欢迎登录材料期刊网

材料期刊网

高级检索

利用Cyanex 923萃取法制备了纳米级CeF3微粉,并研究了分散剂、 CeF3量、 CeF3预处理灼烧温度和微粉粒径分布等因素对CeF3紫外吸收行为的影响. 结果表明,CeF3在255 nm附近有特征吸收峰;分散剂的极性强弱、 分散物浓度的改变都会影响吸收峰的强弱;随着粒径的减小,紫外吸收峰发生明显的红移. 此外还研究了TiO2包覆CeF3的紫外吸收性质,复合材料在250~400 nm区间内同时出现了TiO2和CeF3的特征吸收峰,复合材料的吸光域范围扩展.

参考文献

[1] Masakazu Anpo;Masato Takeuchi .The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation[J].Journal of Catalysis,2003,216(02):505.
[2] 宋绵新,周天亮,丁建旭,边亮,王峰.稀土-沸石-TiO2三元体系光催化材料的性能研究[J].中国稀土学报,2007(02):172-177.
[3] 张莉莉,刘冠鹏,张维光,陆路德,杨绪杰,汪信.层状光催化材料H2La2Ti3O10/CdS的制备及其性质研究[J].中国稀土学报,2006(02):168-173.
[4] Rodriguez JA.;Garcia J.;Gonzalez L. .Electronic and chemical properties of mixed-metal oxides: adsorption of SO2 on SrTiO3(001)[J].Chemical Physics Letters,2002(5-6):380-386.
[5] Futamura Shigeru;Zhang Aihua;Einaga Hisahiro;Kabashima Hajime .Involvement of catalyst materials in nonthermal plasma chemical processing of hazardous air pollutants[J].Catalysis Today,2002,72(3-4):259.
[6] Jong Rack Sohn;Jun Seob Lim .Catalytic properties of NiSO_4/ZrO_2 promoted with Fe_2O_3 for acid catalysis[J].Materials Research Bulletin,2006(7):1225-1241.
[7] Qiu SQ.;Chen GX.;Dong JX. .Synthesis of CeF3 nanoparticles from water-in-oil microemulsions[J].Powder Technology,2000(1/2):9-13.
[8] 徐光宪.稀土(中册)[M].北京:冶金工业出版社,1995:27.
[9] 王亚军,刘前,索全伶,郝东升,郭锋.稀土氟化物的沉淀方法及组成研究[J].稀土,2000(01):14-18.
[10] 吴志申,陶小军,周静芳,党鸿辛.CeF3纳米微粒的合成、结构及摩擦学行为研究[J].稀土,2001(05):1-4.
[11] 张秀凤,涂华民,张迈生,林木良.纳米氟化铈(Ⅲ)的微波固相氧化还原合成法[J].材料导报,2003(01):78-80.
[12] Milan-Johann Schwuger;Katrin Stickdorn;Reinhard Schomaecker .Microemulsions in Technical Processes[J].Chemical Reviews,1995(4):849-864.
[13] Santra S;Tapec R;Theodoropoulou N .Synthesis and characterization of silica-coated iron oxide nanoparticles in microemulsion:the effect of nonionic surfactants[J].Langmuir,2001,17:2900.
[14] Wu M L;Chen D H;Huang T C .Preparation of Au/Pt bimetallic nanoparticles in water-in-oil microemulsions[J].CHEMISTRY OF MATERIALS,2001,13:599.
[15] Li Y C;Park C W .Particle size distribution in the synthesis of nanoparticles using microemulsions[J].Langmuir,1999,15:952.
[16] 李德谦;李红飞;国富强;张志峰 .一种制备高纯三氟化铈微粉的方法[P].CN 200410010618.2,2006.
[17] Lu J;Wei Z G;Li D Q .Recovery of Ce(Ⅳ) and Th(Ⅳ) from rare earths(Ⅲ) with Cyanex 923[J].Hydrometallurgy,1998,50(01):77.
[18] 李德谦;国富强;李红飞;张志峰,孟淑兰 .中性磷(膦)萃取体系制备稀土氟化物微粉调控粒径的方法[P].CN 200610163213.1,2006.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%