概述了多壁富勒烯和新型纳米碳结构(纳米碳球)的表面修饰方法以及在催化中的应用研究现状,结果表明,化学氧化法对纳米碳颗粒进行表面修饰是有效的方法,可以改善其惰性表面,使其功能化.由于结构的独特性,纳米碳颗粒作为载体材料在电催化和某些脱氢反应中已经显示了较好的催化性能.预测了纳米碳在合成低碳烯烃中的潜在应用前景并为其在能源、化工领域中的应用提供了新的思路.
参考文献
[1] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56. |
[2] | Ugarte D .Curling and closure of graphitic network under electron-beam irradiation[J].Nature,1992,359:707. |
[3] | Loutfy R;Pugazhendhi P et al.Fullerene-based electrolyte for fuel cells[P].US,6949304,2005-09-27. |
[4] | Chai GS;Yoon SB;Kim JH;Yu JS .Spherical carbon capsules with hollow macroporous core and mesoporous shell structures as a highly efficient catalyst support in the direct methanol fuel cell[J].Chemical communications,2004(23):2766-2767. |
[5] | Nicolas Keller;Nadezhda I.Maksimova;Vladimir V.Roddatis;Michael Schur;Gerhard Mestl;Robert Schlogl;Yurii V.Butenko;Vladimir L.Kuznetsov .The catalytic use of onion-like carbon materials for styrene synthesis by oxidative dehydrogenation of ethylbenzene[J].Angewandte Chemie International Edition,2002(11):1885-1888. |
[6] | Xu B S et al.A novel catalyst support for DMFC:Onion-like fullerenes[J].Journal of Power Sources,2006,162:160. |
[7] | Hirata A;Igarashi M et al.Study on solid lubricant pro-perties of carbon onions produced by heat treatment of diamond clusters or particles[J].Tribology International,2004,37:899. |
[8] | Choi M;Altman I S et al.Formation of shell-shaped carbon nanoparticles above a critical laser power in irradiated acetylene[J].Advanced Materials,2004,16:1721. |
[9] | Herring A M et al.A novel method for the templated synthesis of homogeneous samples of hollow carbon nanos-pheres from cellulose chars[J].Journal of the American Chemical Society,2003,125:9916. |
[10] | Yu JC;Hu XL;Li Q;Zheng Z;Xu YM .Synthesis and characterization of core-shell selenium/carbon colloids and hollow carbon capsules[J].Chemistry: A European journal,2005(2):548-552. |
[11] | Rodriguez N M et al.Carbon nanofibers:A unique catalyst support medium[J].Journal of Physical Chemistry,1994,98:13108. |
[12] | Koudoumas E.;Kokkinaki O.;Konstantaki M.;Couris S.;Korovin S.;Detkov P.;Kuznetsov V.;Pimenov S.;Pustovoi V. .Onion-like carbon and diamond nanoparticles for optical limiting[J].Chemical Physics Letters,2002(5-6):336-340. |
[13] | Langlet R;Lambin P;Mayer A;Kuzhir PP;Maksimenko SA .Dipole polarizability of onion-like carbons and electromagnetic properties of their composites[J].Nanotechnology,2008(11):15706-1-15706-8-0. |
[14] | Yu X W;Ye S Y .Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC.Part I:Physico-chemical and electronic interaction between Pt and carbon support,and activity enhancement of Pt/C catalyst[J].Journal of Power Sources,2007,172:133. |
[15] | Matsumoto T;Komatsu T et al.Efficient usage of highly dispersed Pt on carbon nanotubes for electrode catalysts of polymer electrolyte fuel cells[J].Catalysis Today,2004,90:277. |
[16] | Li X;Hsing I .The effect of the Pt deposition method and the support on Pt dispersion on carbon nanotubes[J].Electrochimica Acta,2006,51:5250. |
[17] | Rajalakshmi N;Ramaprabhu S et al.Performance of polymer electrolyte membrane fuel cells with carbon nanotubes as oxygen reduction catalyst support material[J].Journal of Power Sources,2005,140:250. |
[18] | 华丽,胡长员,李凤仪,张荣斌.碳纳米管预处理及其在催化材料中应用[J].化学研究与应用,2006(07):765-769. |
[19] | Effect of chemical treatment to hollow carbon nanoparticles (HCNP) on catalytic behaviors of the platinum catalysts[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2008(5 Pt.2):2989. |
[20] | A.Valente;C.Palma;I.M.Fonseca;A.M.Ramos;J.Vital .Oxidation of pinane over phthalocyanine complexes supported on activated carbon:Effect of the support surface treatment[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(14):2793-2803. |
[21] | Cerro-Alarcon M;Maroto-Valiente A et al.Further insights into the Ru nanoparticles-carbon interactions and their role in the catalytic properties[J].Carbon,2005,43:2711. |
[22] | Seok K;Soo-Jin P .Effects of chemical treatment of carbon supports on electrochemical behaviors for platinum catalysts of fuel cells[J].Journal of Power Sources,2006,159:42. |
[23] | Shioyama H;Honjo K et al.C2F6 plasma treatment of a carbon support for a PEM fuel cell electrocatalyst[J].Journal of Power Sources,2006,161:836. |
[24] | Zhicheng Tang;Qiuye Li;Gongxuan Lu .The effect of plasma pre-treatment of carbon used as a Pt catalyst support for methanol electrooxidation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(1):41-46. |
[25] | Planeix J M;Coustel N et al.Application of carbon nanotubes as supports in heterogeneous catalysis[J].Journal of the American Chemical Society,1994,116:7935. |
[26] | Li W;Liang C et al.Preparation and characterization of multiwalled carbon nanotubes supported platinum for catho-de catalysts of direct methanol fuel cells[J].Journal of Physical Chemistry B,2003,107:6292. |
[27] | 徐明丽,张正富,杨显万.纳米材料及其在电催化领域的研究进展[J].材料导报,2006(z2):1-6. |
[28] | Gerhard Mestl;Nadezhda I. Maksimova;Nicolas Keller;Vladimir V. Roddatis;Robert Schlogl .Carbon Nanofilaments in Heterogeneous Catalysis: An Industrial Application for New Carbon Materials?[J].Angewandte Chemie International Edition,2001(11):2066-2068. |
[29] | Liu Y C et al.Methanol electro-oxidation on mesocarbon microbead supported Pt catalysts[J].Carbon,2002,40:2375. |
[30] | Sangjin Han;Youngkwang Yun;Kyung-Won Park;Yung-Eun Sung;Taeghwan Hyeon .Simple Solid-Phase Synthesis of Hollow Graphitic Nanoparticles and their Application to Direct Methanol Fuel Cell Electrodes[J].Advanced Materials,2003(22):1922-1925. |
[31] | Wen ZH;Wang Q;Zhang Q;Li JH .Hollow carbon spheres with wide size distribution as anode catalyst support for direct methanol fuel cells[J].Electrochemistry communications,2007(8):1867-1872. |
[32] | Song YY;Li Y;Xia XH .One-step pyrolysis process to synthesize dispersed Pt/carbon hollow nanospheres catalysts for electrocatalysis[J].Electrochemistry communications,2007(2):201-205. |
[33] | 杜建平,宋昌,宋金玲,赵江红,朱珍平.纳米碳材料负载铂催化剂在环己烷脱氢反应中的催化性能研究[J].燃料化学学报,2009(04):468-472. |
[34] | 杜建平,赵江红,朱珍平.纳米碳颗粒负载碳化钼复合物的制备及其催化性能研究[J].化工新型材料,2009(05):25-27. |
[35] | Venter J J;Kaminsky M et al.Carbon-supported Fe-Mn and K-Fe-Mn clusters for the synthesis of C2-C4 olefins from CO and H2:I.Chemisorption and catalytic behavior[J].Journal of Catalysis,1987,103:450. |
[36] | 张敬畅,卫国宾,曹维良.合成气制低碳烯烃用Fe/AC催化剂的制备及性能表征[J].催化学报,2003(04):259-264. |
[37] | Wenping Ma;Yunjie Ding;Jing Yang;Xing Liu;Liwu Lin .Study of activated carbon supported iron catalysts for the fischer-tropsch synthesis[J].Reaction kinetics & catalysis letters,2005(1):11-19. |
[38] | Rodriguez-Reinoso F. .The role of carbon materials in heterogeneous catalysis[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(3):159-175. |
[39] | Bahome MC;Jewell LL;Hildebrandt D;Glasser D;Coville NJ .Fischer-Tropsch synthesis over iron catalysts supported on carbon nanotubes[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1):60-67. |
[40] | Yu, ZX;Borg, O;Chen, D;Enger, BC;Froseth, V;Rytter, E;Wigum, H;Holmen, A .Carbon nanofiber supported cobalt catalysts for fischer-tropsch synthesis with high activity and selectivity[J].Catalysis Letters,2006(1/2):43-47. |
[41] | Reza M. Malek Abbaslou;Ahmad Tavasoli;Ajay K. Dalai .Effect of pre-treatment on physico-chemical properties and stability of carbon nanotubes supported iron Fischer-Tropsch catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2009(1/2):33-41. |
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