{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以对苯<span style=\"color:red\">二</span>甲酸(PTA)、问<span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸(IPA)和硫酸肼为主要原料,通过一步法合成了<span style=\"color:red\">聚</span><span style=\"color:red\">对</span>/<span style=\"color:red\">间</span><span style=\"color:red\">苯</span>嚼<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>(<span style=\"color:red\">p</span>/<span style=\"color:red\">m-PoD</span>),并使用湿法纺丝制备出了耐高温的<span style=\"color:red\">纤维</span>.通过各种表征方法研究了IPA的引入<span style=\"color:red\">对</span><span style=\"color:red\">纤维</span>热稳定性能、力学性能、耐酸碱性的影响.通过与<span style=\"color:red\">p-POD</span>的对比,结果表明引入IPA能够使<span style=\"color:red\">POD</span>的环化率由70%提高到90%,当IPA的含量不超过10%时,其热稳定性能不会出现降低.IPA的加入能明显地提高<span style=\"color:red\">纤维</span>的耐酸性,<span style=\"color:red\">POD</span>3<span style=\"color:red\">纤维</span>在30%H2SO4中,100 h后仍有55%的强度保留率.","authors":[{"authorName":"吴萌","id":"f4d454b0-b475-4b33-839b-25a2f9c71d4e","originalAuthorName":"吴萌"},{"authorName":"张再兴","id":"9fb66479-8c4b-4fdc-b0fe-6c1c91c00117","originalAuthorName":"张再兴"},{"authorName":"施楣梧","id":"1e56188a-f16e-45b7-8e67-f3655bf8bfbe","originalAuthorName":"施楣梧"},{"authorName":"李文涛","id":"563e3b36-ea26-470f-af80-0b4a104d6424","originalAuthorName":"李文涛"},{"authorName":"叶光斗","id":"a9c0264d-a8ac-4c63-864b-d65904b8e596","originalAuthorName":"叶光斗"},{"authorName":"徐建军","id":"8f66fd67-24ca-4146-bf18-2cdc0e823cac","originalAuthorName":"徐建军"}],"doi":"","fpage":"97","id":"6da1e40d-436c-4b64-baba-5746a07d49bb","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"f76fb7be-e51e-4387-8799-5eb629f48a82","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">对</span>/<span style=\"color:red\">间</span><span style=\"color:red\">苯</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span><span style=\"color:red\">纤维</span>(<span style=\"color:red\">p</span>/<span style=\"color:red\">m-POD</span>)","originalKeyword":"聚对/间苯(口恶)二唑纤维(p/m-POD)"},{"id":"db4cf07c-8b3d-44b7-94e7-61f322ece200","keyword":"<span style=\"color:red\">间</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸","originalKeyword":"间苯二甲酸"},{"id":"77c45342-ac1a-4bdc-8e8d-089c3b30f039","keyword":"共聚","originalKeyword":"共聚"},{"id":"20f528f3-2411-4256-bd63-2caba052f6b1","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"gfzclkxygc200902028","title":"<span style=\"color:red\">间</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>甲酸含量<span style=\"color:red\">对</span>芳香族<span style=\"color:red\">聚</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span><span style=\"color:red\">纤维</span>性能的影响","volume":"25","year":"2009"},{"abstractinfo":"以对氰基氯苄和4,6-<span style=\"color:red\">二</span>氨基<span style=\"color:red\">间</span><span style=\"color:red\">苯</span><span style=\"color:red\">二</span>酚为主要原料,首先合成2,6-<span style=\"color:red\">二</span>(4-氯甲基苯基)<span style=\"color:red\">苯</span>并[1-2,4-5']<span style=\"color:red\">二</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>,又通过2,6-<span style=\"color:red\">二</span>(4-氯甲基苯基)<span style=\"color:red\">苯</span>并[1-2,4-5']<span style=\"color:red\">二</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>与对苯<span style=\"color:red\">二</span>甲醛的Wittig反应,设计合成了一种新的主链插入<span style=\"color:red\">苯</span>并[1-2,4-5']<span style=\"color:red\">二</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>环的PPV聚合物(BO-PPV),通过红外光谱、核磁共振谱、凝胶渗透色谱等分析方法<span style=\"color:red\">对</span>其结构进行了表征.并研究了该聚合物的光电热物理特性,结果表明:该聚合物的Tg为235℃,Td为410℃,电致发光谱峰值λmax为494 nm,由ITO/BO-PPV/A1组成的单层器件在电压15伏特,发光亮度可达650 cd/cm2,发光效率0.24cd/A.","authors":[{"authorName":"张田林","id":"6bcf705f-a9af-479d-9a56-e262e679932d","originalAuthorName":"张田林"},{"authorName":"张晓波","id":"68073dca-fd50-41c2-b7a5-cd0498d082a8","originalAuthorName":"张晓波"},{"authorName":"马娟娟","id":"a176be2c-477e-4103-a9e8-df4e133488ad","originalAuthorName":"马娟娟"}],"doi":"10.3969/j.issn.1673-2812.2007.01.028","fpage":"111","id":"9ac1ca76-24fe-44e6-abde-a7299e3addcb","issue":"1","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"326ff3e3-b595-498c-872b-040ebb87e1ba","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">对</span><span style=\"color:red\">苯</span>撑乙烯","originalKeyword":"聚对苯撑乙烯"},{"id":"00713b11-9b90-44d6-bc43-951731a3df04","keyword":"<span style=\"color:red\">苯</span>并<span style=\"color:red\">二</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>","originalKeyword":"苯并二(口恶)唑"},{"id":"7a040be0-d193-4732-b837-2f2dfd4be0d9","keyword":"合成","originalKeyword":"合成"},{"id":"85d24e52-b956-4c84-b4b6-78990daad9bd","keyword":"光电特性","originalKeyword":"光电特性"}],"language":"zh","publisherId":"clkxygc200701028","title":"主链插入<span style=\"color:red\">苯</span>并<span style=\"color:red\">二</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>环的PPV聚合物的合成及其光电性质","volume":"25","year":"2007"},{"abstractinfo":"2,2-双(4-羟基苯基)-1,1,1,3,3,3-六氟丙烷(BHPFP)、三氟乙酸(TFAA)和硝酸钾(PN)在20～30 ℃的温度范围内反应,合成得到了2,2-双(3-硝基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷(BNHPFP);随后,在Pd/C-H2的还原体系中,被进一步还原,得到了含氟<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>单体2,2-双(3-氨基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷(BAHPFP).利用差示量热计(DSC)、WRR光学熔点仪、傅立叶转换红外光谱仪(FT-IR)、元素分析仪和核磁共振仪(NMR)等仪器,<span style=\"color:red\">对</span>它们进行了表征.","authors":[{"authorName":"虞鑫海","id":"163ed24b-eba7-4667-97d1-b4e57313479b","originalAuthorName":"虞鑫海"},{"authorName":"徐永芬","id":"b51d7af4-2869-435b-a7ae-065095c25957","originalAuthorName":"徐永芬"},{"authorName":"赵炯心","id":"3755de7f-5d6f-4105-a2e2-7837e51a07bb","originalAuthorName":"赵炯心"},{"authorName":"傅菊蓀","id":"04b11594-1107-4d3b-9567-bde42ec8288c","originalAuthorName":"傅菊蓀"}],"doi":"10.3969/j.issn.1009-9239.2007.04.001","fpage":"1","id":"aa8df5a3-7169-4e09-91a7-67050f0da16d","issue":"4","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"d4ad1f87-07e0-4607-8b42-4248070f28ab","keyword":"含氟<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>单体","originalKeyword":"含氟聚苯并(口恶)唑单体"},{"id":"2c60a1dc-9cbe-4163-9593-a482645d64c5","keyword":"2,2-双(3-硝基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷","originalKeyword":"2,2-双(3-硝基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷"},{"id":"a4cacd9b-1579-4caf-b365-e1fa0fae2158","keyword":"2,2-双(3-氨基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷","originalKeyword":"2,2-双(3-氨基4-羟基苯基)-1,1,1,3,3,3-六氟丙烷"},{"id":"3bc43ba6-8637-4cb8-ac32-99960c4889f4","keyword":"合成","originalKeyword":"合成"},{"id":"a34a1657-7311-415c-8d0d-a36f6112881b","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"jycltx200704001","title":"含氟<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>单体的合成与表征","volume":"40","year":"2007"},{"abstractinfo":"用廉价的均<span style=\"color:red\">苯</span>四甲酸<span style=\"color:red\">二</span>酐(PMDA)代替部分或全部3,3′,4,4′-联苯四羧酸<span style=\"color:red\">二</span>酐(BPDA),与3,3′-<span style=\"color:red\">二</span>羟基联苯胺(HAB)进行缩聚,然后脱水酰亚胺化,制备了5种聚酰亚胺(PI). TGA分析显示,这些PI的DTG曲线为2个峰,可分为生成<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>(PBO)再发生PBO分解的2个阶段. PI膜在500 ℃通N2气1 h,所得聚合物膜的DTG曲线仅为1个峰,表明这些PI可充分转变成PBO. 用FTIR表征了PI和PBO膜的结构. PBO的耐热性(用失重5%时的温度Td表示)比PI高100～170 ℃. PMDA-HAB PBO的耐热性高于BPDA-HAB PBO. HAB-BPDA-PMDA PBO的耐热性优于<span style=\"color:red\">二</span>元PBO. 当PMDA在<span style=\"color:red\">二</span>酐单体中所占的摩尔分数为75%时,PBO的Td高达643 ℃.","authors":[{"authorName":"高原","id":"8b527e1d-2ad2-442c-afb5-4fe477c0d084","originalAuthorName":"高原"},{"authorName":"张茂根","id":"e17183d4-0243-4a70-95ab-0c250925dd18","originalAuthorName":"张茂根"},{"authorName":"王昉","id":"f59e3dea-4ca8-44a6-b066-d7ed365e9cbf","originalAuthorName":"王昉"},{"authorName":"王炳祥","id":"52360b3b-85db-4ac1-94e4-f00c5bedcb61","originalAuthorName":"王炳祥"},{"authorName":"沈健","id":"ea8cd8f2-44f0-4cc1-aed7-99db1c16ba54","originalAuthorName":"沈健"}],"doi":"10.3969/j.issn.1000-0518.2005.10.012","fpage":"1096","id":"0142a8a4-90d6-47bc-831d-e6f0f38902cf","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a2e6de59-9580-4a4c-96f1-3daef18001c3","keyword":"均<span style=\"color:red\">苯</span>四甲酸<span style=\"color:red\">二</span>酐","originalKeyword":"均苯四甲酸二酐"},{"id":"1d0e05ac-7e05-40ff-92c2-1d0dcab5e451","keyword":"联苯四羧酸<span style=\"color:red\">二</span>酐","originalKeyword":"联苯四羧酸二酐"},{"id":"c762bd77-d982-4fc5-930f-c23f9f4acee3","keyword":"<span style=\"color:red\">二</span>羟基联苯胺","originalKeyword":"二羟基联苯胺"},{"id":"f1d8568f-65ce-4f1f-a0d7-df4fac28a6e9","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"1d6979e4-0dc9-4691-b263-6d3fbdb0a747","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>","originalKeyword":"聚苯并(口恶)唑"},{"id":"536cd0c4-b692-452e-9a94-9cab7b504f3c","keyword":"耐热性","originalKeyword":"耐热性"}],"language":"zh","publisherId":"yyhx200510012","title":"PMDA-BPDA-HAB<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>的合成及耐热性","volume":"22","year":"2005"},{"abstractinfo":"采用9,10-<span style=\"color:red\">二</span>氢-9-氧杂-10-磷菲-10-氧化物(DOPO)与<span style=\"color:red\">二</span><span style=\"color:red\">苯</span>甲烷<span style=\"color:red\">二</span>胺型<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪(BOZ-<span style=\"color:red\">M</span>)混合,制备了固化浇铸体.采用差示量热扫描(DSC)、动态机械分析(DMA)、垂直燃烧试验、热失重分析(TGA)及扫描电镜(SEM)<span style=\"color:red\">对</span>浇铸体性能进行了分析和研究.结果表明,DOPO可以和<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂发生开环加成反应,进而将DOPO分子结合到<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂的网络结构中;当DOPO的含量大于5%,即可以使<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂的阻燃性达到UL-94V0级;DOPO的加入,降低了<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂的交联密度和玻璃化转变温度,但提高了它的高温残炭量.","authors":[{"authorName":"凌鸿","id":"8373920d-2168-4873-bb62-e2eeb2f24b60","originalAuthorName":"凌鸿"},{"authorName":"叶小舟","id":"673982ca-0a81-49b3-b1a7-d66c7b5dc6bc","originalAuthorName":"叶小舟"},{"authorName":"顾宜","id":"9e7fff0e-3ec5-4abe-a949-cea0bfbba3fe","originalAuthorName":"顾宜"}],"doi":"","fpage":"86","id":"c6871807-1c6b-40ea-bd9b-9d60e875ca26","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ac105b76-7c5e-4526-9b84-8b3389145e33","keyword":"<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪","originalKeyword":"苯并(口恶)嗪"},{"id":"a8e0e5ca-73dc-4028-9402-e6131e2f01d5","keyword":"9,10-<span style=\"color:red\">二</span>氢-9-氧杂-10-磷杂菲-10-氧化物","originalKeyword":"9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物"},{"id":"773f0422-8ad4-4162-b9b6-1ec750f7768b","keyword":"阻燃","originalKeyword":"阻燃"}],"language":"zh","publisherId":"gfzclkxygc201011023","title":"DOPO<span style=\"color:red\">对</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂的阻燃改性","volume":"26","year":"2010"},{"abstractinfo":"文中简要概述了<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺的性能和应用,并<span style=\"color:red\">对</span><span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺的合成作了较详细的综述,特别阐述了在多<span style=\"color:red\">聚</span>磷酸中\"一锅法\"合成<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺合成的新方向,以及展望了<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺合成研究的前景.","authors":[{"authorName":"陈向群","id":"1d7ef1a7-4ea8-4fbe-a55d-ff1c743c8294","originalAuthorName":"陈向群"},{"authorName":"王娟","id":"027d609c-0e87-40e1-9af7-0dc782bf5857","originalAuthorName":"王娟"},{"authorName":"孙秋","id":"59b8e8c9-500c-419b-8bbc-8c37b51c9180","originalAuthorName":"孙秋"},{"authorName":"蔡伟","id":"05d4d532-483a-4652-89e4-816c979b77ea","originalAuthorName":"蔡伟"},{"authorName":"王福平","id":"45d29831-9027-4b45-8b26-add7a025590c","originalAuthorName":"王福平"}],"doi":"","fpage":"11","id":"4a385d90-26d0-479e-93e9-6e5ca1c2ff5d","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"a6052fa3-08d3-4830-9f43-ba7996529ef5","keyword":"<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口","originalKeyword":"聚苯并口"},{"id":"ec7aae66-8aad-451e-8623-638fb647aad0","keyword":"<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺","originalKeyword":"恶唑-酰亚胺"},{"id":"df7fd266-a6a9-4591-b0be-90f195e05489","keyword":"合成","originalKeyword":"合成"},{"id":"0fcce786-1d0a-452c-820a-6f60498fc4a7","keyword":"多<span style=\"color:red\">聚</span>磷酸","originalKeyword":"多聚磷酸"},{"id":"a9c64f48-7949-4c18-ad0e-f5ed07576f20","keyword":"\"一锅法\"","originalKeyword":"\"一锅法\""}],"language":"zh","publisherId":"gfzclkxygc200812003","title":"<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并口<span style=\"color:red\">恶</span><span style=\"color:red\">唑</span>-酰亚胺的合成方法","volume":"24","year":"2008"},{"abstractinfo":"为改善芳香族<span style=\"color:red\">聚</span>噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>的加工性,合成了一种含噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>的双氟单体,将其与<span style=\"color:red\">二</span>酚单体进行溶液缩聚,得到一系列含有醚键与C(CH3)2,CCH3C6H5等官能团的新型<span style=\"color:red\">聚</span>(芳基醚1,3,4-噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>)(PE()D),其黏度达1.0 dL/g,噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>成环率达100%,并通过核磁氢谱(1H-NMR)和元素分析(EA)证实了其化学结构.通过热重分析(TGA)<span style=\"color:red\">对</span>嘞的热稳定性进行了表征,结果表明,这些聚合物具有优良的热性能.通过溶解性试验表明PEOD能够溶解于三氯甲烷(CHCl3)、<span style=\"color:red\">二</span>氯甲烷(CH2Cl2)、四氢呋喃(THF)等有机溶剂,其溶解性比<span style=\"color:red\">聚</span><span style=\"color:red\">对</span><span style=\"color:red\">苯</span>撑噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>(<span style=\"color:red\">p-POD</span>)及<span style=\"color:red\">对</span><span style=\"color:red\">间</span><span style=\"color:red\">苯</span>噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>(<span style=\"color:red\">p</span>/<span style=\"color:red\">m-POD</span>)有了较大的改善.","authors":[{"authorName":"马莹莹","id":"bc91a860-1c15-4d8f-87f7-4b5eac0a18cd","originalAuthorName":"马莹莹"},{"authorName":"杨潇","id":"f6c472e8-9852-4da0-8e10-e41d74c2447d","originalAuthorName":"杨潇"},{"authorName":"周万立","id":"f56bf96d-eea8-41e8-a7c7-60cb56a1e9ce","originalAuthorName":"周万立"},{"authorName":"叶光斗","id":"8cb32ded-1498-4760-9184-d0654c600b73","originalAuthorName":"叶光斗"},{"authorName":"徐建军","id":"c34bb810-fa79-479f-b145-43ae59506bb0","originalAuthorName":"徐建军"}],"doi":"","fpage":"21","id":"45801e45-6a9a-426f-b5cf-33ef92ae0561","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4eaf371f-caa2-465c-b7f0-c2b0defe0fe5","keyword":"4,4'<span style=\"color:red\">二</span>氟-(2,5-<span style=\"color:red\">二</span>苯基)噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>","originalKeyword":"4,4'二氟-(2,5-二苯基)噁二唑"},{"id":"9883c38f-860a-4b90-943c-2bef23a33a9e","keyword":"<span style=\"color:red\">聚</span>(芳基醚1,3,4-噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>)","originalKeyword":"聚(芳基醚1,3,4-噁二唑)"},{"id":"172c2c14-f70b-42d1-8589-dc5ef4a06d63","keyword":"溶解性","originalKeyword":"溶解性"}],"language":"zh","publisherId":"gfzclkxygc201104006","title":"<span style=\"color:red\">聚</span>(芳基醚1,3,4-噁<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>)类聚合物的合成及表征","volume":"27","year":"2011"},{"abstractinfo":"将邻<span style=\"color:red\">苯</span>甲酰磺酰亚胺、1.3,4-(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>2个杂环同时引入到酰基硫脲中,合成了12种新的N'-(5-芳基-1,3,4.(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-基)-N-(邻<span style=\"color:red\">苯</span>磺酰甲酰亚胺乙酰基)硫脲化合物,化合物的结构均经元素分析、1H NMR和IR 等测试技术得以确证.抑菌法生物活性测试结果表明,大部分化合物<span style=\"color:red\">对</span>黄瓜灰霉病菌、油菜菌核病菌抑制效果很好,特别是化合物5b和5l<span style=\"color:red\">对</span>5种病菌抑制率均在87%以上,有的病菌抑制率达到100%.","authors":[{"authorName":"覃章兰","id":"00b6e7f0-3ca8-46a9-8c08-c240a37a4e53","originalAuthorName":"覃章兰"},{"authorName":"李超","id":"3a76ce57-8166-4275-bee7-ee10ce86fdfa","originalAuthorName":"李超"}],"doi":"10.3969/j.issn.1000-0518.2009.04.004","fpage":"388","id":"dec720c2-2e58-43aa-83de-ea0e4f8361a7","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3840ef0b-d478-416a-b4a9-de88c6018123","keyword":"N'-(芳基(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>基)-N-(邻<span style=\"color:red\">苯</span>磺酰甲酰亚胺乙酰基)硫脲","originalKeyword":"N'-(芳基(口恶)二唑基)-N-(邻苯磺酰甲酰亚胺乙酰基)硫脲"},{"id":"17655d27-1d64-46ae-8214-c49dcb53986f","keyword":"合成","originalKeyword":"合成"},{"id":"4900d4a8-ccd6-4471-ab0a-b60321171e5a","keyword":"抑菌活性","originalKeyword":"抑菌活性"}],"language":"zh","publisherId":"yyhx200904004","title":"N'-(5-芳基-1,3,4(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">二</span><span style=\"color:red\">唑</span>-2-基)-N-(邻<span style=\"color:red\">苯</span>磺酰甲酰亚胺乙酰基)硫脲的合成及抑菌活性","volume":"26","year":"2009"},{"abstractinfo":"采用锥形量热测试和垂直燃烧法UL-94研究了氢氧化镁<span style=\"color:red\">对</span><span style=\"color:red\">苯</span>井(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂阻燃性能的影响.结果表明,加入氢氧化镁后<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂的垂直燃烧时间缩短,阻燃性提高,当氢氧化镁加入量大于等于20％时,阻燃性达到UL-94 V0级.锥形量热的测试结果表明,加入20％氢氧化镁后,<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪的引燃时间由33s延长至52s;热释放速率的最大值由635.4kW/<span style=\"color:red\">m</span>2降低至255.93kW/<span style=\"color:red\">m</span>2;总释热量由99.1MJ/<span style=\"color:red\">m</span>2降低为67.72MJ/<span style=\"color:red\">m</span>2；总烟释放量由2578.5<span style=\"color:red\">m</span>2/<span style=\"color:red\">m</span>2降低至1686.19<span style=\"color:red\">m</span>2/<span style=\"color:red\">m</span>2.对于<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪树脂而言,氢氧化镁是一类既阻燃又抑烟的环境友好型阻燃剂.","authors":[{"authorName":"凌鸿","id":"5313d736-a4d0-4fb9-8ff1-799312831af4","originalAuthorName":"凌鸿"},{"authorName":"顾宜","id":"872574c0-bc35-4604-b509-c33e61d92af6","originalAuthorName":"顾宜"}],"doi":"","fpage":"76","id":"edbbb5ce-1b96-4a47-bf4a-16612499ab86","issue":"7","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"f590e279-3304-4da8-bf79-b48bb701cdfc","keyword":"<span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪","originalKeyword":"苯并(口恶)嗪"},{"id":"1ad6295a-df68-4855-bad3-56c449a22115","keyword":"氢氧化镁","originalKeyword":"氢氧化镁"},{"id":"0197cae4-5688-4af3-939d-227584bcb105","keyword":"阻燃","originalKeyword":"阻燃"},{"id":"b7ef3435-dfb5-4790-8f26-96e82df868ee","keyword":"锥形量热","originalKeyword":"锥形量热"}],"language":"zh","publisherId":"gfzclkxygc201307019","title":"氢氧化镁阻燃<span style=\"color:red\">聚</span><span style=\"color:red\">苯</span>并(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)嗪","volume":"29","year":"2013"},{"abstractinfo":"以2,4-<span style=\"color:red\">二</span>苯基甲烷<span style=\"color:red\">二</span>异氰酸酯(MDI-50)、环氧树脂(E-54)为原料,分别以Cr3+、AlCl3和AlCl3·HMPA为催化剂,在100℃合成了<span style=\"color:red\">聚</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮/异氰脲酸酯.用红外光谱研究了异氰脲酸酯与(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮的反应历程,用热重分析表征了(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮/异氰脲酸酯的比例与耐热性能的关系.结果表明,3种催化剂首先快速催化氨基甲酸酯/脲基甲酸酯以及异氰脲酸酯三<span style=\"color:red\">聚</span>环的生成;(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮环逐渐形成,随着受热时间延长,氨基甲酸酯/脲基甲酸酯和异氰脲酸酯逐渐解聚与环氧反应转化为(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮环.材料的耐热性能随(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮含量的增加而增强,最大热失重温度较环氧树脂提高了50℃,达434℃,且750℃时的残炭率提高了3倍.","authors":[{"authorName":"张晓灵","id":"be1f0a49-6e08-46f6-bbbf-337561565c05","originalAuthorName":"张晓灵"},{"authorName":"霍娜丽","id":"e04bbc2b-8395-4ac9-9a0e-b1dcc70949a6","originalAuthorName":"霍娜丽"},{"authorName":"杨加栋","id":"0eb9e20c-d201-4d8b-ad73-5f80dda4adbb","originalAuthorName":"杨加栋"},{"authorName":"张杰","id":"dfbdc4fa-730f-4981-b1cf-37853947fb50","originalAuthorName":"张杰"},{"authorName":"胡春圃","id":"6087df7e-6b13-4281-abbe-77d411f199fb","originalAuthorName":"胡春圃"}],"doi":"","fpage":"36","id":"67f21162-e4fe-4dad-8604-0a7fcb8121eb","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7595ce76-0c21-4e0c-96dc-f74c81eb1fde","keyword":"低温合成","originalKeyword":"低温合成"},{"id":"da02e3cb-8c2f-469a-8c77-80a30324edda","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"f7a4b9e5-2ecb-4c42-a4ea-3c92070ad2c9","keyword":"催化剂","originalKeyword":"催化剂"},{"id":"1ed5fbce-d716-468c-8d69-c3fd643c3d70","keyword":"(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮","originalKeyword":"(口恶)唑烷酮"},{"id":"dd65c22f-8e59-4794-b38d-94e5c8a6d22b","keyword":"异氰脲酸酯","originalKeyword":"异氰脲酸酯"}],"language":"zh","publisherId":"gfzclkxygc201502008","title":"<span style=\"color:red\">聚</span>(<span style=\"color:red\">口</span><span style=\"color:red\">恶</span>)<span style=\"color:red\">唑</span>烷酮/异氰脲酸酯的低温合成与耐热性能","volume":"31","year":"2015"}],"totalpage":16447,"totalrecord":164465}