{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在传统橡胶增韧塑料体系中,由于橡胶含量通常大于10%(质量分数,下同),不仅提高了材料的成本而且大幅降低了材料的强度和模量.文中报道了以马来酸酐化低分子量聚丁二烯(MLPB)接枝改性的线性低密度聚乙烯(LLDPEg)为增韧剂,通过反应挤出的方法制备了LLDPEg与尼龙6(PA6)的合金.利用在反应挤出过程中LLDPEg增韧剂中马来酸酐(MAH)与PA6中端胺基的反应,在合金体系中形成以LLDPE为核,MLPB为壳的核-壳结构.结果发现体系中MLPB净含量只有3%时,核壳增韧体系的缺口冲击强度最高可达到118kJ/m2.与POE-g-MAH增韧PA6的体系相比,在相同增韧剂含量的情况下,核壳增韧体系的冲击强度和拉伸强度都更高.","authors":[{"authorName":"陈利军","id":"e741aab1-bf49-48bb-b777-77fa4154d5f8","originalAuthorName":"陈利军"},{"authorName":"陈华兵","id":"2cc2ec9f-07b4-4b23-b93a-f4a125ac34d3","originalAuthorName":"陈华兵"},{"authorName":"柯卓","id":"8b3c771f-1466-4a15-8c46-e7a6ca3193c7","originalAuthorName":"柯卓"},{"authorName":"施德安","id":"65779dc8-8339-43c9-80f7-5b60a5e6a8e2","originalAuthorName":"施德安"},{"authorName":"殷敬华","id":"7d5bf87b-a650-48ec-add5-d95d55aa71c4","originalAuthorName":"殷敬华"},{"authorName":"吴京","id":"e380e16b-6824-4d0d-a4a0-838d367c0244","originalAuthorName":"吴京"}],"doi":"","fpage":"122","id":"d8774116-909a-478a-b9a1-0d4504bce8c5","issue":"7","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"39c5aee0-00a8-4817-bd9a-c565224c9c2b","keyword":"尼龙6","originalKeyword":"尼龙6"},{"id":"544d4397-1d98-41c0-bb0b-a4798eb2d588","keyword":"线性低密度聚乙烯","originalKeyword":"线性低密度聚乙烯"},{"id":"4cc0504c-7197-4c36-a5fb-00ae8fb7e8bd","keyword":"官能化低分子量聚丁二烯橡胶","originalKeyword":"官能化低分子量聚丁二烯橡胶"},{"id":"8495e082-79dc-4c97-ad03-b0ca77b6e62a","keyword":"增韧","originalKeyword":"增韧"}],"language":"zh","publisherId":"gfzclkxygc201007032","title":"马来酸酐化低分子量聚丁二烯接枝改性LLDPE的制备及增韧尼龙6的性能","volume":"26","year":"2010"},{"abstractinfo":"制备了不同碳链长度的二元环氧化合物,并使其与聚合度为8~9的聚氧乙烯(PEO)或SPAN80反应,合成了含有不同长度间隔链的双亲水基表面活性剂. 用傅立叶红外光谱仪和核磁共振仪对其结构进行了表征. 实验结果表明,具有疏水性间隔链的双亲水基表面活性剂具有良好的表面活性,其表面活性不仅比单亲水基表面活性剂的大,且可随着疏水间隔链长度的增加而增大. ","authors":[{"authorName":"辛志荣","id":"e698f02f-83af-4a47-bc22-7378eb496b97","originalAuthorName":"辛志荣"},{"authorName":"丁永涛","id":"af99f9a9-f182-411b-8c74-ef132f5ac65e","originalAuthorName":"丁永涛"},{"authorName":"柯卓","id":"156e4639-7865-4d90-b48f-e38974482092","originalAuthorName":"柯卓"},{"authorName":"蔡传伦","id":"5466960a-10b8-4684-b546-7eddf4e28f7d","originalAuthorName":"蔡传伦"},{"authorName":"高瑛","id":"04793d17-aa7d-478f-8c5a-50a037d007e8","originalAuthorName":"高瑛"},{"authorName":"殷敬华","id":"dab1598c-827c-495e-9966-b7f7e05b90ae","originalAuthorName":"殷敬华"}],"doi":"10.3969/j.issn.1000-0518.2002.08.003","fpage":"723","id":"1a762d30-a0d8-47b8-8f2c-e9a4d07aaeed","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"9f13ce89-e716-4c9c-9fee-e7cd3be3c62c","keyword":"非离子表面活性剂","originalKeyword":"非离子表面活性剂"},{"id":"1ffc5c0b-bff6-4fd8-9b70-01fe6d6744ad","keyword":"环氧化合物","originalKeyword":"环氧化合物"},{"id":"c2fe652c-5aee-49a9-ae94-1bbed48343ab","keyword":"疏水间隔链","originalKeyword":"疏水间隔链"},{"id":"e911fd4f-9568-40c8-ab7d-b536d222a1ec","keyword":"聚氧乙烯","originalKeyword":"聚氧乙烯"},{"id":"b31012ae-b4fd-4f68-adb1-55165f86b3df","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200208003","title":"新型非离子表面活性剂的合成与表征","volume":"19","year":"2002"},{"abstractinfo":"采用新型双路易斯酸,三甲基氯硅烷和三氯化铟为催化剂引发傅氏烷基化反应,实现了乙烯辛烯共聚物(POE)和聚苯乙烯(PS)共混物的原位增容. 红外光谱的结果验证了接枝物的存在. 用扫描电子显微镜观察了反应共混物和简单物理共混物的形态, 前者分散相的尺寸小于1 μm,后者分散相的尺寸一般为3~4 μm. 原位生成的接枝物(PS-g-POE)起到相容剂的作用,增容后材料的力学性能得到较明显的提升. 如:当m(POE):m(PS)=40:60 时,与相同组成的物理共混物POE/PS相比,其悬臂梁冲击强度由1.9 kJ/m~2增加至9.7 kJ/m~2,断裂伸长率由3.4%提高至46.3%. 增容后的共混物低频区的复数粘度升高,表明POE、PS间相互作用增加.","authors":[{"authorName":"刘焱龙","id":"6c3821b3-bf0c-4bbd-b48d-95b811218970","originalAuthorName":"刘焱龙"},{"authorName":"柯卓","id":"f40b9a78-85aa-424b-8e2e-a95f59b51df9","originalAuthorName":"柯卓"},{"authorName":"尹立刚","id":"1f14b290-7f06-4904-b4b8-216c9bdabec9","originalAuthorName":"尹立刚"},{"authorName":"石强","id":"ca72f4e7-8494-44e8-b0a6-adecefa54691","originalAuthorName":"石强"},{"authorName":"殷敬华","id":"f9ec2f08-028c-4a91-b9f2-bf0eda498bc5","originalAuthorName":"殷敬华"}],"doi":"10.3969/j.issn.1000-0518.2009.10.001","fpage":"1129","id":"3bf08b9b-3ff7-42ee-8a5e-5cc9894a8718","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"d7e70277-80e5-4afa-b1ac-aa11dd0c58a1","keyword":"反应共混","originalKeyword":"反应共混"},{"id":"11cb49bd-c835-4fe2-a3bf-da3d9e6fd7b7","keyword":"增容","originalKeyword":"增容"},{"id":"ecab5bc6-bdca-418f-b097-d1374a218e07","keyword":"接枝物","originalKeyword":"接枝物"},{"id":"a96db051-509b-479f-9bd5-67b51e79dc81","keyword":"乙烯辛烯共聚物","originalKeyword":"乙烯辛烯共聚物"},{"id":"c0aede45-cd8d-4a6d-9b87-8e2a18d4bd5b","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"}],"language":"zh","publisherId":"yyhx200910001","title":"双路易斯酸催化原位增容乙烯辛烯共聚物/聚苯乙烯的共混物","volume":"26","year":"2009"},{"abstractinfo":"改变聚丙烯(PP)熔融接枝马来酸酐(MAH)反应中的单体和引发剂的浓度以及添加适当助剂,考察了接枝产物的接枝率和在恒定剪切应力(600kPa)及温度(210℃)下的剪切粘度,验证了作者先前所提出的PP熔融接枝MAH的反应机理.即:在PP熔融接枝MAH的过程中,过氧化物自由基在熔融接枝过程中直接引发MAH单体及MAH单体在聚丙烯的大分子链段发生β断裂前直接被其引发而产生的接枝反应是影响产物的接枝率和分子量的关键.在不改变单体和引发剂浓度的情况下,降低过氧化物自由基在熔融接枝过程中直接引发MAH单体反应的程度而提高聚丙烯的大分子自由基直接引发MAH单体的反应趋势,是提高接枝产物接枝率和分子量的有效途径.","authors":[{"authorName":"施德安","id":"3b49bf5a-3dac-4982-8823-f7e94e372ddc","originalAuthorName":"施德安"},{"authorName":"殷敬华","id":"24e4b83f-377f-49ea-bce5-773653b5ae7a","originalAuthorName":"殷敬华"},{"authorName":"柯卓","id":"14e2afa2-049b-4c1b-8825-9b11aca23c51","originalAuthorName":"柯卓"}],"doi":"10.3969/j.issn.1000-0518.2001.11.004","fpage":"865","id":"89a4bcc5-033d-4937-a5ce-fff84d3e27af","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"5cf21de4-8d92-4eab-a4e6-56c59bde3e6a","keyword":"聚丙烯","originalKeyword":"聚丙烯"},{"id":"fb7f42a6-6665-4406-be67-1a84a396c4ad","keyword":"马来酸酐","originalKeyword":"马来酸酐"},{"id":"3de3cd8a-c685-4107-bf62-ba9afdd18f4c","keyword":"熔融接枝","originalKeyword":"熔融接枝"},{"id":"f9be4269-022b-43e4-8408-fab1e2142ff9","keyword":"机理","originalKeyword":"机理"}],"language":"zh","publisherId":"yyhx200111004","title":"聚丙烯熔融接枝马来酸酐反应机理的研究","volume":"18","year":"2001"},{"abstractinfo":"卓家庄金矿床是一个与中生代次火山杂岩体(二长闪长玢岩、二长斑岩)有关的小型金矿床,柱状矿体严格地受隐爆角砾岩筒的控制.从角砾岩筒中心向外,角砾粒度、成分、胶结物成分及蚀变均存在分带现象.全文着重阐述了金矿床地质特征,总结出矿床成矿规律,并对矿区成矿远景作了预测.","authors":[{"authorName":"祝德平","id":"b64c2825-d8a8-4a16-bfca-1523ba46f91b","originalAuthorName":"祝德平"},{"authorName":"于超","id":"efdb554f-3afa-445b-a7cd-d2dfaf10e18f","originalAuthorName":"于超"},{"authorName":"廉永","id":"0da023aa-5664-4296-b261-9119c90abb01","originalAuthorName":"廉永"},{"authorName":"杨忠臣","id":"e60999c8-666f-4d0d-98c4-e37f37dc2434","originalAuthorName":"杨忠臣"},{"authorName":"齐可昆","id":"f2d84302-f718-47b9-9f01-a71c519c2e97","originalAuthorName":"齐可昆"}],"doi":"10.3969/j.issn.1001-1277.2001.08.003","fpage":"11","id":"cbd7cad8-5e0a-46fc-acf8-3878f17bd5b5","issue":"8","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"851dbe8d-889e-41e9-8802-2225d6c86a5b","keyword":"次火山杂岩体","originalKeyword":"次火山杂岩体"},{"id":"37060356-312b-4ecd-96eb-216032b31ecc","keyword":"角砾岩筒型金矿床","originalKeyword":"角砾岩筒型金矿床"},{"id":"c7d6e2a9-6cbe-4a48-b458-c595a122c4a2","keyword":"地质特征","originalKeyword":"地质特征"},{"id":"58249dda-b9dc-4a14-8037-fce33acb21b0","keyword":"成矿规律","originalKeyword":"成矿规律"},{"id":"8ae8b516-06c4-4a87-8083-fdd24e15866e","keyword":"卓家庄","originalKeyword":"卓家庄"}],"language":"zh","publisherId":"huangj200108003","title":"平邑卓家庄金矿床成矿地质特征","volume":"22","year":"2001"},{"abstractinfo":"按Koenigs-Knorr 方法将四乙酰溴代半乳糖分别与3-乙酰基卓酚酮和3-乙酰胺基卓酚酮以Ag2CO3为催化剂反应合成了β-构型糖苷. 由于卓酚酮存在互变异构,糖基化物亦为2种异构产物. 应用元素分析、核磁共振、红外光谱表征了它们的结构. 分析结果表明,所得到的化合物是含有卓酚酮基团的四乙酰基β-构型半乳糖苷.","authors":[{"authorName":"钟方丽","id":"5bcf4273-a895-4e07-a8de-1da49efa90c5","originalAuthorName":"钟方丽"},{"authorName":"王晓林","id":"427d3a85-6d9c-432d-ab58-3b47fd8b1130","originalAuthorName":"王晓林"},{"authorName":"尹丙柱","id":"71e6bcda-a262-4726-8dfa-1968f8a88d7d","originalAuthorName":"尹丙柱"},{"authorName":"金钟天","id":"9fd0dacc-c138-45a9-b7c4-06063ecd1f3e","originalAuthorName":"金钟天"}],"doi":"10.3969/j.issn.1000-0518.2004.05.016","fpage":"502","id":"59317e1b-b244-4733-8df4-413a60833734","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"fc2d1bb3-7de4-4c97-b819-0d43a58278e3","keyword":"环庚三烯酚酮","originalKeyword":"环庚三烯酚酮"},{"id":"66daf074-3e44-4c48-b0e8-7f0252d50ef7","keyword":"半乳糖苷","originalKeyword":"半乳糖苷"},{"id":"67587e24-3aec-4a3e-af0f-675cd8894c78","keyword":"Koenigs-Knorr糖基化反应","originalKeyword":"Koenigs-Knorr糖基化反应"}],"language":"zh","publisherId":"yyhx200405016","title":"含卓酚酮基团的四乙酰基半乳糖苷的合成","volume":"21","year":"2004"},{"abstractinfo":"达涅利摩根沙玛将为美国纽柯钢公司位于达林顿的钢厂新建一条线材轧制生产线和一条热处理作业线,用于生产和加工特殊工程用钢。这是美国第一次采用先进的TMB双模块轧制机组/WRS线材定径轧制技术。","authors":[],"doi":"","fpage":"21","id":"84f01335-05df-4cc9-958b-0a8439da9565","issue":"6","journal":{"abbrevTitle":"GTYJ","coverImgSrc":"journal/img/cover/GTYJ.jpg","id":"29","issnPpub":"1001-1447","publisherId":"GTYJ","title":"钢铁研究"},"keywords":[{"id":"e8e2cc49-0a64-4473-91dc-3cf39de6658b","keyword":"线材生产线","originalKeyword":"线材生产线"},{"id":"186c428f-7c15-4f97-b9d8-bf6d68770969","keyword":"钢厂","originalKeyword":"钢厂"},{"id":"2f1ce2b6-8e75-4fd4-a1e7-b024ee00ec57","keyword":"轧制生产线","originalKeyword":"轧制生产线"},{"id":"48da2611-552d-4827-b2ab-dfdaad3566a7","keyword":"轧制技术","originalKeyword":"轧制技术"},{"id":"f3bee5da-03ae-4f77-9708-11c108375878","keyword":"作业线","originalKeyword":"作业线"},{"id":"d466823d-725f-460d-99fc-af7369cc27a8","keyword":"热处理","originalKeyword":"热处理"},{"id":"75d6229d-b740-494d-a140-205513f42f26","keyword":"达林顿","originalKeyword":"达林顿"},{"id":"0cb71188-8ff4-4876-bd09-4a2ac53b08cb","keyword":"达涅利","originalKeyword":"达涅利"}],"language":"zh","publisherId":"gtyj201206008","title":"纽柯钢公司新建线材生产线","volume":"40","year":"2012"},{"abstractinfo":"本文主要介绍了EAST实验中罗柯受电磁干扰的影响,由实验现象推测产生噪声的原因,通过大量的探索过程和模拟测试方法最终将这些干扰有效的抑制和去除,得到最佳解决方案.","authors":[{"authorName":"郑龙贵","id":"54ea57cc-bdd0-4b3e-9592-46209d61a32b","originalAuthorName":"郑龙贵"},{"authorName":"陆建华","id":"3911f055-295b-48a4-8674-4ceb711f996d","originalAuthorName":"陆建华"},{"authorName":"吕环宇","id":"5a58d35b-7ac4-4b76-b40f-8849d6283ed6","originalAuthorName":"吕环宇"},{"authorName":"潘超","id":"7acf4bb9-b8fc-47f4-849b-b57d971eab2b","originalAuthorName":"潘超"},{"authorName":"肖业政","id":"64f6f752-0570-4718-ac6a-29e6e81cd6e6","originalAuthorName":"肖业政"},{"authorName":"倪其才","id":"4c5b0e1f-fadf-4a2f-a749-342103503c10","originalAuthorName":"倪其才"},{"authorName":"朱崇铭","id":"a9ff8d6d-8562-47a3-88df-1158074c7f15","originalAuthorName":"朱崇铭"}],"doi":"","fpage":"238","id":"f677d040-1f37-49ba-8ff3-25fa084ad183","issue":"3","journal":{"abbrevTitle":"DWWLXB","coverImgSrc":"journal/img/cover/DWWLXB.jpg","id":"19","issnPpub":"1000-3258","publisherId":"DWWLXB","title":"低温物理学报 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