{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"利用开环接枝聚合反应, 在超高分子量苯乙烯/马来酸酐(SMA)交替<span style=\"color:red\">共聚物</span>中引入具有多羟基结构的生物相容<span style=\"color:red\">性</span>分子盐酸葡萄糖(GLA·HCl), 生成<span style=\"color:red\">糖基</span><span style=\"color:red\">两亲性</span><span style=\"color:red\">刷</span><span style=\"color:red\">状</span><span style=\"color:red\">共聚物</span>(SMA-g-GLA),用1H NMR和GPC分别表征SMA-g-GLA的结构与分子量.以SMA-g-GLA为膜添加剂,通过浸没沉淀相转化法制备PVDF共混合金膜,纯水接触角测定结果表明,<span style=\"color:red\">糖基</span>化<span style=\"color:red\">两亲性</span><span style=\"color:red\">刷</span><span style=\"color:red\">状</span><span style=\"color:red\">共聚物</span>的加入显著提高了膜的表面亲水性; BSA静态吸附实验研究表明,SMA-g-GLA膜添加剂有效地改善了PVDF膜的静态抗蛋白质污染性能.","authors":[{"authorName":"李建华","id":"98f4379d-9e75-4bb2-b84c-c006b7d9f3d4","originalAuthorName":"李建华"},{"authorName":"徐又一","id":"717c042b-4d51-4a1a-8f3b-2de93ae9d9e9","originalAuthorName":"徐又一"}],"doi":"","fpage":"1650","id":"a8bc5396-a44f-477c-97b4-d8b1f789b332","issue":"9","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"ee6937bd-68df-4658-8b54-bf6223f3bca8","keyword":"超高分子量SMA","originalKeyword":"超高分子量SMA"},{"id":"8cb34137-232b-43f0-97d3-9d65549e29c0","keyword":"<span style=\"color:red\">糖基</span><span style=\"color:red\">两亲性</span><span style=\"color:red\">刷</span><span style=\"color:red\">状</span><span style=\"color:red\">共聚物</span>","originalKeyword":"糖基两亲性刷状共聚物"},{"id":"34bfa5ca-9bf8-42e1-8e95-6e23e716eab9","keyword":"共混合金膜","originalKeyword":"共混合金膜"},{"id":"eeb467af-409b-4fe7-b604-34dee837ab6f","keyword":"亲水性","originalKeyword":"亲水性"}],"language":"zh","publisherId":"gncl201009043","title":"苯乙烯/马来酸酐<span style=\"color:red\">糖基</span><span style=\"color:red\">共聚物</span>对PVDF膜的<span style=\"color:red\">亲</span>水化改性研究","volume":"41","year":"2010"},{"abstractinfo":"对新型的<span style=\"color:red\">两亲性</span>生物降解接枝<span style=\"color:red\">共聚物</span>羟丙基纤维素接枝聚己内酯(HPC-g-PCL)的综合性能进行了测试.X射线衍射结果表明,接枝<span style=\"color:red\">共聚</span>有效地降低了PCL的结晶度,且随着PCL链段含量的降低,接枝<span style=\"color:red\">共聚物</span>的结晶度相应下降.DSC结果表明,与PCL均聚<span style=\"color:red\">物</span>相比,所得接枝<span style=\"color:red\">共聚物</span>的Tm、Tc和Xc均明显降低,且随着PCL链段含量的降低而不断下降;同时,与先熔融后冷却相比,室温下的<span style=\"color:red\">共聚物</span>溶液浇注膜,其结晶程度更完善.水解降解实验结合GPC曲线和SEM照片结果表明,与均聚<span style=\"color:red\">物</span>PCL相比,接枝<span style=\"color:red\">共聚物</span>更易发生降解.","authors":[{"authorName":"王彩旗","id":"30f00ce0-3df2-49c9-b9ad-bd69106fb142","originalAuthorName":"王彩旗"},{"authorName":"谭惠民","id":"a6be79eb-fe2d-4bfb-9cef-8d63615a1c83","originalAuthorName":"谭惠民"},{"authorName":"董宇平","id":"4ae5eda9-42f2-4ea4-89e1-e4039de7feb7","originalAuthorName":"董宇平"},{"authorName":"李广涛","id":"91ba48e0-a0d1-4cdc-8b30-ab90d88ae43d","originalAuthorName":"李广涛"}],"doi":"","fpage":"123","id":"8c1693eb-1615-4104-aa71-64680896dc6c","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c390a03a-859c-48bb-8922-3f1e150c9ab8","keyword":"羟丙基纤维素","originalKeyword":"羟丙基纤维素"},{"id":"51dd4096-1f97-411e-a5f1-b23531146230","keyword":"己内酯","originalKeyword":"己内酯"},{"id":"ae02b3d4-0495-4313-b13d-b612e9c7f892","keyword":"生物降解","originalKeyword":"生物降解"},{"id":"768643d0-91bf-47ed-b4eb-caae14337505","keyword":"接枝<span style=\"color:red\">共聚物</span>","originalKeyword":"接枝共聚物"},{"id":"da947b7e-dfc6-4c16-a45c-adc5a2230070","keyword":"<span style=\"color:red\">两亲性</span>","originalKeyword":"两亲性"}],"language":"zh","publisherId":"gfzclkxygc200601031","title":"新型<span style=\"color:red\">两亲性</span>生物降解接枝<span style=\"color:red\">共聚物</span>的性能","volume":"22","year":"2006"},{"abstractinfo":"通过对碳纳米管进行表面改性制得具有引发ATRP反应活性的碳纳米管(MWNT-Br),以MWNT-Br作引发剂经过<span style=\"color:red\">两</span>次ATRP反应将聚乙烯基吡咯烷酮(PVP)和聚甲基丙烯酸特丁酯(PtBMA)先后接枝到多壁碳纳米管表面制得<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>接枝的碳纳米管(MWNT-PVP-b-PtBMA),用红外光谱、热失重和透射电镜对<span style=\"color:red\">两亲性</span>碳纳米管进行了表征.并考察了修饰前弱<span style=\"color:red\">亲</span>油性的纯碳纳米管、酸化后亲水性的碳纳米管和修饰后<span style=\"color:red\">两亲性</span>碳纳米管这3种碳纳米管在水和氯仿形成的<span style=\"color:red\">两</span>相体系中的分散情况,观察到所制备的<span style=\"color:red\">两亲性</span>碳纳米管能够均匀分散在油水<span style=\"color:red\">两</span>相界面上.","authors":[{"authorName":"王国建","id":"86de0271-051e-4b7c-9365-1d6e87a3c475","originalAuthorName":"王国建"},{"authorName":"陶春锋","id":"10b59ed9-81ad-4133-a601-233b24aa2598","originalAuthorName":"陶春锋"},{"authorName":"董玥","id":"eed0281a-6152-49e7-961e-043b5f811ab4","originalAuthorName":"董玥"}],"doi":"","fpage":"1022","id":"d9312ce1-cb62-4471-ace9-cb8e65129f25","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"b62383eb-530e-4c56-bfbf-54107e99e434","keyword":"碳纳米管","originalKeyword":"碳纳米管"},{"id":"fa5dd30a-2cfd-412d-a557-bf9288328b73","keyword":"聚乙烯基吡咯烷酮","originalKeyword":"聚乙烯基吡咯烷酮"},{"id":"3095bf15-3cfe-4c21-adda-d3e7ce324377","keyword":"聚甲基丙烯酸特丁酯","originalKeyword":"聚甲基丙烯酸特丁酯"},{"id":"993da332-a2f6-4fc1-a160-fac5c872dbab","keyword":"<span style=\"color:red\">两亲性</span>","originalKeyword":"两亲性"},{"id":"7b8caf15-a5f8-4a98-98f1-e960291b1386","keyword":"原子转移自由基聚合","originalKeyword":"原子转移自由基聚合"}],"language":"zh","publisherId":"gncl200706049","title":"<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>改性的多壁碳纳米管的制备","volume":"38","year":"2007"},{"abstractinfo":"从分子结构设计出发,合成了一系列可用于聚偏氟乙烯(PVDF)膜共混改性的<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>,这些<span style=\"color:red\">共聚物</span>具有不同的分子结构(包括接枝、嵌段、交替、超支化等)和链形态(包括梳<span style=\"color:red\">状</span>、哑铃<span style=\"color:red\">状</span>、链球状等).将这些<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>与PVDF膜材料进行溶液共混,通过溶液相转化法制备共混合金膜.在对成膜体系热力学和动力学分析的基础上,调控成膜工艺参数,实现了对PVDF共混合金膜的结构控制.通过研究发现:<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>在成膜过程中自发地向膜表面迁移富集,并进行自组装,显著改善了PVDF膜的亲水性和抗污染性能.通过<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>中的反应<span style=\"color:red\">性</span>基团,还可在膜表面固定某些功能分子或基团,进一步对膜进行表面修饰.","authors":[{"authorName":"徐又一","id":"64cc8499-874f-40d2-b302-2d3d91b9c85f","originalAuthorName":"徐又一"},{"authorName":"章帆","id":"9d8d129b-5d0f-40a4-990b-0ecaedbc916e","originalAuthorName":"章帆"},{"authorName":"朱利平","id":"f257fe59-687b-4d51-a128-6b305907c57e","originalAuthorName":"朱利平"},{"authorName":"王建宇","id":"db45df76-8d8f-4ee4-acb0-72989e17bf41","originalAuthorName":"王建宇"}],"doi":"10.3969/j.issn.1007-8924.2008.02.001","fpage":"1","id":"c5ed6921-aca8-4ac9-a3fe-db53410b22cb","issue":"2","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"6361da0d-ce2b-4aad-8f44-abf32028e8d3","keyword":"<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>","originalKeyword":"两亲性共聚物"},{"id":"45dde465-687b-46be-a9f4-7a9afcb4748e","keyword":"聚偏氟乙烯","originalKeyword":"聚偏氟乙烯"},{"id":"ceeb3b94-fae3-4994-aa23-878e45a6ee90","keyword":"结构控制","originalKeyword":"结构控制"},{"id":"c143bc71-0baf-455e-8941-fb44d5461dd7","keyword":"表面自组装","originalKeyword":"表面自组装"}],"language":"zh","publisherId":"mkxyjs200802001","title":"<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>与PVDF共混合金膜的结构控制与表面自组装行为","volume":"28","year":"2008"},{"abstractinfo":"以2-苄基三硫代碳酸酯基乙醇为引发剂,在辛酸亚锡催化下引发丙交酯(LA)开环聚合,合成大分子链转移剂PLA macro-CTA,加入第二单体聚甲基丙烯酸N,N-二甲氨基乙酯(DMAEMA),通过可逆—加成—断裂链转移(RAFT)自由基聚合,得到<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>PLA-b-PDMAEMA.采用核磁共振光谱(1HNMR和13 CNMR)、红外光谱(FT-IR)及凝胶色谱(GPC)对合成的<span style=\"color:red\">共聚物</span>化学结构进行表征,并通过接触角测试和热重分析(TGA)对其进行性能测试.结果表明成功合成了嵌段<span style=\"color:red\">共聚物</span>且分子量分布指数较窄；引入PDMAEMA链段后聚乳酸的热稳定性和亲水性得到提高.","authors":[{"authorName":"刘真真","id":"55538736-d5b9-481c-873a-ef92dd917f18","originalAuthorName":"刘真真"},{"authorName":"宁俊锟","id":"05ed291b-3cc1-41f6-bb04-c9d433100ff9","originalAuthorName":"宁俊锟"},{"authorName":"史新峰","id":"480bdba2-d85d-42e2-9fd4-a10ec5556d0b","originalAuthorName":"史新峰"},{"authorName":"宋晴","id":"03eb11ea-5573-4056-a949-6152b2825958","originalAuthorName":"宋晴"},{"authorName":"聂康明","id":"9db139c8-84d4-4554-a717-637a12e16a0f","originalAuthorName":"聂康明"}],"doi":"","fpage":"74","id":"d6cc5231-8b25-4826-8f1a-daf0a2be0634","issue":"8","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"e840c101-5348-40b9-b34a-25eab707b390","keyword":"<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>","originalKeyword":"两亲性嵌段共聚物"},{"id":"72fc74e7-b3ab-439b-bc4b-6a918b30e24b","keyword":"RAFT聚合","originalKeyword":"RAFT聚合"},{"id":"c06b2cdb-0488-4587-84f5-2032bf4afc34","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"cldb201308020","title":"<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>PLA-b-PDMAEMA的合成及性能研究","volume":"27","year":"2013"},{"abstractinfo":"采用可逆加成-断裂链转移(RAFT)聚合法制备了以苯乙烯-马来酸酐交替<span style=\"color:red\">共聚物</span>(PSMA)与聚乙二醇甲基丙烯酸酯(MAPEG)组成的<span style=\"color:red\">共聚物</span>(PS-MA-b-PMAPEG)，经4-氨基偶氮苯(4-AAB)修饰得光响应<span style=\"color:red\">性</span><span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span> P(St-al-Ma/azo-MaIM)-b-PMAPEG.用红外光谱(FT-IR )、核磁共振(1 H NMR)、凝胶渗透色谱(GPC)对其结构进行表征.此<span style=\"color:red\">共聚物</span>在水中可自组装形成胶束，由透射电子显微镜(TEM)和动态光散射(DLS )表征可知胶束直径约100 nm.用紫外-可见光谱法(UV-Vis)研究胶束溶液的吸光度随光照时间的变化；DLS 和扫描电子显微镜(SEM)观察紫外光和可见光辐射对胶束粒径的影响，结果表明，胶束经365 nm 紫外光照射后，偶氮苯由反式结构转变成顺式结构，粒径增大；再经420 nm 可见光照射，偶氮苯结构又从顺式转变回反式，粒径减小到初始值.","authors":[{"authorName":"韩晗","id":"713554bc-7588-4530-96aa-81a742c7f539","originalAuthorName":"韩晗"},{"authorName":"袁金芳","id":"5476249e-8270-4310-a52e-eca49d66fba5","originalAuthorName":"袁金芳"},{"authorName":"高青雨","id":"7a6b5b00-978d-4edb-8f2c-397640722c6c","originalAuthorName":"高青雨"}],"doi":"10.3969/j.issn.1001-9731.2015.09.007","fpage":"9036","id":"8fc2f37a-418b-4b1a-b64e-7ccc11085246","issue":"9","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"9ed09d74-90d2-45fe-b36c-1b59372f4deb","keyword":"<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>","originalKeyword":"两亲性嵌段共聚物"},{"id":"45b5ce00-50fb-4ff6-b329-055ac92b2def","keyword":"偶氮苯","originalKeyword":"偶氮苯"},{"id":"e33d672e-cc86-474a-9a56-7d44c6133534","keyword":"光响应<span style=\"color:red\">性</span>","originalKeyword":"光响应性"},{"id":"192e8535-bf0e-4c61-b43c-c5f83e3c28e8","keyword":"自组装","originalKeyword":"自组装"},{"id":"a9270ebf-5a75-45dd-bd60-64590cb50b67","keyword":"光致异构","originalKeyword":"光致异构"}],"language":"zh","publisherId":"gncl201509007","title":"新型偶氮功能化<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>的合成及其光响应行为?","volume":"","year":"2015"},{"abstractinfo":"考察了星形<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>-C(CH2OCOCH2- PS80-b-PDMA111)4在选择<span style=\"color:red\">性</span>溶剂中的自组装过程,通过DLS研究了嵌段<span style=\"color:red\">共聚物</span>组装成胶束的粒径及粒径分布,并采用TEM观察了胶束的形貌.研究了在不同的pH条件下,胶束粒径随温度的升高而变化的现象;以及胶束在去离子水及pH=10的缓冲溶液中对CLB的控制释放行为.结果发现:嵌段<span style=\"color:red\">共聚物</span>在选择<span style=\"color:red\">性</span>溶剂中可自组装成粒径均匀的球形聚集结构,粒径在406nm左右,粒径分布为0.113;在pH=10的缓冲溶液中,胶束浓度较小时,粒径随温度的升高而减小,而浓度较大时胶束粒径则会增加并发生胶束间的聚集直至沉淀析出;在去离子水中,胶束能够有效地加载药物并能延长药物的释放时间.","authors":[{"authorName":"陈卫星","id":"f8cab934-6bbd-4b8e-bf96-206e1c0aaf9b","originalAuthorName":"陈卫星"},{"authorName":"范晓东","id":"5362be1d-0f48-45e8-a958-8bf66381e169","originalAuthorName":"范晓东"},{"authorName":"刘郁杨","id":"c7843f76-75cc-492c-90a3-8a0fa4cf3adb","originalAuthorName":"刘郁杨"}],"doi":"","fpage":"663","id":"94fe56a8-5b78-4cb9-907c-7df17e7a7691","issue":"4","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"f7229fef-387d-49f9-acac-15c36c36c11e","keyword":"<span style=\"color:red\">两亲性</span>","originalKeyword":"两亲性"},{"id":"e8b20f2f-3d31-48de-8bb9-ba68b4132312","keyword":"嵌段<span style=\"color:red\">共聚物</span>","originalKeyword":"嵌段共聚物"},{"id":"84afe680-7625-4991-9ffc-c5ce83155117","keyword":"自组装","originalKeyword":"自组装"},{"id":"d9479f6c-c0da-4950-bd01-a18a9730a84a","keyword":"药物控释","originalKeyword":"药物控释"},{"id":"fc6ff681-f5fc-408c-bb2d-6c424170fb24","keyword":"苯丁酸氮芥","originalKeyword":"苯丁酸氮芥"}],"language":"zh","publisherId":"gncl200804039","title":"星形<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>的自组装及其药物控释行为研究","volume":"39","year":"2008"},{"abstractinfo":"合成了端环氧基硅油与聚醚胺（D-230）的嵌段<span style=\"color:red\">共聚物</span>。采用端环氧基硅油和嵌段<span style=\"color:red\">共聚物</span>对双酚A型环氧树脂（E-51）进行改性。结果表明,采用端环氧基硅油和D-230的嵌段<span style=\"color:red\">共聚物</span>改性环氧树脂（EP）,效果优于端环氧基硅油改性的方式。采用4份端环氧基硅油预反应改性EP后,Tg由未改性的163.23℃提高到164.81℃。除耐热性有所提高外,其拉伸强度也几乎能保持不变,断裂伸长率由38.62%降低到30.53%,冲击强度由20.23 kJ/m2提高到32.51 kJ/m2。","authors":[{"authorName":"李宏静","id":"59b2dbd4-e742-4518-9c70-41bb0c2b9662","originalAuthorName":"李宏静"},{"authorName":"刘伟区","id":"bdbad82b-9cd3-4617-a700-01f404f31d2d","originalAuthorName":"刘伟区"},{"authorName":"魏振杰","id":"390be6d3-f72b-4abb-a81e-cffb6951934b","originalAuthorName":"魏振杰"}],"doi":"","fpage":"61","id":"3d974abb-d265-47c4-a721-58854194271a","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"3e8dad8d-5acd-4173-874e-8403a292e228","keyword":"<span style=\"color:red\">两亲性</span>","originalKeyword":"两亲性"},{"id":"c404f903-099a-403e-95d4-5df80bfbccc3","keyword":"嵌段<span style=\"color:red\">共聚物</span>","originalKeyword":"嵌段共聚物"},{"id":"4b726720-9630-4a51-b62f-79ef8826b141","keyword":"增韧","originalKeyword":"增韧"},{"id":"c92c1041-6977-4928-8e89-c44e552524bf","keyword":"环氧树脂","originalKeyword":"环氧树脂"},{"id":"41e785b6-efdb-4648-9a75-73fda5faa76c","keyword":"聚醚胺","originalKeyword":"聚醚胺"}],"language":"zh","publisherId":"gfzclkxygc201111017","title":"<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>增韧环氧树脂","volume":"27","year":"2011"},{"abstractinfo":"采用可逆加成-断裂链转移(RAFT)自由基聚合及季铵化后处理方法制备出2种苯乙烯(St)和对氯甲基苯乙烯(VBC)的阳离子<span style=\"color:red\">两亲性</span>三嵌段<span style=\"color:red\">共聚物</span>PS-b-Q-PVBC-b-PS和Q-PVBC-b-PS-b-Q-PVBC.PS和PS-b-PVBC-b-PS的相对分子质量分别为8100和11700; PVBC和Q.PVBC-b-PS-b-Q-PVBC的相对分子质量分别为3600和12700,可以发现,二者的相对分子质量和嵌段比例均相近.以二甲基甲酰胺(DMF)为共溶剂,分别以去离子水和甲苯为选择<span style=\"color:red\">性</span>溶剂,对2种聚合<span style=\"color:red\">物</span>的自组装行为进行对比研究,探索了分子结构对聚合<span style=\"color:red\">物</span>自组装行为的影响.结果表明,当在相同的条件下进行自组装时,若成壳嵌段在大分子<span style=\"color:red\">两</span>端,聚合<span style=\"color:red\">物</span>自组装产生球形胶束聚集体;若成壳嵌段在大分子中间,聚合<span style=\"color:red\">物</span>自组装形态则是核壳胶束聚集体(选择<span style=\"color:red\">性</span>溶剂含量较低时)或棒<span style=\"color:red\">状</span>、球状胶束的聚集体(选择<span style=\"color:red\">性</span>溶剂含量较高时).","authors":[{"authorName":"杨兵兵","id":"04d4a9bd-ba38-44d3-b2f5-6042f44ef44e","originalAuthorName":"杨兵兵"},{"authorName":"石艳","id":"44e25b43-8ace-4195-a22b-cdab46045e4b","originalAuthorName":"石艳"}],"doi":"","fpage":"38","id":"df79fe83-ec62-4257-8cc1-105fd5d3ec48","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7f1670b4-f119-4b61-9014-b8a14eb0d5e1","keyword":"可逆加成-断裂链转移自由基聚合","originalKeyword":"可逆加成-断裂链转移自由基聚合"},{"id":"09a82841-20c1-44ac-a831-7d80156bd384","keyword":"阳离子<span style=\"color:red\">两亲性</span>三嵌段<span style=\"color:red\">共聚物</span>","originalKeyword":"阳离子两亲性三嵌段共聚物"},{"id":"d858ae11-af3c-45d0-8808-6ad1f57345dd","keyword":"自组装","originalKeyword":"自组装"},{"id":"011302f7-4f6a-4700-92f7-48abd25acbd2","keyword":"分子结构","originalKeyword":"分子结构"},{"id":"50d55e6d-fb6c-4535-b6b6-9fb8b5b18fbd","keyword":"核壳胶束","originalKeyword":"核壳胶束"}],"language":"zh","publisherId":"gfzclkxygc201410009","title":"阳离子<span style=\"color:red\">两亲性</span>三嵌段<span style=\"color:red\">共聚物</span>的合成及自组装","volume":"30","year":"2014"},{"abstractinfo":"合成了一种温敏<span style=\"color:red\">性</span>嵌段<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>P(NIPAAm-co-DMAAm)-b-PLA.通过自由基聚合的方法制备了一种含端羟基的N-异丙基丙烯酰胺(NIPAAm) 和二甲基丙烯酰胺(DMAAm)的温敏<span style=\"color:red\">性</span>无规<span style=\"color:red\">共聚物</span>,利用端羟基开环丙交酯得到<span style=\"color:red\">两亲性</span>嵌段<span style=\"color:red\">共聚物</span>P(NIPAAm-co-DMAAm)-b-PLA.核磁氢谱的结果验证了嵌段<span style=\"color:red\">共聚物</span>的成功合成,此<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>在水中可以自组装成胶束,采用可控温的紫外可见分光光度计表征了其温敏性能,测量结果表明,嵌段<span style=\"color:red\">共聚物</span>显示了较好的温度敏感特性,相转变温度LCST被成功地调节到40℃以上.此嵌段<span style=\"color:red\">共聚物</span>兼具良好的温度敏感特性,将在药物缓释方面具有良好的应用前景.","authors":[{"authorName":"曹阳","id":"427fa11d-e533-4b12-9917-dc3f82934dcf","originalAuthorName":"曹阳"},{"authorName":"任杰","id":"418aabe7-b730-4af9-bf1a-8a8e1c8eaa92","originalAuthorName":"任杰"},{"authorName":"徐敏明","id":"6d2b5cb8-4987-44c5-8c91-5e368f4f0b52","originalAuthorName":"徐敏明"}],"doi":"","fpage":"112","id":"e9e7a356-82ae-4a52-90d0-0f3de8d7015a","issue":"18","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"5371c24b-2a48-48cf-8a09-1cfcdcfa043e","keyword":"温敏<span style=\"color:red\">性</span>","originalKeyword":"温敏性"},{"id":"c8ebb232-1903-4b3e-a154-3745e17ad715","keyword":"<span style=\"color:red\">两亲性</span><span style=\"color:red\">共聚物</span>","originalKeyword":"两亲性共聚物"},{"id":"0620b771-6fa9-4131-8aca-05c4afbf715f","keyword":"药物载体","originalKeyword":"药物载体"}],"language":"zh","publisherId":"cldb201018032","title":"<span style=\"color:red\">两亲性</span>温敏嵌段<span style=\"color:red\">共聚物</span>P(NIPAAm-co-DMAAm)-b-PLA的合成与表征","volume":"24","year":"2010"}],"totalpage":9483,"totalrecord":94830}