采用高频感应熔炼方法制备了PuNi3型La0.67Mg0.33Ni2.5Co0.5合金;用X射线衍射分析和电化学方法研究了添加不同Mg含量以补偿Mg元素烧损时合金的组织结构和电化学性能.X射线衍射分析(XRD)表明,铸态合金由PuNi3型主相和少量的CaCu5型第二相组成,铸态合金经1 223 K和10 h退火处理后,CaCu5型第二相可明显减少,其中Mg增加10%时得到纯度较高的PuNi3型组织.电化学测试表明,增加适当Mg含量和进行退火热处理能明显提高和改善合金电极容量、循环稳定性和大电流放电性能.与AB5型和AB2型Laves相贮氢合金比较,PuNi3型La0.67Mg0.33Ni2.5Co0.5贮氢合金具有电极容量高及优良的大电流放电性能.
参考文献
[1] | 江建军,雷永泉,孙大林.非化学计量比贮氢电极合金的电化学性能和结构及热力学研究[J].稀有金属材料与工程,1997(03):14-19. |
[2] | Ovshinsky S R;Fetcenko M A;Ross J .[J].科学(上海),1993,260:176. |
[3] | Reilly JJ;Johnson JR;Vogt T;Mukerjee S;McBreen J;Adzic GD .Correlation between composition and electrochemical properties of metal hydride electrodes[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):569-582. |
[4] | Dong-Myung Kim;Kuk-Jin Jang;Jai-Young Lee.[J].Journal of Alloys and Compounds,1999:293-295:583-592. |
[5] | Don T Cromer;Clayton E Olsen .[J].Acta Crystallographica,1959,12:689. |
[6] | Parthe E;Lemaire R .[J].Acta Crystallographica,1975,B31:1879. |
[7] | Yartys V A et al.[J].International Journal of Hydrogen Energy,1982,7:957-965. |
[8] | Kadir K;Sakai T;Uehara I .[J].Journal of Alloys and Compounds,1997,257:115-121. |
[9] | Inui H;Yamamoto T;Zhang Di.[J].Journal of Alloys and Compounds,1999:203-295:140-145. |
[10] | Kohno T;Yoshida H;Kawashima F et al.[J].Journal of Alloys and Compounds,2000,311:L5-L7. |
[11] | Chen J;Kuriyama N;Takeshita H T et al.[J].Electrochemical and Solid-State Letters,2000,3(06):249-252. |
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