{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"在酸性介质中,痕量Ru(Ⅲ)的存在对KIO4氧化偶氮氯膦Ⅲ的褪色反应有明显的催化作用, 且褪色程度与钌含量有很好的线性关系. 据此褪色反应, 提出了痕量钌的催化分光光度分析法. 方法检出限为0.001 μg/ml, 灵敏度高. 反应在水相中进行, 钌含量在0.002～0.020 μg/ml符合比耳定律. 可用于贵金属精矿中钌含量的测定.","authors":[{"authorName":"金灵芬","id":"ed1c76b7-59b8-4c41-aa2c-2803b5ec6bc0","originalAuthorName":"金灵芬"},{"authorName":"施卫国","id":"2fb7a9e1-33ca-4e3b-a529-20f969e63cf8","originalAuthorName":"施卫国"},{"authorName":"<span style=\"color:red\">刘</span><span style=\"color:red\">锡林</span>","id":"7a31716a-262e-4719-8a6c-994e68ec22a5","originalAuthorName":"刘锡林"},{"authorName":"寇宗燕","id":"2026a105-0293-4853-ac74-de99b5bc9497","originalAuthorName":"寇宗燕"}],"doi":"10.3969/j.issn.0258-7076.1998.06.005","fpage":"418","id":"3e84dbc4-57bf-47d5-afa9-42e220b4f5e9","issue":"6","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"6a2c1e4e-8a1e-43b5-a1f8-f6b41885b423","keyword":"钌","originalKeyword":"钌"},{"id":"3267480b-5ec6-41f5-8a59-ba052fb6398f","keyword":"偶氮氯膦Ⅲ","originalKeyword":"偶氮氯膦Ⅲ"},{"id":"036c9131-db6c-4574-8211-96a26763a5a3","keyword":"高碘酸钾","originalKeyword":"高碘酸钾"},{"id":"e2992eb9-2a59-4093-ae5e-79e6efef9054","keyword":"催化分光光度法","originalKeyword":"催化分光光度法"}],"language":"zh","publisherId":"xyjs199806005","title":"Ru(Ⅲ)-偶氮氯膦Ⅲ-KIO4体系催化分光光度法测定痕量钌","volume":"22","year":"1998"},{"abstractinfo":"在钯(Ⅱ)与对碘偶氮氯膦配合物中加入吐温-60,形成三元显色体系,后者的灵敏度有显著的提高,其表观摩尔吸光系数ε638=6.0×104 L*mol-1*cm-1,钯含量在 0.1～1.2 mg*L-1 范围内符合比耳定律;同时方法的选择性亦有所改善,可在水相中直接测定微量钯,常见阳离子对此反应均无干扰,其他贵金属离子也有数倍的允许值,在钯催化剂回收液和二次阳极泥的微量钯的测定中,获得满意的结果.","authors":[{"authorName":"<span style=\"color:red\">刘</span><span style=\"color:red\">锡林</span>","id":"af491646-9c74-4583-84cb-5ad8beb66dbb","originalAuthorName":"刘锡林"},{"authorName":"朱鑫","id":"28044071-0f8f-4f60-88fd-4d231d76d19e","originalAuthorName":"朱鑫"},{"authorName":"林安平","id":"1006956e-2a44-41f8-9649-5b5aed030848","originalAuthorName":"林安平"},{"authorName":"李欣","id":"a757a6db-ba6e-4b7e-8c3e-a6127716a0d7","originalAuthorName":"李欣"}],"doi":"10.3969/j.issn.0258-7076.2002.03.019","fpage":"235","id":"76541075-5e52-479d-8f02-19499a098c9c","issue":"3","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"712648c8-31e7-46bb-b386-8b98b5e303a0","keyword":"钯","originalKeyword":"钯"},{"id":"e8b0c835-ccc8-4c3e-9c7d-609158d925aa","keyword":"对碘偶氮氯膦","originalKeyword":"对碘偶氮氯膦"},{"id":"13d2bb44-e074-49d7-b8a0-45cee057661d","keyword":"吐温-60","originalKeyword":"吐温-60"},{"id":"d792da63-a0b4-4bc5-949a-712231620f8b","keyword":"分光光度法","originalKeyword":"分光光度法"}],"language":"zh","publisherId":"xyjs200203019","title":"钯(Ⅱ)-对碘偶氮氯膦-吐温-60三元体系分光光度法测微量钯的研究","volume":"26","year":"2002"},{"abstractinfo":"在酸性介质中,痕量Rh(Ⅲ)的存在对KIO4氧化偶氮氯膦-PN的褪色反应有明显的催化作用.据此褪色反应建立了测定痕量铑的催化光度法,Rh(Ⅲ)在0.02～0.08μg/10mL范围内服从比尔定律.反应在水相中进行,且重现性好,用于铂-铑催化剂中铑的测定,结果满意.","authors":[{"authorName":"李欣","id":"02866f98-c7d7-4a77-8015-db52452f348d","originalAuthorName":"李欣"},{"authorName":"<span style=\"color:red\">刘</span><span style=\"color:red\">锡林</span>","id":"9fe73cc2-0ac6-4ce8-a50e-b28089912b15","originalAuthorName":"刘锡林"}],"doi":"10.3969/j.issn.1000-7571.1999.03.004","fpage":"11","id":"c3a65b3e-2887-494d-ab13-ca4c08415b93","issue":"3","journal":{"abbrevTitle":"YJFX","coverImgSrc":"journal/img/cover/YJFX.jpg","id":"71","issnPpub":"1000-7571","publisherId":"YJFX","title":"冶金分析   "},"keywords":[{"id":"3018bf97-62a2-4f00-a109-e74fc46ab89e","keyword":"铑","originalKeyword":"铑"},{"id":"77e004dd-2e75-4016-b3d9-14dd40261b7a","keyword":"偶氮氯膦-PN","originalKeyword":"偶氮氯膦-PN"},{"id":"c8502902-96b7-4f86-bdf1-c51538ce17c7","keyword":"催化分光光度法","originalKeyword":"催化分光光度法"}],"language":"zh","publisherId":"yjfx199903004","title":"Rh(Ⅲ)-偶氮氯膦-PN-KIO4褪色反应催化光度法测定痕量铑","volume":"19","year":"1999"},{"abstractinfo":"根据对碘偶氮氯膦在微量铂系元素Ru、Rh、Os、Ir、Pt等离子的存在下与氧化剂KIO4(KBrO3)之间的褪色反应建立了这5种铂系元素的催化光度分析新方法;而对碘偶氮氯膦在硝酸介质中能与钯形成稳定的蓝色络合物又建立了分光光度法测定微量钯的新方法.作者研究了此系列反应的最佳条件及用于各种铂系元素测定的方法和应用.","authors":[{"authorName":"<span style=\"color:red\">刘</span><span style=\"color:red\">锡林</span>","id":"d1f5b8f6-d5ca-46e8-aec2-a3b3a6f6175a","originalAuthorName":"刘锡林"},{"authorName":"李欣","id":"79dbc660-700b-40cf-97ff-cd870b4ee2ae","originalAuthorName":"李欣"},{"authorName":"寇宗燕","id":"bcd5b29e-ac17-4e7b-bcca-705451843ac1","originalAuthorName":"寇宗燕"}],"doi":"10.3969/j.issn.1004-0676.2006.01.008","fpage":"38","id":"7ac9509f-78e2-4b92-aaa8-8ad9c38e69a8","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"61ae0030-b97d-458b-a526-37bcf07a24bf","keyword":"分析化学","originalKeyword":"分析化学"},{"id":"c19aadd6-33c9-496a-a8c3-b5014fcdc56d","keyword":"铂系元素","originalKeyword":"铂系元素"},{"id":"ce259555-8991-44ec-8a0d-bd75216171f6","keyword":"对碘偶氮氯膦","originalKeyword":"对碘偶氮氯膦"},{"id":"ee0e83d8-9471-4037-a327-a1223a5fe81a","keyword":"分光光度分析","originalKeyword":"分光光度分析"},{"id":"b84074a9-ee06-4740-ac47-e95199da3508","keyword":"催化光度分析","originalKeyword":"催化光度分析"}],"language":"zh","publisherId":"gjs200601008","title":"对碘偶氮氯膦用于微量铂系元素测定的应用研究","volume":"27","year":"2006"},{"abstractinfo":"当吐温-80存在时,Pd(Ⅱ)与二溴对甲偶氮羧的显色反应呈现了很高的灵敏度和选择性.其摩尔吸光系数ε623=4.6×104L·mol-1·cm-1,Pd含量在0.1 ～0.5μg·ml-1符合比耳定律.这种水相中直接测定微量钯的分光光度分析法已用于钯催化剂和二次阳极泥中微量钯的测定.","authors":[{"authorName":"<span style=\"color:red\">刘</span><span style=\"color:red\">锡林</span>","id":"057599a9-c7d3-4a50-9a13-96360acf1c00","originalAuthorName":"刘锡林"},{"authorName":"李俊庆","id":"80d54d08-c2b6-48cc-a0fa-a239e3eccaf2","originalAuthorName":"李俊庆"},{"authorName":"李欣","id":"823f66fa-60a0-402b-ab7d-cc256990706f","originalAuthorName":"李欣"}],"doi":"10.3969/j.issn.1004-0676.2000.04.010","fpage":"40","id":"e8fa6942-1fe8-41c6-8084-de29d23ffdf6","issue":"4","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"5770842d-6f90-4d26-a9d1-f828b6164c30","keyword":"钯","originalKeyword":"钯"},{"id":"1f7b3c11-b952-4524-8c92-9362f2325e55","keyword":"二溴对甲偶氮羧","originalKeyword":"二溴对甲偶氮羧"},{"id":"1b98a0c4-7e23-44bf-b3f3-dc6d7a55908e","keyword":"吐温-80","originalKeyword":"吐温-80"},{"id":"4a20dbeb-f377-4752-bc4e-c14656fb117d","keyword":"分光光度法","originalKeyword":"分光光度法"}],"language":"zh","publisherId":"gjs200004010","title":"Pd(Ⅱ)-二溴对甲偶氮羧-吐温-80用于微量钯的分光光度测定","volume":"21","year":"2000"},{"abstractinfo":"内蒙古<span style=\"color:red\">锡林</span>郭勒盟东部金属成矿带是中国重要的黑色金属、有色金属、贵金属成矿带,成矿带岩浆活动频繁,构造活动强烈,具备有利的成矿条件.通过对2个成矿带(东乌旗成矿带、西乌旗成矿带)的地质背景及成矿条件的研究,将东乌旗成矿带分为4个成矿亚带,西鸟旗成矿带分为2个成矿亚带,为下一步的地质找矿工作提供依据.","authors":[{"authorName":"杜继旭","id":"fd584c9e-5605-4769-b01e-db0a7c05ac10","originalAuthorName":"杜继旭"},{"authorName":"潘成林","id":"2d9e2d78-d308-4289-9a42-7a54cc16cd55","originalAuthorName":"潘成林"},{"authorName":"邱金柱","id":"2474a6dc-72af-4a95-9e2f-56448fd73709","originalAuthorName":"邱金柱"},{"authorName":"杨云鹏","id":"1e1d74b3-d31a-49a3-a790-1c80da0a957f","originalAuthorName":"杨云鹏"}],"doi":"10.11792/hj20160807","fpage":"29","id":"500e6a9a-d291-4f67-9d99-2d0225acffb5","issue":"8","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"234ef34d-b332-4ab1-b80d-bb028910cf34","keyword":"成矿带","originalKeyword":"成矿带"},{"id":"8090e080-2ef1-43ff-a166-52884abebb15","keyword":"成矿亚带","originalKeyword":"成矿亚带"},{"id":"214d318d-1c65-4ea5-b498-a4819fa7778c","keyword":"地质特征","originalKeyword":"地质特征"},{"id":"722c1f11-cd69-4dfa-8936-52ad489667aa","keyword":"划分","originalKeyword":"划分"},{"id":"a8343aef-70ac-4a69-a653-fbf9d67b10a2","keyword":"<span style=\"color:red\">锡林</span>郭勒盟东部","originalKeyword":"锡林郭勒盟东部"},{"id":"4cb1d4e4-8634-47ac-9f44-fffea1d483e7","keyword":"内蒙古","originalKeyword":"内蒙古"}],"language":"zh","publisherId":"huangj201608007","title":"内蒙古<span style=\"color:red\">锡林</span>郭勒盟东部金属成矿亚带的划分及其意义","volume":"37","year":"2016"},{"abstractinfo":"<span style=\"color:red\">刘</span>文中,关于贝氏体形成机制,包括形核过程的文献很少被引述。作者（<span style=\"color:red\">刘</span>等）的主要论点为贝氏体铁素体以无扩散、非切变机制在奥氏体内贫碳区形核,并未引述形成贫碳区的必要条件。本文作者强调,在钢及铜合金中,不可能由Spinodal分解和位错偏聚形成贫溶质区。<span style=\"color:red\">刘</span>等的理念未得到先进理论观点和精细实验结果的支持。在<span style=\"color:red\">刘</span>文中,据此对临界核心大小和形核能的计算并无显著意义,期望青年学者对贝氏体相变机制作进一步研究。","authors":[{"authorName":"徐祖耀","id":"f5bc6b26-ec4d-45e7-a1da-067daa9d3115","originalAuthorName":"徐祖耀"}],"doi":"","fpage":"158","id":"66a9e9e8-09a0-408c-8c33-bc00aeff35c0","issue":"2","journal":{"abbrevTitle":"CLRCLXB","coverImgSrc":"journal/img/cover/CLRCLXB.jpg","id":"15","issnPpub":"1009-6264","publisherId":"CLRCLXB","title":"材料热处理学报"},"keywords":[{"id":"5224cfe0-dd6d-4ccc-aac3-2bed80f388a5","keyword":"贝氏体形核","originalKeyword":"贝氏体形核"},{"id":"cae16aae-8a2b-43f5-9886-1ca5759c5972","keyword":"扩散机制","originalKeyword":"扩散机制"},{"id":"36bc9f8f-ee13-4c27-8020-c2c5b0dfca8f","keyword":"切变机制","originalKeyword":"切变机制"},{"id":"a3bb808d-ba7a-4c9a-90ff-d5e59a6a0f1a","keyword":"贫碳区","originalKeyword":"贫碳区"}],"language":"zh","publisherId":"jsrclxb201202033","title":"评<span style=\"color:red\">刘</span>宗昌等《贝氏体铁素体的形核》一文","volume":"33","year":"2012"},{"abstractinfo":"利用质子激发X射线荧光分析(PIXE)测试分析汝官瓷、张公巷窑青瓷和<span style=\"color:red\">刘</span>家门窑青瓷样品的主要化学组成,用多元统计判别分析方法对数据进行分析,以确定它们的分类和起源关系.结果表明:汝官瓷、张公巷窑青瓷和<span style=\"color:red\">刘</span>家门窑青瓷釉基本能很好的区分；但是胎区分得不是很理想,张公巷窑青瓷的胎可以和汝官瓷、<span style=\"color:red\">刘</span>家门窑青瓷胎很好的区分,汝官瓷胎和<span style=\"color:red\">刘</span>家门窑青瓷胎有个别样品不能分开.","authors":[{"authorName":"蔡敏敏","id":"bf1f4660-208a-4999-ac81-266bf48c5bcb","originalAuthorName":"蔡敏敏"},{"authorName":"李国霞","id":"f8d3a4dc-7472-4dd6-9382-9f4430feef58","originalAuthorName":"李国霞"},{"authorName":"赵维娟","id":"9572b140-eca3-4192-af6e-ab9fdb21502b","originalAuthorName":"赵维娟"},{"authorName":"李融武","id":"e2d1fb82-016c-4ae3-9ee6-0cabbe60a2a0","originalAuthorName":"李融武"},{"authorName":"赵文军","id":"ea875a05-c1f7-4a8f-b405-2005de7db87c","originalAuthorName":"赵文军"},{"authorName":"承焕生","id":"9ff5fa85-a1fb-4cd2-bdc3-3bd240fd6894","originalAuthorName":"承焕生"},{"authorName":"郭敏","id":"d4074d21-787e-429b-8123-a13fcf5ce433","originalAuthorName":"郭敏"}],"doi":"","fpage":"1363","id":"f1ea8842-b3fe-42a2-9557-aa4c186cac5a","issue":"6","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"d281b6ff-a4b5-41d8-ad69-47236e801de5","keyword":"汝官瓷","originalKeyword":"汝官瓷"},{"id":"adf8b648-9625-4b38-96ff-ec6174d0c5d4","keyword":"张公巷窑青瓷","originalKeyword":"张公巷窑青瓷"},{"id":"3a61e23c-a3f8-43e6-84fc-1b7cd4edef5b","keyword":"<span style=\"color:red\">刘</span>家门窑青瓷","originalKeyword":"刘家门窑青瓷"},{"id":"494e2983-99cd-4c53-a919-4bfad5b7c54a","keyword":"判别分析","originalKeyword":"判别分析"}],"language":"zh","publisherId":"gsytb201206005","title":"汝官瓷、张公巷窑青瓷和<span style=\"color:red\">刘</span>家门窑青瓷的判别分析研究","volume":"31","year":"2012"},{"abstractinfo":"本文采用质子激发X射线荧光分析(PIXE)技术测试了34个汝官瓷样品、30个蓝色系列钧官瓷样品(不含红釉系列)和17个<span style=\"color:red\">刘</span>家门窑青瓷样品的主量化学组成含量,根据这些样品的主量化学组成含量数据,应用多元统计分析方法进行分析.结果表明:汝官瓷、钧官瓷和<span style=\"color:red\">刘</span>家门窑青瓷的釉样品能够较好的区分开;但是3种瓷胎并不能很好的分开.","authors":[{"authorName":"肖朋飞","id":"6c5bc42f-0f99-48b4-b412-749a9ae0e046","originalAuthorName":"肖朋飞"},{"authorName":"赵红梅","id":"27edfee9-f617-4a36-af10-1a11a2aec85c","originalAuthorName":"赵红梅"},{"authorName":"李融武","id":"019184bd-8770-4aad-9618-4e2e6642f646","originalAuthorName":"李融武"},{"authorName":"赵文军","id":"6c10bb80-2026-4274-9965-bf564b102cc6","originalAuthorName":"赵文军"},{"authorName":"李国霞","id":"6f63b95a-67cb-4f68-b4b5-7c0b6f8f38e7","originalAuthorName":"李国霞"},{"authorName":"赵维娟","id":"ee11e4bc-a40c-4de3-90c4-e81dd16a55e3","originalAuthorName":"赵维娟"},{"authorName":"承焕生","id":"528f9874-c9c9-4258-bc3c-5a0d9ea8b362","originalAuthorName":"承焕生"}],"doi":"","fpage":"312","id":"3b352bdd-7627-42ad-a3b3-45e88dc561eb","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"080b7cee-826f-4a82-af62-9feed6531e66","keyword":"汝官瓷","originalKeyword":"汝官瓷"},{"id":"684a6128-65b6-45ce-be61-e74720b4c844","keyword":"钧官瓷","originalKeyword":"钧官瓷"},{"id":"14ccb09f-07d1-4f4b-bb41-c0ad3eea1fa0","keyword":"<span style=\"color:red\">刘</span>家门窑青瓷","originalKeyword":"刘家门窑青瓷"},{"id":"4b254520-d0a1-406e-a9ef-92267cd23fb0","keyword":"PIXE","originalKeyword":"PIXE"},{"id":"12b26595-24a4-4ea9-b303-ae046a74c72d","keyword":"因子分析","originalKeyword":"因子分析"}],"language":"zh","publisherId":"gsytb201102013","title":"汝官瓷、钧官瓷和<span style=\"color:red\">刘</span>家门窑青瓷的多元统计分析","volume":"30","year":"2011"},{"abstractinfo":"","authors":[{"authorName":"史景利","id":"eb3ee983-3b98-452d-bd41-180cba2f25e6","originalAuthorName":"史景利"},{"authorName":"宋进仁","id":"e0292a69-a79a-4255-b798-ef2706c5416b","originalAuthorName":"宋进仁"}],"doi":"10.3969/j.issn.1007-8827.2004.02.015","fpage":"158","id":"cf9f8f06-799b-40d4-a4ee-26ab16ebdaf7","issue":"2","journal":{"abbrevTitle":"XXTCL","coverImgSrc":"journal/img/cover/XXTCL.jpg","id":"70","issnPpub":"1007-8827","publisherId":"XXTCL","title":"新型炭材料"},"keywords":[{"id":"474a985e-f87f-4649-87f2-8bd88c9cece1","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"xxtcl200402015","title":"<span style=\"color:red\">刘</span>朗研究员和他的研究活动","volume":"19","year":"2004"}],"totalpage":5,"totalrecord":46}