采集了卧龙湖煤矿松散层水、砂岩水和灰岩水样品进行稀土元素测试分析,结果表明,卧龙湖矿区三个含水层均呈现偏碱性水质,稀土总量偏低(∑REE =0.046 μg/L ~0.15 μg/L),经后太古代平均页岩标准化后,均表现为轻稀土亏损,重稀土富集,所有样品均表现为明显的Eu正异常(δEu =1.12~11.36),多数样品表现为Ce负异常,灰岩水表现明显的Y正异常;这些特征受到多种因素控制,其中Ce负异常主要受到地下水氧化还原环境的影响,而Eu异常除受到了测试条件影响外,长石的溶解、氧化还原条件及灰岩水中过高的Sr都有一定的影响,Y异常和灰岩水中较高的Y/Ho值分别受到Sr含量和Ca的影响.这些特征及影响因素均表明利用稀土元素特征进行矿井水源识别具有一定的可行性.
参考文献
[1] | 陈松,傅雪海,孙林华,桂和荣.皖北新元古代-寒武纪界线灰岩稀土元素地球化学特征[J].中国稀土学报,2013(01):108-118. |
[2] | 孙林华,桂和荣,贺振宇.皖北灵璧地区新元古代灰岩的稀土元素特征[J].稀土,2010(06):32-40. |
[3] | 李善平,谢智勇,李小雪,白宗海,陈静,任华.青海大风山天青石矿稀土元素地球化学特征及物源分析[J].稀土,2013(01):41-48. |
[4] | SUN Linhua,GUI Herong,CHEN Song.Rare earth element geochemistry of groundwaters from coal bearing aquifer in Renlou coal mine, northern Anhui Province, China[J].稀土学报(英文版),2011(02):185-192. |
[5] | Banks D.;Reimann C.;Siewers U.;Hall G. .Distribution of rare earth elements in crystalline bedrock groundwaters: Oslo and Bergen regions, Norway[J].Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry,1999(1):27-39. |
[6] | 陈松,桂和荣,孙林华,刘向红.灰岩含水层中稀土元素在地下水与围岩间的分异:以皖北任楼煤矿太原组灰岩含水层为例[J].现代地质,2011(04):802-807,818. |
[7] | Nelson BJ.;Wood SA.;Osiensky JL. .Partitioning of REE between solution and particulate matter in natural waters: a filtration study[J].International Journal of Quantum Chemistry,2003(1/2):51-56. |
[8] | Quinn KA;Byrne RH;Schijf J .Comparative scavenging of yttrium and the rare earth elements in seawater: Competitive influences of solution and surface chemistry[J].Aquatic geochemistry,2004(1/2):59-80. |
[9] | Koppi AJ.;Field DJ.;Geering HR.;Klessa DA.;Cockayne DJH.;Edis R. .RARE EARTH ELEMENT TRENDS AND CERIUM-URANIUM-MANGANESE ASSOCIATIONS IN WEATHERED ROCK FROM KOONGARRA, NORTHERN TERRITORY, AUSTRALIA[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,1996(10):1695-1707. |
[10] | Lee SG.;Lee DH.;Kim Y.;Chae BG.;Kim WY.;Woo NC. .Rare earth elements as indicators of groundwater environment changes in a fractured rock system: evidence from fracture-filling calcite[J].Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry,2003(1):135-143. |
[11] | Tanaka K.;Miura N.;Asahara Y.;Kawabe I. .Rare earth element and strontium isotopic study of seamount-type limestones in Mesozoic accretionary complex of Southern Chichibu Terrane, central Japan: Implication for incorporation process of seawater REE into limestones[J].Geochemical Journal,2003(2):163-180. |
[12] | Bau M.;Dulski P.;Hein JR.;Koschinsky A. .COMPARISON OF THE PARTITIONING BEHAVIOURS OF YTTRIUM, RARE EARTH ELEMENTS, AND TITANIUM BETWEEN HYDROGENETIC MARINE FERROMANGANESE CRUSTS AND SEAWATER[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,1996(10):1709-1725. |
[13] | Tang JW;Johannesson KH .Controls on the geochemistry of rare earth elements along a groundwater flow path in the Carrizo Sand aquifer, Texas, USA[J].Chemical geology,2006(1-2):156-171. |
[14] | 桂和荣,孙林华.皖北任楼煤矿深层地下水稀土元素地球化学特征[J].煤炭学报,2011(02):210-216. |
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