{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"由6-羟基-2-苯基-3-哒嗪酮和<span style=\"color:red\">二</span>丁基氧化<span style=\"color:red\">锡</span>合成了新的有机<span style=\"color:red\">锡</span><span style=\"color:red\">氧</span>簇化合物Ⅰ,用元素分析、IR、1H、13C和119Sn NMR表征了其结构.由X射线单晶衍射测定了其晶体结构,该化合物属于三斜晶系,P1空间群,晶体学参数为a=1.221 75(13)nm,b=1.267 90(13)nm,c=1.345 33(14)nm,α=87.168 0(10)°,β=672.265 0(10)°,γ=87.261 0(10)°,V=1.981 4(4)nm3,Z=1,Dc=1.435 g/cm3,μ(MoKα)=0.870 0,F(000)=868.该化合物具有中心对称的梯形结构,<span style=\"color:red\">锡</span>原子为五配位的三角双锥构型.该化合物催化乙酰乙酸乙酯和甲醇的酯交换的产率为88%、催化丙<span style=\"color:red\">二</span>酸<span style=\"color:red\">二</span>甲酯和乙醇的酯交换的产率为90%,但较难催化环己酮和甘油的缩酮反应,产率低于22%.","authors":[{"authorName":"毛武涛","id":"04665c7c-f8df-4da3-aca4-735db517c1cb","originalAuthorName":"毛武涛"},{"authorName":"田来进","id":"2d8b8e2b-1d83-43ac-b008-9b5985484eec","originalAuthorName":"田来进"},{"authorName":"郑晓风","id":"225ab9f3-fa42-4d15-8956-aedf3aebf846","originalAuthorName":"郑晓风"},{"authorName":"尹玲","id":"7ab86bce-8dfc-482b-baa9-7802d1f76cde","originalAuthorName":"尹玲"}],"doi":"10.3969/j.issn.1000-0518.2007.12.005","fpage":"1368","id":"e214903e-260d-4e82-a63b-1b2793902f77","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"4b175dd2-c346-4d21-b1af-85303fd73582","keyword":"<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"四烃基二锡氧烷"},{"id":"e8af8a74-4cab-4c4c-961c-7e184a5aa5e0","keyword":"羟基苯基哒嗪酮","originalKeyword":"羟基苯基哒嗪酮"},{"id":"a062bd30-958e-41dd-883b-192b80438610","keyword":"催化活性","originalKeyword":"催化活性"},{"id":"32be49d9-c971-4312-a689-7c7172c95868","keyword":"晶体结构","originalKeyword":"晶体结构"}],"language":"zh","publisherId":"yyhx200712005","title":"6-羟基-2-苯基-3-哒嗪酮<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span><span style=\"color:red\">二</span>聚体的合成、表征和催化性能","volume":"24","year":"2007"},{"abstractinfo":"合成了3个含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>化合物,并通过乙酸与异戊醇的反应和丁醛与乙<span style=\"color:red\">二</span>醇的反应,考察了它们在酯化反应和缩醛化反应中的催化活性,讨论了催化剂用量、反应时间和溶剂等因素对催化反应的影响.结果表明,与<span style=\"color:red\">二</span>氯代<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>相比,3种含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>在酯化反应和缩醛化反应中均表现出类似的高催化活性;催化剂[ClBu2SnOSn(CH2SiMe3)2Cl]2用量为反应物料质量的1.5%时,乙酸异戊酯的产率为91.8%,丁醛缩乙<span style=\"color:red\">二</span>醇的产率为94.2%.在<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>结构中,<span style=\"color:red\">锡</span>原子上的<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>或桥联基团的不同,对其催化活性均有一定程度的影响.","authors":[{"authorName":"何小立","id":"3d428ee3-95e5-45d1-bb18-8d128128557e","originalAuthorName":"何小立"},{"authorName":"林森","id":"087cac7e-99a0-4930-af7e-3b30053d8d44","originalAuthorName":"林森"},{"authorName":"郭璇","id":"fe47fbf3-4c1a-4e44-a107-313e890b25cd","originalAuthorName":"郭璇"},{"authorName":"陆路德","id":"9cec6b86-10a1-425e-ab65-79abc84c418f","originalAuthorName":"陆路德"},{"authorName":"汪信","id":"bd8905a3-55bb-4397-95ad-bcd87df28394","originalAuthorName":"汪信"},{"authorName":"杨绪杰","id":"cfda73b7-676f-455a-8a9a-9e24e9ce1470","originalAuthorName":"杨绪杰"}],"doi":"10.3969/j.issn.1000-0518.2007.11.010","fpage":"1268","id":"ec8720aa-85a2-4b58-820a-8fae5ba70001","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"f02d2d5f-09f0-4b2d-ba78-e94e92cf02a9","keyword":"含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"含硅四烃基二锡氧烷"},{"id":"0644d0d9-16db-4c24-95e0-bada7f460794","keyword":"合成","originalKeyword":"合成"},{"id":"8bb83849-6fd3-494c-b124-1ef40c4a5197","keyword":"催化","originalKeyword":"催化"},{"id":"4f6ea8a3-6afe-4a38-a3c5-c96860e98fce","keyword":"酯化反应","originalKeyword":"酯化反应"},{"id":"ab9962c0-3d3e-4e74-849f-1d7bff92d2be","keyword":"缩醛化反应","originalKeyword":"缩醛化反应"}],"language":"zh","publisherId":"yyhx200711010","title":"含硅<span style=\"color:red\">四</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的合成及其催化性能","volume":"24","year":"2007"},{"abstractinfo":"以<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>为催化剂,通过尿素的醇解反应,合成了<span style=\"color:red\">四</span>种高沸点碳酸<span style=\"color:red\">二</span>酯化合物.研究结果表明,尿素的第一步醇解反应较易进行,产物收率大于60%;第<span style=\"color:red\">二</span>步从氨基甲酸酯醇解变为碳酸<span style=\"color:red\">二</span>酯的反应较难进行.尿素醇解反应与所用的醇有密切的关系,其中尿素与苯甲醇醇解为碳酸<span style=\"color:red\">二</span>酯的反应最易进行,正己醇次之,而正辛醇反应最难进行. 提高反应温度到195 ℃,以官能团为NCS的<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>代替官能团为Cl的<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>为催化剂时,适当提高醇的配比,尿素与正辛醇醇解为碳酸<span style=\"color:red\">二</span>酯的产物收率有较大的提高. 提出了尿素醇解反应的可能机理.","authors":[{"authorName":"兰支利","id":"4d1ac5f5-7c94-4344-b4d1-15513e6edf54","originalAuthorName":"兰支利"},{"authorName":"吕妍","id":"b5bb708c-71a8-4a2a-8a1d-d48bfcf6374d","originalAuthorName":"吕妍"},{"authorName":"李靖","id":"3cbdd153-20ec-4838-a94e-b301893969e8","originalAuthorName":"李靖"},{"authorName":"谢庆兰","id":"a67708e9-faa2-4360-86c2-99e85c9677cc","originalAuthorName":"谢庆兰"}],"doi":"","fpage":"77","id":"e58461a1-3cc8-4c4b-82f4-ca33a1df343c","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"0bb05d61-d274-4eb5-b388-eaaedd1e6633","keyword":"<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"四丁基二锡氧烷"},{"id":"591eb2c1-b00d-4640-8497-cc2023ce0488","keyword":"尿素","originalKeyword":"尿素"},{"id":"9ad666a2-7a0f-4651-8a29-0d4fcba12e82","keyword":"碳酸<span style=\"color:red\">二</span>酯","originalKeyword":"碳酸二酯"},{"id":"2d43d64b-e16e-42e5-9cb0-bc3dcdf30cc1","keyword":"氨基甲酸酯","originalKeyword":"氨基甲酸酯"}],"language":"zh","publisherId":"cuihuaxb200201018","title":"<span style=\"color:red\">四</span>丁基<span style=\"color:red\">二</span><span style=\"color:red\">锡</span><span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>催化合成碳酸<span style=\"color:red\">二</span>酯类化合物的新方法","volume":"23","year":"2002"},{"abstractinfo":"合成了13种三<span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span><span style=\"color:red\">二</span>茂铁甲酸酯类化合物,对化合物进行了元素分析和谱学表征. 化合物生物活性测定表明,其生物选择性主要取决于<span style=\"color:red\">锡</span>原子上的3个<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>,其中含有环己基、丁基、甲基和RMe2SiCH2<span style=\"color:red\">基</span>的衍生物具有较好的杀螨活性,而三丁基<span style=\"color:red\">锡</span><span style=\"color:red\">二</span>茂铁甲酸酯的杀菌活性较好.","authors":[{"authorName":"罗宁","id":"23497959-227a-4d2f-98ea-d409b0bc8601","originalAuthorName":"罗宁"},{"authorName":"孙丽娟","id":"19bf1d03-b9c1-424d-a0c4-62684a9d2d5e","originalAuthorName":"孙丽娟"},{"authorName":"刘治中","id":"c334835a-8293-4b35-bb8d-b5b934739500","originalAuthorName":"刘治中"},{"authorName":"谢庆兰","id":"7e001d31-dbf1-451f-bbcb-cc230556b83c","originalAuthorName":"谢庆兰"},{"authorName":"母昭德","id":"dbb26f57-e249-4d9c-b4c8-2bd00038f8e0","originalAuthorName":"母昭德"}],"doi":"10.3969/j.issn.1000-0518.2000.02.010","fpage":"154","id":"c82c8b1f-9a2d-44a1-ae64-def8743544cf","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"6f4cd8a0-2af1-4a02-8741-11fd8a69f4a9","keyword":"三<span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span>","originalKeyword":"三烃基锡"},{"id":"df0b4559-c7de-4fa3-9622-d1a674be4144","keyword":"<span style=\"color:red\">二</span>茂铁甲酸","originalKeyword":"二茂铁甲酸"},{"id":"e337f33d-3de1-4d59-9983-ccce3ed8b9a6","keyword":"谱学表征","originalKeyword":"谱学表征"},{"id":"fb178b15-b2fe-4dfa-9e81-0ff71715307e","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx200002010","title":"三<span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span><span style=\"color:red\">二</span>茂铁甲酸酯的合成、表征及其生物活性","volume":"17","year":"2000"},{"abstractinfo":"以八甲基环<span style=\"color:red\">四</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(D4)为主链剂,<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>乙烯<span style=\"color:red\">基</span><span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>(MM)为封端剂,用碱催化平衡法合成乙烯<span style=\"color:red\">基</span>聚<span style=\"color:red\">二甲基硅氧烷</span>(V-PDMS),探讨了影响合成反应及产物分子量、乙烯<span style=\"color:red\">基</span>含量(Vi%)的主要因素,并对合成的V-PDMS进行精制处理.","authors":[{"authorName":"胡友慧","id":"065075a0-31d6-4d43-8656-831e0f45b834","originalAuthorName":"胡友慧"},{"authorName":"许新社","id":"8e4f5665-f8a0-4bce-81c4-afd7e51f661f","originalAuthorName":"许新社"}],"doi":"","fpage":"67","id":"fcd5cc8d-d74b-4a6a-915b-fc06931a0c85","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4a5fd6ea-14db-47f3-b7a3-62c00f2280c8","keyword":"<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>乙烯<span style=\"color:red\">基</span><span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"四甲基二乙烯基二硅氧烷"},{"id":"9cdb9cf2-f4d0-406f-bd98-1af50ce67992","keyword":"八甲基环<span style=\"color:red\">四</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"八甲基环四硅氧烷"},{"id":"7dab883f-6436-41e7-a444-4a1ad89ee297","keyword":"聚硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"聚硅氧烷"},{"id":"3e1b9587-f22e-443c-b0ac-14ed184616ac","keyword":"纯化","originalKeyword":"纯化"}],"language":"zh","publisherId":"gfzclkxygc200003019","title":"乙烯<span style=\"color:red\">基</span>聚<span style=\"color:red\">二甲基硅氧烷</span>的合成与纯化","volume":"16","year":"2000"},{"abstractinfo":"考察了10种含硅<span style=\"color:red\">二</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span>化合物对柠檬醛与乙<span style=\"color:red\">二</span>醇及环己酮与乙<span style=\"color:red\">二</span>醇的缩合反应的催化活性.研究了催化剂用量、反应时间、醛醇及酮醇的物质的量之比和溶剂等对反应产率的影响.结果表明,除一种催化剂外,9种化合物对缩醛和缩酮反应均有良好的催化活性,当催化剂用量为反应物质量分数的1.4％,醛与乙<span style=\"color:red\">二</span>醇的物质量之比为1:1.3,酮与乙<span style=\"color:red\">二</span>醇的物质量之比为1:1.6,以环己烷为带水剂,回流反应3h,产物收率分别达92％和86％以上.","authors":[{"authorName":"林森","id":"5b8f4a56-d986-41ba-9a4b-d8bacb1bffcb","originalAuthorName":"林森"},{"authorName":"郭杨洋","id":"8a751fb8-904a-4397-9dd6-4e13f565bd2e","originalAuthorName":"郭杨洋"},{"authorName":"邓瑞红","id":"e4f82ee6-407d-4586-a199-ef90404e4ff1","originalAuthorName":"邓瑞红"},{"authorName":"黄志强","id":"5e099e75-3508-40d2-ba7c-3fda3522cb69","originalAuthorName":"黄志强"}],"doi":"10.3724/SP.J.1095.2013.20211","fpage":"271","id":"fde341d4-d292-4803-baa7-23189720e719","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bf429546-c4a9-491d-a056-bcbff57749ea","keyword":"含硅<span style=\"color:red\">二</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span>化合物","originalKeyword":"含硅二烃基锡化合物"},{"id":"619cd2bb-1f9f-4425-ae41-edc93443b593","keyword":"催化活性","originalKeyword":"催化活性"},{"id":"82904501-0c68-4d88-8122-5fbd6e984b27","keyword":"缩醛反应","originalKeyword":"缩醛反应"},{"id":"d1e9fec0-5672-40d1-be0f-e1517b6acd16","keyword":"缩酮反应","originalKeyword":"缩酮反应"}],"language":"zh","publisherId":"yyhx201303005","title":"含硅<span style=\"color:red\">二</span><span style=\"color:red\">烃</span><span style=\"color:red\">基</span><span style=\"color:red\">锡</span>化合物对醇醛(酮)缩合反应的催化活性","volume":"30","year":"2013"},{"abstractinfo":"采用一步法以<span style=\"color:red\">二</span>甲基<span style=\"color:red\">二</span>氯硅烷、<span style=\"color:red\">四</span>氢呋喃和金属镁粉为原料,在碘乙烷和单质碘催化下合成<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>.产物温合物减压过滤,以除去镁盐.滤液无需蒸馏提纯,而直接水解,干燥,减压蒸馏,收集71℃/1333Pa馏份.还探讨和优化合成条件:<span style=\"color:red\">四</span>氢呋喃与<span style=\"color:red\">二</span>甲基<span style=\"color:red\">二</span>氯硅烷之摩尔比应大于3.5;Grignard反应停止后应继续加热回流1小时;蒸馏时系统压力为1333Pa.","authors":[{"authorName":"游革新","id":"18b3e304-3a30-4f1a-ad74-4fea584adcb6","originalAuthorName":"游革新"},{"authorName":"赵耀明","id":"f0f53e1e-2a4e-4679-8a73-401ef23e464c","originalAuthorName":"赵耀明"},{"authorName":"刘海敏","id":"d86775a5-42c4-4648-ab7f-bd7a7134535c","originalAuthorName":"刘海敏"},{"authorName":"严玉蓉","id":"f1c0de76-b33a-4322-bcc9-28cde699c620","originalAuthorName":"严玉蓉"},{"authorName":"谭<span style=\"color:red\">锡</span>荣","id":"bcb8b6ba-eb9f-46a3-b51f-416c797eacee","originalAuthorName":"谭锡荣"}],"doi":"10.3969/j.issn.1671-5381.2003.03.003","fpage":"6","id":"918330b6-78f0-4a89-8d26-1b68a0ec766d","issue":"3","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"54481ade-7dc7-4917-902f-e0ae474db126","keyword":"硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"硅氧烷"},{"id":"7fdd0f68-ac0f-409d-8b16-b3c449d0edb2","keyword":"<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"二-(4-羟基丁基)四甲基二硅氧烷"}],"language":"zh","publisherId":"hccllhyyy200303003","title":"<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的合成研究","volume":"32","year":"2003"},{"abstractinfo":"三苯基氯化<span style=\"color:red\">锡</span>和烯(或炔)<span style=\"color:red\">基</span>膦酸<span style=\"color:red\">二</span>钠反应，合成了8种新的双(三苯基<span style=\"color:red\">锡</span>)不饱和<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>膦酸酯.利用元素分析、红外光谱、核磁共振氢谱和<span style=\"color:red\">锡</span>谱以及质谱表征了这些化合物的结构.生物活性测试表明，该类化合物具有很高的杀菌活性.","authors":[{"authorName":"尹汉东","id":"051d8029-7e6c-4e9c-ac3e-2959aaf4b8d8","originalAuthorName":"尹汉东"},{"authorName":"张如芬","id":"c5eb45c6-90c8-4f80-8a94-603e9a78eea2","originalAuthorName":"张如芬"},{"authorName":"马春林","id":"32ce6414-8caf-40ec-8edc-e4a90cf516e6","originalAuthorName":"马春林"}],"doi":"10.3969/j.issn.1000-0518.2001.02.013","fpage":"134","id":"630e4b5a-a6a7-4960-baa1-9708c4b04d32","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"acade526-ab67-4549-a882-ea07d27f1adc","keyword":"三苯基<span style=\"color:red\">锡</span>","originalKeyword":"三苯基锡"},{"id":"77f5e66e-85d4-4ef5-a588-106b9cbda452","keyword":"不饱和<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>膦酸酯.合成","originalKeyword":"不饱和烃基膦酸酯.合成"},{"id":"7171c1cd-37e2-4154-b0ab-95c41c83a174","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx200102013","title":"双(三苯基<span style=\"color:red\">锡</span>)不饱和<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>膦酸酯的合成和性质","volume":"18","year":"2001"},{"abstractinfo":"利用双[三(硅<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>亚甲基)<span style=\"color:red\">锡</span>]氧化物与吡啶甲酸反应,合成了9种三(硅<span style=\"color:red\">烃</span><span style=\"color:red\">基</span>亚甲基)<span style=\"color:red\">锡</span>吡啶甲酸酯.通过IR、1H NMR、13C NMR、MS以及元素分析测试技术,对这些化合物的结构进行了表征.生物活性的初步测定结果表明,三[(三甲硅<span style=\"color:red\">基</span>)亚甲基]<span style=\"color:red\">锡</span>吡啶甲酸酯和三[(乙基<span style=\"color:red\">二</span>甲基硅<span style=\"color:red\">基</span>)亚甲基]<span style=\"color:red\">锡</span>吡啶甲酸酯具有较好的杀螨活性,而三[(丁基<span style=\"color:red\">二</span>甲基硅<span style=\"color:red\">基</span>)亚甲基]<span style=\"color:red\">锡</span>吡啶甲酸酯的杀螨活性较差.","authors":[{"authorName":"林森","id":"8abbd8d4-afd7-48ce-8cca-c2cdf0cb4e3c","originalAuthorName":"林森"},{"authorName":"邓瑞红","id":"c8912be2-c87e-4224-9e1a-1a282b966de1","originalAuthorName":"邓瑞红"},{"authorName":"姚华","id":"cecf1649-689c-436d-a17e-b2168f4a3077","originalAuthorName":"姚华"},{"authorName":"孙小强","id":"a34cc47b-e3e7-4220-847c-5da1cd4766e4","originalAuthorName":"孙小强"},{"authorName":"汪信","id":"eff808c3-2812-4c66-9dad-e7c7cf5359ab","originalAuthorName":"汪信"}],"doi":"10.3969/j.issn.1000-0518.2005.09.015","fpage":"989","id":"1cb46c99-4e56-4d20-a867-958387148cdf","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"8ea6de5f-fe57-4034-a194-9647ed012da1","keyword":"含硅有机<span style=\"color:red\">锡</span>化合物","originalKeyword":"含硅有机锡化合物"},{"id":"dbeb0927-6805-48d5-9bfc-4e37e5f03cc0","keyword":"合成","originalKeyword":"合成"},{"id":"753a3ee0-7236-4d3f-be7d-f24d95af8fc5","keyword":"结构表征","originalKeyword":"结构表征"},{"id":"3f0a5595-897a-4bc2-b0f2-95ebe070271e","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx200509015","title":"三(三<span style=\"color:red\">烃</span>硅<span style=\"color:red\">基</span>亚甲基)<span style=\"color:red\">锡</span>吡啶甲酸酯的合成和结构表征","volume":"22","year":"2005"},{"abstractinfo":"采用气相色谱内标法,对<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>合成产物进行定量分析,并确定了色谱操作条件和产物的重量校正因子.该方法操作简单、快速、精度高、重现性好.","authors":[{"authorName":"游革新","id":"df142f9f-f74d-4811-917f-93616e292ffb","originalAuthorName":"游革新"},{"authorName":"赵耀明","id":"fff04c24-5e70-4fbf-9780-22aa9bf36689","originalAuthorName":"赵耀明"},{"authorName":"严玉蓉","id":"8fcb54e8-f86d-4234-9132-3fe595701c9f","originalAuthorName":"严玉蓉"},{"authorName":"汪朝阳","id":"e60062af-1869-4b4e-8449-106aa1aa4801","originalAuthorName":"汪朝阳"}],"doi":"10.3969/j.issn.1671-5381.2003.02.008","fpage":"21","id":"a8763fc6-aaec-452c-aba9-c3e0d2d074fe","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"b565efa3-b0dd-4bb5-a0f8-c07837eda151","keyword":"气相色谱","originalKeyword":"气相色谱"},{"id":"f259f757-e0ee-4792-944e-4e6f5ca4b75a","keyword":"内标法","originalKeyword":"内标法"},{"id":"cf5a8180-b9c4-4ae9-a761-9091744b2b9d","keyword":"<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>","originalKeyword":"二-(4-羟基丁基)四甲基二硅氧烷"}],"language":"zh","publisherId":"hccllhyyy200302008","title":"气相色谱法测定<span style=\"color:red\">二</span>-(4-羟基丁基)<span style=\"color:red\">四</span>甲基<span style=\"color:red\">二</span>硅<span style=\"color:red\">氧</span><span style=\"color:red\">烷</span>的合成产物含量","volume":"32","year":"2003"}],"totalpage":5902,"totalrecord":59019}