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实验在MoSi2电阻炉内用饱和浓度法测试了FeCN体系氮的浓度和活度,并根据含化合物的金属熔体结构的共存理论模型,推导了FeCN金属熔体作用浓度计算模型。实验测得1 485 ℃碳饱和的FeCN熔体中在氮分压01 MPa时氮的溶解度为0006 5%,并且计算的作用浓度与相应的实测活度相符合,从而证明所得模型可以反映FeCN金属熔体的结构本质,由模型得出金属熔体高碳含量有利于脱氮。

In MoSi2 high temperature furnace the concentration and activity of N in FeCN system were measured, and according to the coexistent theory about metal melt structure containing compounds, the computational model of action concentration of FeCN system is got. The experimental result shows that at 1 485 ℃ the nitrogen solubility in this carbon saturation melt is 0006 5% for nitrogen partial pressure of 01 MPa. The computed action concentration accords with the relevant measured activity, which proves that the model can express the structural quality of FeCN metal melt. This model shows that high carbon content in metal melt is beneficial to the denitrification.

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