{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"用Al(NO3)3·9H2O 作为Al2O3 源,间苯二酚-糠醛为碳源,环氧丙烷为<span style=\"color:red\">凝胶</span>促进剂,通过溶胶-<span style=\"color:red\">凝胶</span>方法一釜合成了湿<span style=\"color:red\">凝胶</span>,并经超临界正己烷干燥和碳化制备了Al2O3-C <span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>. 研究了Al2O3含量、间苯二酚-糠醛浓度和环氧丙烷/铝摩尔比对所合成的<span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>孔隙性质的影响.结果表明,此<span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>均为中孔结构,其平均孔径小于20 nm,Al2O3属于γ-型结构但X射线衍射峰很宽.<span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>在Al2O3含量小于5.31 wt%和间苯二酚-糠醛浓度为10 g/mL时可形成整体块状.在其他条件相同的情况下,中孔孔容、BET比表面、外表面积和中孔孔径随环氧丙烷/铝摩尔比增加而增大.制备过程中<span style=\"color:red\">凝胶</span>的体积收缩率和炭化收率随Al2O3含量增加而增大,但密度随Al2O3含量增加在4.93 wt%处达到最大.中孔孔容和孔径以及外表面积在环氧丙烷/铝摩尔比为5和6时随间苯二酚-糠醛浓度增加而减小,而在环氧丙烷/铝摩尔比为4时随间苯二酚-糠醛浓度增加而增大.","authors":[{"authorName":"张睿","id":"56745765-1279-4d39-b8c3-973fd0e3a84f","originalAuthorName":"张睿"},{"authorName":"蒋宁","id":"7a474e8a-d716-4437-9887-9f5387e796f8","originalAuthorName":"蒋宁"},{"authorName":"段晓佳","id":"f232388b-07d1-4978-a7a5-232cf7d5f347","originalAuthorName":"段晓佳"},{"authorName":"金双玲","id":"c4d24843-e0bc-4be8-968e-51bc79025e59","originalAuthorName":"金双玲"},{"authorName":"金鸣林","id":"02712847-8680-4a1a-b952-b10365d2ce53","originalAuthorName":"金鸣林"}],"doi":"10.1016/S1872-5805(17)60122-7","fpage":"258","id":"b76ac970-7250-445e-a7ac-448ba64ac08a","issue":"3","journal":{"abbrevTitle":"XXTCL","coverImgSrc":"journal/img/cover/XXTCL.jpg","id":"70","issnPpub":"1007-8827","publisherId":"XXTCL","title":"新型炭材料"},"keywords":[{"id":"048a4d3f-233f-4cc7-ab8b-c658916fb666","keyword":"<span style=\"color:red\">氧化铝</span>-<span style=\"color:red\">碳</span><span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>","originalKeyword":"氧化铝-碳杂化气凝胶"},{"id":"a251c333-f7a2-45ff-b397-d9a6b05e6a36","keyword":"溶胶-<span style=\"color:red\">凝胶</span>","originalKeyword":"溶胶-凝胶"},{"id":"97d8b261-135e-4033-98e0-bc52523f9b2b","keyword":"超临界干燥","originalKeyword":"超临界干燥"}],"language":"zh","publisherId":"xxtcl201703010","title":"溶胶-<span style=\"color:red\">凝胶</span>一釜法Al2O3-C<span style=\"color:red\">杂</span><span style=\"color:red\">化</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的合成和表征","volume":"32","year":"2017"},{"abstractinfo":"在众多<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>中，<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>不仅热导率低，而且高温稳定性好（长期使用温度高达950℃），在高温催化、高温隔热等领域是一种理想的材料。但在工作温度超过1000℃时，<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的使用受到限制。简要介绍了<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的制备工艺，分析了<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的失效理论，并对其耐高温性能的改善进行了探讨。","authors":[{"authorName":"温培刚","id":"69d36daf-1c4f-4e5a-b30b-d569cb50c3fd","originalAuthorName":"温培刚"},{"authorName":"巢雄宇","id":"e2aa3ed3-fcca-4e7e-8059-5666d8dbfee2","originalAuthorName":"巢雄宇"},{"authorName":"袁武华","id":"d5cf1b4b-d421-4775-88f2-3f2716a2a838","originalAuthorName":"袁武华"},{"authorName":"顾立","id":"1d921bd2-9039-4263-a509-65947a918213","originalAuthorName":"顾立"}],"doi":"10.11896/j.issn.1005-023X.2016.015.008","fpage":"51","id":"729758f5-1076-48cb-a68a-39315e768577","issue":"15","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"41723885-64e2-47bc-823e-d4ebe298cf7d","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"},{"id":"1ea8857e-ab6b-431d-b4c8-6436e405853a","keyword":"<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>","originalKeyword":"气凝胶"},{"id":"22217294-c802-44b9-8f33-c12c87a1abe0","keyword":"烧结","originalKeyword":"烧结"},{"id":"3bc364ad-bd20-41cc-a0cb-b7fc4cd00d61","keyword":"耐高温","originalKeyword":"耐高温"}],"language":"zh","publisherId":"cldb201615009","title":"耐高温<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>研究进展","volume":"30","year":"2016"},{"abstractinfo":"由铝的纳米<span style=\"color:red\">氧化</span>物溶胶制得纳米<span style=\"color:red\">氧化铝</span><span style=\"color:red\">杂</span><span style=\"color:red\">化</span>的聚酰亚胺(PI)薄膜.对PI薄膜的耐电晕性进行了测试,结果表明<span style=\"color:red\">氧化铝</span>质量百分数为23%的PI薄膜在棒板电极系统、<span style=\"color:red\">气</span>隙间距0.1 mm、50 Hz、90 MV/m条件下耐电晕时间达120h以上.比纯PI薄膜提高30倍以上;使用介电谱仪测试其介电常数和介质损耗;采用FTIR、SEM分别表征了<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>PI薄膜与纯PI薄膜的化学结构和表面形貌.","authors":[{"authorName":"范勇","id":"3c333ed4-bca0-4139-96f5-493298314d5c","originalAuthorName":"范勇"},{"authorName":"安军伟","id":"f0c22418-206d-4c64-b0a0-eab0070ba7dc","originalAuthorName":"安军伟"},{"authorName":"周宏","id":"49150109-5aaa-448c-b914-94188a870256","originalAuthorName":"周宏"},{"authorName":"刘伟","id":"300b04a6-3375-49c0-b001-7898e86e560f","originalAuthorName":"刘伟"}],"doi":"10.3969/j.issn.1009-9239.2007.02.001","fpage":"1","id":"d1b9a5fd-0fe0-4c2a-a809-fdcedcdcc952","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"bd0869fa-784f-4362-9241-6997399dac47","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"28116b30-7500-4638-abe3-8e537bd2288d","keyword":"介电性能","originalKeyword":"介电性能"},{"id":"6f1a0ecb-894b-4904-971e-52f8e242420d","keyword":"耐电晕","originalKeyword":"耐电晕"},{"id":"53081425-e9f6-46ea-aea6-fb4809728b2a","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"}],"language":"zh","publisherId":"jycltx200702001","title":"纳米<span style=\"color:red\">氧化铝</span><span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚酰亚胺薄膜的制备与性能研究","volume":"40","year":"2007"},{"abstractinfo":"以AlCl_3·6H_2O为前驱体,无水乙醇和去离子水的混合溶液为溶剂,环氧丙烷为<span style=\"color:red\">凝胶</span>网络诱导荆,通过溶胶-<span style=\"color:red\">凝胶</span>技术制备得到溶胶,再经超临界干燥制备出块状<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>.采用SEM、TEM、XRD、BET等手段,对<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>在不同热处理温度下的微观结构进行了对比和分析.结果表明,<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的主要成分为多晶勃姆石相,微观结构由许多叶片状纤维堆积形成,经500和1 000℃热处理后成块性未受到明显的影响,比表面积各为429和174 m~2/g.在20～1000℃内,<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>发生了由多晶态勃姆石相→γ-Al_2O_3→δ-Al_2O_3的相转变.","authors":[{"authorName":"周洁洁","id":"04973b8b-587e-43f2-83e3-496494aff170","originalAuthorName":"周洁洁"},{"authorName":"陈晓红","id":"0368d8dc-31ef-41aa-bce6-dbfbc82ec7be","originalAuthorName":"陈晓红"},{"authorName":"胡子君","id":"337d21ed-1f23-42c0-b49b-826c1b77d273","originalAuthorName":"胡子君"},{"authorName":"孙陈诚","id":"0172780a-d8bd-4340-8d92-a213ef501275","originalAuthorName":"孙陈诚"},{"authorName":"陈海坤","id":"85dab661-cde7-4741-8915-3c692cf8d80c","originalAuthorName":"陈海坤"},{"authorName":"宋怀河","id":"70227b4e-abdb-4a6c-ace0-1e02fc2fe3b6","originalAuthorName":"宋怀河"}],"doi":"10.3969/j.issn.1007-2330.2010.02.014","fpage":"51","id":"2b603b41-f819-493f-a540-dfefde10cee3","issue":"2","journal":{"abbrevTitle":"YHCLGY","coverImgSrc":"journal/img/cover/YHCLGY.jpg","id":"77","issnPpub":"1007-2330","publisherId":"YHCLGY","title":"宇航材料工艺   "},"keywords":[{"id":"f8d37c41-0a02-4b5b-b14d-801cf385fd4e","keyword":"块状","originalKeyword":"块状"},{"id":"7f4d1a0c-5ccd-4524-a767-b999fe22886b","keyword":"<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>","originalKeyword":"氧化铝气凝胶"},{"id":"d3325bc6-0ab1-4b67-9082-076552f6d54c","keyword":"比表面积","originalKeyword":"比表面积"},{"id":"04b0c7c2-ea8e-4e50-8d6b-c40b31fd599e","keyword":"热处理","originalKeyword":"热处理"}],"language":"zh","publisherId":"yhclgy201002014","title":"热处理对块状<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>微观结构的影响","volume":"40","year":"2010"},{"abstractinfo":"Al_2O_3<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>以其独特性质受到人们的广泛关注.本文就Al_2O_3<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的结构、性质和制备方法进行了综述,制备方法包括铝醇盐的一步法、两步法和无机铝盐的滴加环氧丙烷法,其中滴加环氧丙烷法是制备高性能Al_2O_3<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>非常有发展潜力的方法之一.同时还介绍了纤维增强<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>、多组分及掺杂改性气<span style=\"color:red\">凝胶</span>.","authors":[{"authorName":"胡子君","id":"a1554964-3e43-4aa8-adaa-f51f081cb2a5","originalAuthorName":"胡子君"},{"authorName":"周洁洁","id":"e91c726e-80ed-4b63-b7cf-11d4aa6db69b","originalAuthorName":"周洁洁"},{"authorName":"陈晓红","id":"13a29dea-e19a-4a1c-98d9-52c260b6154e","originalAuthorName":"陈晓红"},{"authorName":"孙陈诚","id":"d2969b25-3cc3-4ab3-9122-6cef9714140e","originalAuthorName":"孙陈诚"}],"doi":"","fpage":"1002","id":"0e4ca05b-479d-4878-8249-995beec3ae5b","issue":"5","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"e6d2ffb1-78d3-4202-82f7-2f4095a9d4b2","keyword":"<span style=\"color:red\">氧化铝</span>","originalKeyword":"氧化铝"},{"id":"cc3368b1-4121-4d4b-ba71-64cba61cc922","keyword":"<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>","originalKeyword":"气凝胶"},{"id":"c9096bda-8959-4c43-8f9a-39953a3b4770","keyword":"制备方法","originalKeyword":"制备方法"},{"id":"a87ef70b-c80d-40d5-835c-8449ac1c6d2b","keyword":"复合","originalKeyword":"复合"},{"id":"60c5cd4e-f354-456d-8bef-dcf86a163135","keyword":"掺杂","originalKeyword":"掺杂"}],"language":"zh","publisherId":"gsytb200905026","title":"<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>的研究进展","volume":"28","year":"2009"},{"abstractinfo":"通过相转化法制备了纳米氢<span style=\"color:red\">氧化铝</span>镁/PVDF<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜,考察了铸膜液组成中的复配添加剂、AMH含量和分散剂对<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜结构和性能的影响.结果表明,通过复配添加剂可明显改变<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜的断面结构,再结合AMH含量以及通过分散剂的调节来辅助改变<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜的性能可得到不同结构和性能的<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜","authors":[{"authorName":"魏汉辉","id":"1f1d9ac7-8591-429c-b258-67e5e40fc077","originalAuthorName":"魏汉辉"},{"authorName":"刘红斌","id":"5a0c5950-2bac-47fb-bddf-f142cf303b7b","originalAuthorName":"刘红斌"},{"authorName":"吕晓龙","id":"2a9d76e6-8ce0-4122-8e08-6907f969cf6d","originalAuthorName":"吕晓龙"},{"authorName":"马军","id":"c9a6f3ed-327d-44f1-918e-d48285760a3e","originalAuthorName":"马军"}],"doi":"","fpage":"981","id":"3a61eedf-fadc-4a34-8490-c529899cecc5","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"968ebe61-10e3-4d12-a6ef-9abc9ca07091","keyword":"聚偏氟乙烯","originalKeyword":"聚偏氟乙烯"},{"id":"f216c480-aaf0-4f56-aeb0-8ab15453bed0","keyword":"纳米氢<span style=\"color:red\">氧化铝</span>镁","originalKeyword":"纳米氢氧化铝镁"},{"id":"310b27c8-2717-41a2-93de-da97473e3c84","keyword":"<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜","originalKeyword":"杂化膜"},{"id":"bad2d563-d44d-4330-886b-381017d2470b","keyword":"结构和性能","originalKeyword":"结构和性能"}],"language":"zh","publisherId":"gncl200906031","title":"纳米氢<span style=\"color:red\">氧化铝</span>镁/PVDF<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>膜的制备研究","volume":"40","year":"2009"},{"abstractinfo":"以陶瓷纤维制成的高温隔热瓦为骨架,真空浸渍<span style=\"color:red\">氧化铝</span>溶胶,再经过<span style=\"color:red\">凝胶</span>、老化和超临界干燥制备出<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>复合高温隔热瓦,研究了其在不同温度处理后(最高温度1 400℃)的微观结构、隔热和力学性能.结果表明:<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>复合高温隔热瓦在1 400℃保温30 min后线收缩率仅为2％;随着热处理温度升高,<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>颗粒发生熔并、长大,<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>从填充纤维空隙到不断收缩,但对纤维骨架没有明显影响;隔热瓦的室温、高温热导率均显著降低;在热面1 400的背温测试中,复合后材料的背温从945℃降到870℃;复合后隔热瓦的力学性能略有增加;但是1 200～1 400℃的压缩强度下降较大.可见,<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>复合高温隔热瓦可改善其隔热性能,但在高温下力学性能下降.","authors":[{"authorName":"孙晶晶","id":"3487cbeb-8a48-45b0-9b75-86bda823345a","originalAuthorName":"孙晶晶"},{"authorName":"胡子君","id":"793c2269-12d9-4ad9-8d7b-178d38bfaec1","originalAuthorName":"胡子君"},{"authorName":"吴文军","id":"5b6c39b8-b64d-423b-944b-3cfa9068bc37","originalAuthorName":"吴文军"},{"authorName":"周洁洁","id":"ce26e11e-b0c2-4d74-87c1-d44544a88788","originalAuthorName":"周洁洁"},{"authorName":"李俊宁","id":"55c5839e-d2f5-48fb-8b51-1a1137e5be0d","originalAuthorName":"李俊宁"}],"doi":"10.12044/j.issn.1007-2330.2017.03.008","fpage":"33","id":"52160d95-27de-481a-a304-8833b4717330","issue":"3","journal":{"abbrevTitle":"YHCLGY","coverImgSrc":"journal/img/cover/YHCLGY.jpg","id":"77","issnPpub":"1007-2330","publisherId":"YHCLGY","title":"宇航材料工艺   "},"keywords":[{"id":"798fb5db-cadb-4dcd-96fe-92f2ec6a47dd","keyword":"<span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>","originalKeyword":"气凝胶"},{"id":"cab737c3-416a-4682-9012-13daaaf7fdab","keyword":"隔热瓦","originalKeyword":"隔热瓦"},{"id":"1096de02-d64b-4fcb-846e-e945c6eff16b","keyword":"隔热性能","originalKeyword":"隔热性能"},{"id":"4012ceed-8094-4837-9117-d390480ef698","keyword":"力学性能","originalKeyword":"力学性能"}],"language":"zh","publisherId":"yhclgy201703008","title":"<span style=\"color:red\">氧化铝</span><span style=\"color:red\">气</span><span style=\"color:red\">凝胶</span>复合高温隔热瓦的制备及性能","volume":"47","year":"2017"},{"abstractinfo":"　　采用微乳化-热液法制备了一系列<span style=\"color:red\">氧化</span>锆（ZrO2）改性的纳米<span style=\"color:red\">氧化铝</span>分散液，然后用原位聚合法制备了相应的<span style=\"color:red\">氧化</span>锆复配纳米<span style=\"color:red\">氧化铝</span><span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚酰亚胺复合薄膜，并对其进行了TEM表征、电气强度和电导电流测试以及电老化阈值分析。结果表明：掺杂<span style=\"color:red\">氧化</span>锆复配纳米<span style=\"color:red\">氧化铝</span>的<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚酰亚胺复合薄膜的电气强度大幅提高，当ZrO2的掺杂量为7%时，电气强度达到最高为396.8 MV/m；其电导电流密度、电老化阈值均高于只掺杂纳米<span style=\"color:red\">氧化铝</span>的聚酰亚胺薄膜，且随ZrO2含量增加均出现先增大后减小的趋势。","authors":[{"authorName":"范勇","id":"e7a79f84-8b01-484f-b50b-7d4d9eac3d2b","originalAuthorName":"范勇"},{"authorName":"韩笑笑","id":"ac1e545c-a8b1-4f2a-812b-7176009f0e3c","originalAuthorName":"韩笑笑"},{"authorName":"陈昊","id":"b2b329b8-5612-4c16-9385-439f86b7974f","originalAuthorName":"陈昊"},{"authorName":"杨瑞宵","id":"f57e7cbf-71e8-4550-8d7a-c6aaf5acd14e","originalAuthorName":"杨瑞宵"}],"doi":"","fpage":"63","id":"16d5fa13-9d12-4242-9180-e02c738e66d0","issue":"4","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"1d24677d-6414-42fe-9235-f7adf0e1eb42","keyword":"聚酰亚胺薄膜","originalKeyword":"聚酰亚胺薄膜"},{"id":"c738b2f8-9aa5-4baa-9a1d-76be2ca5386c","keyword":"电气强度","originalKeyword":"电气强度"},{"id":"6585f39b-9b85-4390-ba07-c804d2566c27","keyword":"电导电流","originalKeyword":"电导电流"},{"id":"a5f899b9-e37b-4369-96ee-f288b29cdb26","keyword":"电老化阈值","originalKeyword":"电老化阈值"}],"language":"zh","publisherId":"jycltx201304017","title":"<span style=\"color:red\">氧化</span>锆复配纳米<span style=\"color:red\">氧化铝</span><span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚酰亚胺薄膜的介电性能研究","volume":"","year":"2013"},{"abstractinfo":"用溶胶-<span style=\"color:red\">凝胶</span>法制备了纳米<span style=\"color:red\">氧化</span>硅( SiO2)及纳米<span style=\"color:red\">氧化铝</span>( Al2O3)溶胶,并将二者掺入到聚酰胺酸基体中,亚胺<span style=\"color:red\">化</span>得到聚酰亚胺 (PI)/SiO2/Al2O3<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>薄膜 ,采用红外光谱、原子力显微镜、热失重及阻抗分析仪对薄膜的结构及热性能、介电性能进行表征.结果表明, SiO2和 Al2O3粒子呈纳米级均匀分散在薄膜基体中,并且与有机相存在键合;材料的热分解温度有所提高 ;介电常数随无机含量的增加而增加.","authors":[{"authorName":"王伟","id":"e5904b53-7ab1-4526-9c32-cf362f7bc414","originalAuthorName":"王伟"},{"authorName":"刘立柱","id":"91e9a907-dd72-4971-af84-1b80b954a534","originalAuthorName":"刘立柱"},{"authorName":"杨阳","id":"60ab89ce-ae96-4c5b-b565-94b7fba232a8","originalAuthorName":"杨阳"},{"authorName":"雷清泉","id":"07bd5508-bdf2-48c2-9d76-0fe36ec340d3","originalAuthorName":"雷清泉"}],"doi":"10.3969/j.issn.1009-9239.2005.05.004","fpage":"11","id":"15a17407-3925-4293-b13c-5ee9768de69d","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"115d55dc-5b95-422e-94d6-309ebdd8488f","keyword":"聚酰亚胺薄膜","originalKeyword":"聚酰亚胺薄膜"},{"id":"5df5dd9d-640e-45cb-abc0-c71431130cea","keyword":"二<span style=\"color:red\">氧化</span>硅","originalKeyword":"二氧化硅"},{"id":"b1d669be-7215-473d-9d02-245c9f2c2eea","keyword":"三<span style=\"color:red\">氧化</span>二铝","originalKeyword":"三氧化二铝"},{"id":"d51c267a-e4c5-4f4b-a8d6-ef02b6b0f584","keyword":"溶胶-<span style=\"color:red\">凝胶</span>法","originalKeyword":"溶胶-凝胶法"},{"id":"6f049a7c-4a57-4603-8c72-c049bca0ba00","keyword":"<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>薄膜","originalKeyword":"杂化薄膜"}],"language":"zh","publisherId":"jycltx200505004","title":"聚酰亚胺/<span style=\"color:red\">氧化</span>硅/<span style=\"color:red\">氧化铝</span>纳米<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>薄膜的制备及结构与性能研究","volume":"38","year":"2005"},{"abstractinfo":"用<span style=\"color:red\">氧化</span>-还原引发体系((NH4)2S2O8-NaHSO3)合成了氢<span style=\"color:red\">氧化铝</span>-聚丙烯酰胺<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>复合絮凝剂.电导和热失重研究的结果表明,<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>物聚丙烯酰胺链的端基(-SO2-4)与带正电荷的氢<span style=\"color:red\">氧化铝</span>胶体粒子以离子键性质键合.实验考察了反应温度,引发剂用量,氢<span style=\"color:red\">氧化铝</span>粒径和用量等因素对<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚丙烯酰胺合成的影响,发现氢<span style=\"color:red\">氧化铝</span>的存在可使<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>聚合物分子量显著提高.透射电镜结果显示原位聚合过程能使团聚的氢<span style=\"color:red\">氧化铝</span>胶体微粒纳米<span style=\"color:red\">化</span>.","authors":[{"authorName":"杨鹜远","id":"df155bec-1d56-49de-b391-08296dc8bb8c","originalAuthorName":"杨鹜远"},{"authorName":"钱锦文","id":"ca7bcd4c-f6e7-429e-9e42-5a086a62edda","originalAuthorName":"钱锦文"},{"authorName":"沈之荃","id":"b552d96a-e2cd-4e5a-9df8-a08e77a33cbd","originalAuthorName":"沈之荃"},{"authorName":"赵兴军","id":"0fbcb957-7f5e-4f43-ade2-a4b4179db9ae","originalAuthorName":"赵兴军"}],"doi":"","fpage":"68","id":"0745b7eb-7eda-46b2-85b7-3cc51b7056ea","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"63f537bd-0205-4a87-9550-e389bf203439","keyword":"有机-无机<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>","originalKeyword":"有机-无机杂化"},{"id":"751d3c78-0507-4c53-92ca-54be83863f00","keyword":"聚丙烯酰胺","originalKeyword":"聚丙烯酰胺"},{"id":"57b48897-d832-4142-bbf7-5387e7cc7c82","keyword":"氢<span style=\"color:red\">氧化铝</span>","originalKeyword":"氢氧化铝"},{"id":"d849966b-08b2-4202-b9cf-9af7e4ffa3b0","keyword":"絮凝剂","originalKeyword":"絮凝剂"},{"id":"fd5fb4a2-30e2-4bdf-abe5-0df73d65d7b9","keyword":"原位聚合","originalKeyword":"原位聚合"}],"language":"zh","publisherId":"gfzclkxygc200401017","title":"氢<span style=\"color:red\">氧化铝</span>-聚丙烯酰胺<span style=\"color:red\">杂</span><span style=\"color:red\">化</span>复合絮凝剂的合成与表征","volume":"20","year":"2004"}],"totalpage":6900,"totalrecord":69000}