Preliminary Research on Structure and Properties of Nano-cellulose

武汉理工大学学报-材料科学版(英文版), 2007, 22(4): 677-680.

^1, , ^2, , ^3, , ^4,

1.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

2.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

3.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

4.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

基金项目: Postdoctoral Research Support Program of Jiangsu Province

Preliminary Research on Structure and Properties of Nano-cellulose

SUN Dongping ^1, , ZHOU Lingli ^2, , WU Qinghang ^3, , YANG Shulin ^4,

1.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

2.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

3.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

4.School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing,210094, China

Keywords： nano-cellulose

The structure of bacterial cellulose (BC) produced by Acetobacter xylinum NUST4 (A.xylinum NUST4) under static (SBC) and shake culture condition (ABC) was studied by means of transmission electron microscopic (TEM), X-ray diffraction (XRD) and Fourier transform-infrared spectrum (FT-IR). It was revealed that BC is Ⅰ crystal cellulose and the proportion of cellulose Ⅰα exceeds 80% and BC diameter is 10-80 nm.Mechanical properties and water absorption capacity were also determined. These properties could result from crystalline and nanometer structure of BC.

参考文献

[1]	A C O'Sullivan .Cellulose:The Structure Slowly Unravels[J].Cellulose,1997,4:173-207.
[2]	S Hestrin;M Schramm .Synthesis of Cellulose by Acetobacter xylinum 2.Preparation of Freeze-Dried Cells Capable of Polymerizing Glucose to Cellulose[J].Biochemical Journal,1954,58:345-352.
[3]	K Zaar .Visualization of Pores (Export Sites) Correlated With Cellulose Production in the Envelope of the Gram-Negative Bacterium Acetobacter xylinum[J].Journal of Cell Biology,1979,80:773-777.
[4]	Mitsuro Ishihara;Masahiro Matsunaga;Noriko Hayashi;Vesna Tisler .Utilization of D-xylose as carbon source for production of bacterial cellulose[J].Enzyme and Microbial Technology,2002(7):986-991.
[5]	Dieter Klemm;Dieter Schumann;Ulrike Udhardt;Silvia Marsch .Bacterial synthesized cellulose-artificial blood vessels for microsurgery[J].Progress in Polymer Science,2001(9):1561-1603.
[6]	Vandamme EJ.;Vanbaelen A.;Joris K.;De Wulf P.;De Baets S. .Improved production of bacterial cellulose and its application potential[J].Polymer Degradation and Stability,1998(1/3):93-99.
[7]	K Watanabe;M Tabuchi;Y Morinaga;F Yoshinaga .Structure Features and Properties of Bacterial Cellulose Produced in Agitated Culture[J].Cellulose,1998,5:187-200.
[8]	Vinita Dubey;Chhaya Saxena;Lokendra Singh;R.S.Chauhan .Pervaporation of binary water-ethanol mixtures through bacterial cellulose membrane[J].Separation and Purification Technology,2002(2):163-171.
[9]	Evans BR.;O'Neill HM.;Malyvanh VP.;Lee I.;Woodward J. .Palladium-bacterial cellulose membranes for fuel cells[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2003(7):917-923.
[10]	M. IGUCHI;S. YAMANAKA;A. BUDHIONO .Bacterial cellulose—a masterpiece of nature's arts[J].Journal of Materials Science,2000(2):261-270.
[11]	Svensson A;Nicklasson E;Harrah T;Panilaitis B;Kaplan DL;Brittberg M;Gatenholm P .Bacterial cellulose as a potential scaffold for tissue engineering of cartilage.[J].Biomaterials,2005(4):419-431.
[12]	Mihranyan A;Llagostera AP;Karmhag R;Stromme M;Ek R .Moisture sorption by cellulose powders of varying crystallinity.[J].International Journal of Pharmaceutics,2004(2):433-442.
[13]	L N Zhang;Q Xi;Z S Mo;X G Jin.Current Researching Methods on Polymer Physics[M].武汉:武汉大学出版社,2003:194-195.
[14]	熊犍,叶君,梁文芷,范佩明.微波对纤维素Ⅰ超分子结构的影响[J].华南理工大学学报,2000(03):84-89.
[15]	T Imai;J Sugiyama .Nanodomains of Ⅰα and Ⅰβ Cellulose in Algal Microfibrils[J].Macromolecules,1998,31:6275-6279.
[16]	GB 1040-1979.GB 1040-1979.Tensile Testing Method on Plastic[S].,1979.
[17]	GB 1039-1979.GB 1039-1979.General Principles of Mechanical Properties Testing Methods on Plastic[S].,1979.
[18]	郝常明,罗祎.细菌纤维素--一种新兴的生物材料[J].纤维素科学与技术,2002(02):56-61.
[19]	F Yoshinaga;N Tonouchi;K Watanabe .Research Process in Production Cellulose by Aeration and Agitation Culture and Its Application as a New Industrial Material[J].J Biotech Biochem,1997,61(02):219-224.
[20]	C Tokoh;K Takabe;M Fujita .Cellulose Synthesized by Acetobacter xylinum in the Presence of Acetyl Glucomannan[J].Cellulose,1998,5:249-261.
[21]	S Yamanaka;M Ishihara;J Sugiyama .Structure Modification of Bacterial Cellulose[J].CELLULOSE,2000,7:213-225.
[22]	K Abe;J Sugiyama;Itoh T;M Ishihara S Yamanaka .Crystalline Feature of Bacterial Cellulose Altered by Chemical Agents During Biosynthesis[J].Wood Research,1998,85:66-67.
[23]	A N Nakagaito;S Iwamoto;H Yano .Bacterial Cellulose:the Ultimate Nano-Scalar Cellulose Morphology for the Production of High-Strength Composites[J].Applied Physics A,2004,DOI:10.

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Preliminary Research on Structure and Properties of Nano-cellulose

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