span style=\"color:red\">基</span>二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>结构中,锡原子上的烃<span style=\"color:red\">基</span>或桥联基团的不同,对其催化活性均有一定程度的影响.","authors":[{"authorName":"何小立","id":"3d428ee3-95e5-45d1-bb18-8d128128557e","originalAuthorName":"何小立"},{"authorName":"林森","id":"087cac7e-99a0-4930-af7e-3b30053d8d44","originalAuthorName":"林森"},{"authorName":"郭璇","id":"fe47fbf3-4c1a-4e44-a107-313e890b25cd","originalAuthorName":"郭璇"},{"authorName":"陆路德","id":"9cec6b86-10a1-425e-ab65-79abc84c418f","originalAuthorName":"陆路德"},{"authorName":"汪信","id":"bd8905a3-55bb-4397-95ad-bcd87df28394","originalAuthorName":"汪信"},{"authorName":"杨绪杰","id":"cfda73b7-676f-455a-8a9a-9e24e9ce1470","originalAuthorName":"杨绪杰"}],"doi":"10.3969/j.issn.1000-0518.2007.11.010","fpage":"1268","id":"ec8720aa-85a2-4b58-820a-8fae5ba70001","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f02d2d5f-09f0-4b2d-ba78-e94e92cf02a9","keyword":"含<span style=\"color:red\">硅</span><span style=\"color:red\">四</span>烃<span style=\"color:red\">基</span>二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"含硅四烃基二锡氧烷"},{"id":"0644d0d9-16db-4c24-95e0-bada7f460794","keyword":"合成","originalKeyword":"合成"},{"id":"8bb83849-6fd3-494c-b124-1ef40c4a5197","keyword":"催化","originalKeyword":"催化"},{"id":"4f6ea8a3-6afe-4a38-a3c5-c96860e98fce","keyword":"酯化反应","originalKeyword":"酯化反应"},{"id":"ab9962c0-3d3e-4e74-849f-1d7bff92d2be","keyword":"缩醛化反应","originalKeyword":"缩醛化反应"}],"language":"zh","publisherId":"yyhx200711010","title":"含<span style=\"color:red\">硅</span><span style=\"color:red\">四</span>烃<span style=\"color:red\">基</span>二锡<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的合成及其催化性能","volume":"24","year":"2007"},{"abstractinfo":"苯并<span style=\"color:red\">环</span>丁烯树脂在许多高科技领域都有应用,是当今高性能树脂研究的热点之一.本文采用Heck反应合成了二<span style=\"color:red\">乙烯基</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>-双苯并<span style=\"color:red\">环</span>丁烯树脂,并用红外、质谱、核磁共振对其结构进行了表征,研究了该树脂的固化反应,最后测定了固化树脂的物理性能.研究结果表明,二<span style=\"color:red\">乙烯基</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>-双苯并<span style=\"color:red\">环</span>丁烯固化树脂具有优异的热稳定性能和介电性能.","authors":[{"authorName":"朱国敏","id":"97f9663a-7df7-49bd-8e7e-82201b3b0ed7","originalAuthorName":"朱国敏"},{"authorName":"沈学宁","id":"f940103f-8337-42ec-85dc-3ab6758165a5","originalAuthorName":"沈学宁"},{"authorName":"王靖","id":"efd6dac8-1c97-4aa7-9096-be0075c02dec","originalAuthorName":"王靖"},{"authorName":"黄发荣","id":"16ad15e9-7d29-45ac-8755-93f89c1e2472","originalAuthorName":"黄发荣"}],"doi":"10.3969/j.issn.1003-0999.2005.04.005","fpage":"16","id":"e8dfef14-3f1b-4842-909a-c2568ac8d58d","issue":"4","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"9aabbdb9-bd09-4c11-a755-bb21375886af","keyword":"苯并<span style=\"color:red\">环</span>丁烯","originalKeyword":"苯并环丁烯"},{"id":"fc818d42-a475-4ec3-96a8-b36fef4cfdd2","keyword":"二<span style=\"color:red\">乙烯基</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>树脂","originalKeyword":"二乙烯基硅氧烷树脂"},{"id":"5112b561-ea09-4c29-a7a6-678ffdd4b498","keyword":"Heck反应","originalKeyword":"Heck反应"},{"id":"475a3a3a-ee7c-46f8-aefb-d78c9de68df2","keyword":"固化","originalKeyword":"固化"}],"language":"zh","publisherId":"blgfhcl200504005","title":"二<span style=\"color:red\">乙烯基</span><span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>-双苯并<span style=\"color:red\">环</span>丁烯树脂的制备与性能研究","volume":"","year":"2005"},{"abstractinfo":"以1,4-双(二<span style=\"color:red\">甲基</span><span style=\"color:red\">硅</span><span style=\"color:red\">基</span>)苯、二<span style=\"color:red\">甲基</span>二甲氧基硅烷和<span style=\"color:red\">甲基</span><span style=\"color:red\">乙烯基</span>二甲氧基硅烷为原料,用Si-H/Si-OR缩聚的方法制备了一系列聚(<span style=\"color:red\">四</span><span style=\"color:red\">甲基</span>对<span style=\"color:red\">硅</span>亚苯基-二<span style=\"color:red\">甲基</span>-<span style=\"color:red\">甲基</span><span style=\"color:red\">乙烯基</span>)<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>三元共聚物(PTMPS/DMS/VMS),并用TG与DSC对共聚物的热性质进行了表征.结果表明,<span style=\"color:red\">乙烯基</span>能显著提高PTMPS/DMS/VMS在氮气中的热稳定性,且当DMS/VMS为50:50(摩尔比)时热稳定性最好.在空气中,引入<span style=\"color:red\">乙烯基</span>同样能提高PTMPS/DMS/VMS的热稳定性,但其影响比氮气中小得多.PTMPS/DMS/VMS的Tg与VMS链节含量的关系为:Tg=-56.1-0.04[VMS%],Tg随共聚物中VMS链节含量的增加而线性降低,但降低的幅度很小(不超过4.3℃).","authors":[{"authorName":"陈循军","id":"5e185e63-f9fd-4642-a79b-a8aee57adc49","originalAuthorName":"陈循军"},{"authorName":"崔英德","id":"4c03b655-996d-4ba8-a600-dcc657691c32","originalAuthorName":"崔英德"},{"authorName":"尹国强","id":"1bfec6c3-e221-40a2-a5a0-c8de3af8b54b","originalAuthorName":"尹国强"},{"authorName":"胡文斌","id":"6a74a820-8164-4bd8-a8a0-5ce917a965a7","originalAuthorName":"胡文斌"}],"doi":"","fpage":"361","id":"4245eb2a-a8b1-4b12-867f-6529f0dd0bc8","issue":"z1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"60dc043b-8358-4d4f-88fa-5e11b3ca2ed0","keyword":"耐高温","originalKeyword":"耐高温"},{"id":"3be1182a-edd6-44d7-aa90-543ab5df07ca","keyword":"弹性体","originalKeyword":"弹性体"},{"id":"3804209c-8425-4e61-a6fc-f02949e258e6","keyword":"聚苯撑<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"聚苯撑硅氧烷"},{"id":"28cb2a30-ecc1-4694-a0dd-16f8a713ccdf","keyword":"热性质","originalKeyword":"热性质"}],"language":"zh","publisherId":"cldb2008z1109","title":"<span style=\"color:red\">乙烯基</span>取代聚苯撑<span style=\"color:red\">硅</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的热性质","volume":"22","year":"2008"}],"totalpage":5105,"totalrecord":51049}