{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过X射线衍射(X-ray)、差(DTA)和热重(TG)等手段分析了不同工艺条件下制备的十六烷基三甲基溴化铵(CTMAB)插层有机膨润土(CTMAB-MMT),讨论了有机膨润土的结构和层间发生的有机化反应,确定了本实验的最佳工艺条件,首次提出了季铵盐在插层过程中分解出季铵离子头的观点.初步认为不仅体积较大的有机阳离子可以插入蒙脱石片层间,体积较小的有机阳离子也可以插入其中.","authors":[{"authorName":"叶巧明","id":"e56b37ef-81f4-436e-b252-7f2b9254f040","originalAuthorName":"叶巧明"},{"authorName":"刘兴奋","id":"b843a1a0-3849-47e2-9d72-85fb87d54eb3","originalAuthorName":"刘兴奋"}],"doi":"10.3969/j.issn.1001-1625.2004.05.010","fpage":"40","id":"f489f8e3-df82-4c12-bb6f-7e09d8ee179e","issue":"5","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"6568b14b-6c4d-4dfc-8838-c36f754b10b2","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"f0ba8792-3f1d-438c-ad35-5f3b489bbdbf","keyword":"季铵盐","originalKeyword":"季铵盐"},{"id":"76e6f4cd-d6ec-4633-9f10-5a90fe0dff79","keyword":"季铵离子头","originalKeyword":"季铵离子头"},{"id":"9027e26b-eb2c-4913-ae55-6e6ac05e36f5","keyword":"插层","originalKeyword":"插层"},{"id":"3b3cc7e4-98a8-4ab4-b140-ffea842a3963","keyword":"结构","originalKeyword":"结构"}],"language":"zh","publisherId":"gsytb200405010","title":"CTMAB插层有机膨润土的结构分析","volume":"23","year":"2004"},{"abstractinfo":"以双酚A型环氧树脂(CYD-128)为基体,有机膨润土为增韧改性剂,选用自行合成的固化剂,固化不同质量比的环氧树脂/有机膨润土复合体系的共混物,测定了共混固化复合体系的冲击强度、拉伸强度和热分解温度,并用扫描电镜(SEM)观察了环氧树脂/有机膨润土复合体系的微观结构.结果表明:随着有机膨润土含量的增加,冲击强度逐渐增加,当有机膨润土含量达3%~4%时冲击强度出现了极大值;随着有机膨润土含量的进一步增加,冲击强度减小.当共混复合体系的质量比为(3~4):100时,复合体系增韧的效果非常明显,把冲击强度从20.4kJ/m2提高到25.0kJ/m2;拉伸强度和热分解初始温度均有较大程度的改善;并且随着有机膨润土的加入,复合体系的断裂面逐渐呈韧性断裂.","authors":[{"authorName":"牟其伍","id":"1e3bab03-ab6d-4815-9477-274af4d9784e","originalAuthorName":"牟其伍"},{"authorName":"朱红梅","id":"21725871-299b-4151-bf1b-0f1933121e39","originalAuthorName":"朱红梅"},{"authorName":"粟笛","id":"c730703d-cf0c-4822-a51e-ef7eca276027","originalAuthorName":"粟笛"}],"doi":"","fpage":"226","id":"9d77dc2e-65d1-4c9b-a24e-86c359971894","issue":"z1","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"0feeebb0-2f9a-477e-b71e-1271268c7528","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"3c9b2f38-cbed-42d7-8dc0-4b4cc6c20b90","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"d874090d-a6bd-4dc1-90b9-da46468aa4bb","keyword":"改性","originalKeyword":"改性"},{"id":"4dc5ad25-fcc4-45c7-989b-3bfe8a18fefa","keyword":"耐热性","originalKeyword":"耐热性"}],"language":"zh","publisherId":"cldb2009z1067","title":"环氧树脂/有机膨润土复合体系的性能研究","volume":"23","year":"2009"},{"abstractinfo":"分别以钠化和热化预处理膨润土,再用CTMAB进行改性,制得两种有机膨润土,通过红外(IR)和X射线衍射(XRD)表征结构,采用批量实验研究两种有机膨润土的吸附性能,讨论pH值、吸附时间和温度等因素对吸附能力的影响,从动力学和热力学方面探讨吸附机理.结果表明,热化有机土(TOB)比钠化有机土(NOB)的层间距更大,吸附性能更强.准二级动力方程能更好的描述两种有机土对双酚A的吸附过程,等温曲线符合Freundlich方程,热力学参数△H0、△G0和△S0均小于零,说明两种有机土对双酚A的吸附是放热的、自发的过程.","authors":[{"authorName":"唐婧","id":"6ca2a3b0-6a7b-47b5-bdfa-396a84120b07","originalAuthorName":"唐婧"},{"authorName":"范开敏","id":"46b4ee66-ef27-4196-a072-9b70b285e4c4","originalAuthorName":"范开敏"}],"doi":"","fpage":"405","id":"d319a768-b108-4ccb-8a31-17d2cb79ba99","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"7cb1cc6e-26b4-402a-be35-bae958039577","keyword":"热化","originalKeyword":"热化"},{"id":"4d78cf50-ca40-433a-b52b-c6bba19a7059","keyword":"钠化","originalKeyword":"钠化"},{"id":"8384f4bb-ea0d-41f5-8a04-b9aa4e34f5fb","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"6b920d13-889b-4c0a-95c0-3905af24227c","keyword":"吸附","originalKeyword":"吸附"},{"id":"3064bf02-61d5-4cd9-8ac6-c7414df41946","keyword":"双酚A","originalKeyword":"双酚A"}],"language":"zh","publisherId":"gsytb201602012","title":"不同预处理方式对有机膨润土吸附性能的影响","volume":"35","year":"2016"},{"abstractinfo":"以新疆乌兰林格提纯膨润土为原料,经NaNO3钠化改性、十六烷基三甲基氯化铵和十八烷基三甲基氯化铵2种季铵盐有机改性得到有机膨润土,考察了反应条件对有机膨润土性能的影响;用该有机土改性市售乳胶漆,考察了有机膨润土对乳胶漆性能的影响.实验表明:较优的有机化反应条件为浆液pH为9、反应温度为60℃、反应时间为1.5h,由此得到的有机膨润土的性能远优于行标;当十八烷基三甲基氯化铵有机膨润土的用量为4%时,乳胶漆的黏度、耐溶剂性、耐磨性、耐冲击性分别提高了144%、80%、74%、120%,指标符合国家标准.","authors":[{"authorName":"李金娥","id":"703a2e75-6033-499d-9dbb-9ad6bf119586","originalAuthorName":"李金娥"},{"authorName":"代斌","id":"0da2883d-cd58-42dc-8d87-7159f7d5ff12","originalAuthorName":"代斌"}],"doi":"","fpage":"31","id":"f13f1e41-5b99-41a0-9322-cd0e377b4d08","issue":"6","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"3ceb2ce2-9d9b-4e8c-8cf8-29e8d32c040e","keyword":"提纯膨润土","originalKeyword":"提纯膨润土"},{"id":"e3554525-f7f6-4cf7-9ff7-ce4143686e70","keyword":"钠化","originalKeyword":"钠化"},{"id":"50537abd-54e5-44a3-84db-ee3391afdf71","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"05dcee2d-bb30-4a4a-9e05-b5507a62f82b","keyword":"乳胶漆","originalKeyword":"乳胶漆"}],"language":"zh","publisherId":"tlgy201506007","title":"制备有机膨润土的影响因素分析及其在乳胶漆中的应用研究","volume":"45","year":"2015"},{"abstractinfo":"有机膨润土取代涂料中部分填料和助剂,既可节省成本,又可提高涂料产品的质量.介绍了制备有机膨润土的工艺流程.论述了有机膨润土在涂料中的应用及作用机理.","authors":[{"authorName":"阎为秋","id":"40f5695f-c70e-49b9-a4ba-5bb9d23d0ef6","originalAuthorName":"阎为秋"},{"authorName":"王新玲","id":"30ffdb56-684c-4c3b-8150-76be03e5175a","originalAuthorName":"王新玲"},{"authorName":"陈主峰","id":"8ff21b6a-2349-4154-85e8-1e9d2a611954","originalAuthorName":"陈主峰"}],"doi":"10.3969/j.issn.0253-4312.2000.12.006","fpage":"15","id":"d045388b-67f3-4bd3-96a5-81640131e308","issue":"12","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"87cf33ef-52ae-4391-ac80-e65133d11401","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"1108812b-5669-46ec-8e3d-d2e069b3b4f4","keyword":"制备","originalKeyword":"制备"},{"id":"e4439ff0-14b0-4717-ab49-eb481db11121","keyword":"涂料","originalKeyword":"涂料"}],"language":"zh","publisherId":"tlgy200012006","title":"有机膨润土的制备及在涂料中的应用","volume":"30","year":"2000"},{"abstractinfo":"以有机插层膨润土、淀粉和丙烯酸为原料,N,N'-亚甲基双丙烯酰胺为交联剂制备了一种新型网络凝胶吸附剂.通过红外光谱(FT-IR)、X射线衍射(XRD)和扫描电镜(SEM)对凝胶结构进行了表征.研究了吸附剂对亚甲基蓝的吸附行为,考察了pH值、吸附时间和初始浓度等因素对吸附剂吸附性能的影响,并用不同等温方程对吸附数据进行了拟合.结果表明Skip等温模型的拟合效果更好,吸附剂在26℃,pH =6时对亚甲基蓝的最大量论吸附量为341 mg/g.再生实验表明凝胶吸附剂可多次回收利用.","authors":[{"authorName":"杨盛春","id":"808c520a-647f-4cdc-ae1a-b038b8a4b84a","originalAuthorName":"杨盛春"},{"authorName":"白友明","id":"3dddb21f-a034-4229-b330-1bf342ba1702","originalAuthorName":"白友明"},{"authorName":"贺洁","id":"1915184d-a7de-41ad-8a80-9f068bb8a54f","originalAuthorName":"贺洁"},{"authorName":"何丽仙","id":"ddbad37e-40ea-4851-b15a-3eee10979fa7","originalAuthorName":"何丽仙"}],"doi":"","fpage":"1539","id":"cdd49920-66dd-483c-a25f-844f567a64a0","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"bd174db7-9172-4fb3-9805-881c8e8868e6","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"312c172f-222c-4d3c-98ef-fbc31674440d","keyword":"凝胶","originalKeyword":"凝胶"},{"id":"7e447a46-a40e-4559-8e48-a7b807754a85","keyword":"亚甲基蓝","originalKeyword":"亚甲基蓝"},{"id":"e82757f6-dd50-47c6-bd79-a8ea6689e426","keyword":"吸附","originalKeyword":"吸附"},{"id":"4734156c-d5c9-45f7-b2c2-7b97ca30469b","keyword":"再生","originalKeyword":"再生"}],"language":"zh","publisherId":"gsytb201406050","title":"有机膨润土/淀粉/丙烯酸复合凝胶的制备及吸附性能研究","volume":"33","year":"2014"},{"abstractinfo":"以新疆乌兰陵格膨润土为原料,进行了原矿湿法提纯、钙基膨润土钠化改型及钠基膨润土有机化改性用于钻井油基泥浆的研究.结果表明,湿法提纯前钠基膨润土的蒙脱石含量为57.55%;提纯后蒙脱石含量为60.91%.而钙基膨润土蒙脱石含量为56.53%,提纯后蒙脱石含量为59.48%.Na2CO3作为改型剂使钙基土的CEC(阳离子交换容量)提高了26.7%,钠化改型后所制得的有机土的粘度达到0.840Pa·s.季铵盐用量在(8.5~9.0)×10-4mol/g时,D1631有机土的粘度出现了明显的突变点.FTIR表明有机插层剂已进入膨润土的层间.XRD特征峰位移表明膨润土的层间距有明显增加.SEM观察也表明膨润土的层间距增大,层间厚度约为72nm.将有机膨润土应用于钻井油基泥浆中,各项指标均已达到要求,研究表明新疆乌兰陵格膨润土的高附加值开发是可行的.","authors":[{"authorName":"甄卫军","id":"cfdf772e-c94e-4917-86cf-99c86e5e7222","originalAuthorName":"甄卫军"},{"authorName":"李振江","id":"24109f72-82d1-44e1-87d5-2d838a1bafa6","originalAuthorName":"李振江"},{"authorName":"蔡香丽","id":"a570eaa5-30d7-4c72-a09f-af08463b60a2","originalAuthorName":"蔡香丽"},{"authorName":"庞桂林","id":"8edc3ad2-b048-4788-8de9-0186b751eca7","originalAuthorName":"庞桂林"}],"doi":"10.3969/j.issn.1001-1625.2005.02.006","fpage":"24","id":"bb162ffd-b23a-4c42-949e-b824656d580a","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"6fdd8a0c-a992-40f9-95d3-dbe1db382249","keyword":"膨润土","originalKeyword":"膨润土"},{"id":"10fc60b6-8e78-4f29-9fad-cc1830178d6a","keyword":"有机膨润土","originalKeyword":"有机膨润土"},{"id":"d80d2d7c-4ce1-4a97-b9e5-45e96a8b61f3","keyword":"湿法提纯","originalKeyword":"湿法提纯"},{"id":"51aab68d-588f-4b8c-b523-ed95787c931e","keyword":"钠化改型","originalKeyword":"钠化改型"},{"id":"78799c7b-d1c4-4b07-a38f-cf37203ee015","keyword":"性能表征","originalKeyword":"性能表征"}],"language":"zh","publisherId":"gsytb200502006","title":"新疆乌兰陵格膨润土的开发及性能表征","volume":"24","year":"2005"},{"abstractinfo":"以天然钙基膨润土为原料,经过提纯、钠化、有机化改性,研究了有机改性剂的类型及体系的pH值对有机膨润土性能的影响,并采用X-ray衍射分析(XRD)、傅立叶红外(FTIR)光谱分析等测试手段对其表征.研究表明,钠基土在中性偏碱的环境下,以有机阳离子季铵盐为改性剂,可以制备出性能优良的有机膨润土.","authors":[{"authorName":"刘国玉","id":"a9e57439-3963-4259-b1f9-e3c37129bce8","originalAuthorName":"刘国玉"},{"authorName":"刘曙光","id":"6605cf9b-77db-4782-95d0-ec07645a1abb","originalAuthorName":"刘曙光"}],"doi":"","fpage":"285","id":"45094fb6-d756-44fd-bf81-7d590c5fb599","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"0997ea18-008e-427a-bf47-ea594fb15c65","keyword":"膨润土","originalKeyword":"膨润土"},{"id":"0af34c2d-e67e-4f3b-963f-3aba2d43c7bb","keyword":"蒙脱石","originalKeyword":"蒙脱石"},{"id":"b14684ba-ab5c-424f-9fe4-2b286272ad44","keyword":"钠化","originalKeyword":"钠化"},{"id":"8ff7abf9-e8dd-4f9f-b44b-a78a27ee0f67","keyword":"有机化","originalKeyword":"有机化"}],"language":"zh","publisherId":"gsytb200902015","title":"膨润土的有机改性研究","volume":"28","year":"2009"},{"abstractinfo":"以十六烷基三甲基溴化铵(CTAB)为改性剂,对纯化后的膨润土进行活化改性,制得了有机改性膨润土.通过对改性剂用量、有机膨润土投加量、废水pH值及吸附时间等因素的考察,系统研究了有机改性膨润土对废水中油的吸附效果,并通过XRD分析了改性剂用量对膨润土的结构影响.结果表明,CTAB能够进入到膨润土的层间,使其层间距增大.有机改性膨润土对含油废水有较好的去除效果,在25℃,当改性剂用量为20%,有机改性膨润土投加量为9 g/L,吸附时间为60 min,pH值为6时废水中COD的去除率可达85.84%,有机膨润土处理含油废水时的等温吸附曲线更好的符合Freundlich方程.","authors":[{"authorName":"曹春艳","id":"0040ccc5-e40e-4328-ada1-5f1749e1ae28","originalAuthorName":"曹春艳"},{"authorName":"于冰","id":"5b262aff-60f2-455d-97ea-b5f09ef55983","originalAuthorName":"于冰"},{"authorName":"赵莹莹","id":"b5265ea5-e5d2-42d1-8012-e221e1dbab54","originalAuthorName":"赵莹莹"}],"doi":"","fpage":"1382","id":"a007ea26-b7e6-4be5-a7f5-a199b092cb6d","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"4975531b-2b57-4bb0-8224-4acafd88adb5","keyword":"有机改性膨润土","originalKeyword":"有机改性膨润土"},{"id":"dbc5e2d9-2141-4399-a35f-39089ccbcfc2","keyword":"十六烷基三甲基溴化铵","originalKeyword":"十六烷基三甲基溴化铵"},{"id":"7a90019e-57ee-454a-9e60-a987c86aba3f","keyword":"含油废水","originalKeyword":"含油废水"},{"id":"39a4a232-f2c2-4cfc-abd5-59a4ae207d6f","keyword":"吸附","originalKeyword":"吸附"},{"id":"f78fd22b-8275-4717-8fac-f04e986fca25","keyword":"去除率","originalKeyword":"去除率"}],"language":"zh","publisherId":"gsytb201206009","title":"有机改性膨润土处理含油废水的研究","volume":"31","year":"2012"},{"abstractinfo":"采用溴化十六烷基三甲铵(CTMAB)对天然膨润土进行了有机改性处理,并在静态条件下,进行了有机膨润土对含Cr(Ⅵ)工业废水的吸附试验.研究了CTMAB浓度、有机膨润土用量、废水pH值、搅拌时间等因素对Cr(Ⅵ)去除率的影响,确定了用有机膨润土处理含Cr(Ⅵ)废水的适宜条件.结果表明,有机膨润土能有效地除去废水中的Cr(Ⅵ),其最佳工艺条件为废水pH值3.0~5.0、搅拌时间约30 min、有机膨润土用量10 g/L,按该工艺条件对含Cr(Ⅵ)35 mg/L左右的废水进行处理,铬的去除率达到98.0%以上,处理后的水样中Cr(Ⅵ)含量小于0.50 mg/L,达到国家排放标准.","authors":[{"authorName":"杨明平","id":"fd37ee11-8e5f-47cf-a244-c9585645c3bd","originalAuthorName":"杨明平"},{"authorName":"傅勇坚","id":"92725ac4-eb97-43a6-9bcc-cdca4e1149c1","originalAuthorName":"傅勇坚"}],"doi":"10.3969/j.issn.1001-1560.2006.02.020","fpage":"67","id":"45a2425b-2911-4f92-93c7-d6c869b6e0e5","issue":"2","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"c432e02c-1384-422d-ac15-83b6089133d3","keyword":"废水处理","originalKeyword":"废水处理"},{"id":"e1f7bc81-77ad-4eec-839f-ec09fb1f8082","keyword":"含Cr(Ⅵ)废水","originalKeyword":"含Cr(Ⅵ)废水"},{"id":"95773825-86b5-45dd-9c26-d5b9ade95189","keyword":"改性有机膨润土","originalKeyword":"改性有机膨润土"},{"id":"21da079d-26af-4b6b-9de2-8a35dd2d974a","keyword":"工艺","originalKeyword":"工艺"}],"language":"zh","publisherId":"clbh200602020","title":"用有机膨润土吸附处理含铬(Ⅵ)废水的研究","volume":"39","year":"2006"}],"totalpage":11552,"totalrecord":115520}