功能材料, 2002, 33(5): 568-570.
导电聚合物发光材料能隙和能带参数的确定方法
佟拉嘎 1, , 蹇锡高 2, , 王锦艳 3, , 尹军英 三苯胺(MeO-TPA)和4,4'.二甲氧基三苯胺(DMeO-TPA)两种具有良好溶解性的甲氧基取代三苯胺,通过FFIR、'H NMR和元素分析等手段对其进行了表征,并采用循环伏安(CV)结合UV-Vis吸收光谱测试了其能级结构.以甲氧基取代三苯胺为电荷传输材料,TiOPc为电荷产生材料制备了双层光电导体,测试了其光敏性.结果表明MeO-TPA和DMeO-TPA具有较三苯胺(TPA)更为优良的空穴传输性能.","authors":[{"authorName":"徐清","id":"682b14aa-cdd0-4251-90d9-3ea085ad331c","originalAuthorName":"徐清"},{"authorName":"陈红征","id":"b673e094-aee2-4393-bfc5-d9dbe5e5e76e","originalAuthorName":"陈红征"},{"authorName":"施敏敏","id":"758381e3-43dc-4258-9d7d-e0c9e91295b2","originalAuthorName":"施敏敏"},{"authorName":"汪茫","id":"af96e53a-4f47-4f74-a2b0-55f175734216","originalAuthorName":"汪茫"}],"doi":"10.3969/j.issn.1673-2812.2007.02.007","fpage":"190","id":"65c4ad43-4bd1-4fd0-a424-8f4d54b94975","issue":"2","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"7a14bd1e-5a7b-4ce6-81f7-cc299bb6f07e","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"5abe6e66-00fe-4083-8ab4-d5f5cbdbafc8","keyword":"甲氧基","originalKeyword":"甲氧基"},{"id":"fb9e238f-0583-471c-b0aa-2b8e46f99f96","keyword":"合成","originalKeyword":"合成"},{"id":"c5f22bb9-ef35-49cc-b8fa-b076f684b96d","keyword":"空穴传输材料","originalKeyword":"空穴传输材料"},{"id":"565cb91f-cf88-4fa8-82e3-6e4385b4701e","keyword":"有机光电导体","originalKeyword":"有机光电导体"}],"language":"zh","publisherId":"clkxygc200702007","title":"甲氧基取代三苯胺的合成及其性能研究","volume":"25","year":"2007"},{"abstractinfo":"三苯胺结构单元中,与氮原子相连的3个苯环具有较高的活性、结构多样性和易裁剪修饰的特性,因此通过在苯环适当的位置外接不同的识别基团,可得到一系列具有特定传感性能的三苯胺类荧光探针分子.系统总结了三苯胺衍生物在金属离子、阴离子和小分子检测中的研究进展,并对探针分子的设计思路、合成方法、应用范围等进行了详细的比较分析,同时对其未来的发展趋势进行了展望.","authors":[{"authorName":"杨杨","id":"82f20cc4-8742-40f5-bf83-6c5a1c4a2900","originalAuthorName":"杨杨"},{"authorName":"高超颖","id":"c74bb60c-bcc9-4879-823d-b140f374aa5e","originalAuthorName":"高超颖"},{"authorName":"许良","id":"08dc2b05-2388-4cbc-bc3f-305f461b7235","originalAuthorName":"许良"},{"authorName":"白锁柱","id":"2a84363e-5bbf-4ef7-bdd3-f07fa5db3372","originalAuthorName":"白锁柱"},{"authorName":"陈静","id":"1c70adcc-2818-43ef-91ac-9d84efd27a96","originalAuthorName":"陈静"}],"doi":"10.11896/j.issn.1005-023X.2014.15.011","fpage":"56","id":"934a2f25-a135-4c99-80a4-06d09cabf66b","issue":"15","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b564f6cc-61a7-4e09-afa3-952035f2258b","keyword":"荧光探针","originalKeyword":"荧光探针"},{"id":"675c35b1-1cd8-4803-b8d1-3843115cf3c4","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"91896fcb-8973-4f87-9186-90a62b6ff0bd","keyword":"选择性","originalKeyword":"选择性"},{"id":"35726a72-32c4-4946-9ae0-c000de5d1643","keyword":"灵敏度","originalKeyword":"灵敏度"},{"id":"ba74412d-1d7c-4155-ad4d-ebbd581d8eb0","keyword":"检测限","originalKeyword":"检测限"}],"language":"zh","publisherId":"cldb201415011","title":"三苯胺类荧光探针的研究进展","volume":"28","year":"2014"},{"abstractinfo":"通过钯盐催化的Suzuki偶联反应,将2,2′-二溴螺硅芴与三苯胺二硼酸共聚得三苯胺-螺硅芴聚合物. 其中2,2′-二溴螺硅芴是以邻二溴苯为原料,经2步偶联,硝化,还原,取代共5步反应制得;三苯胺二硼酸是以三苯胺为原料,经溴化,锂化,再与硼酸三甲酯反应制得. 单体和共聚物的结构经核磁共振氢谱、质谱、红外光谱测试技术确证. 凝胶渗透色谱法测得共聚物的分子量Mn=7 014,Mw=9 577,分散度1.36. 螺硅芴的引入提高了共聚物的溶解性和热稳定性. 共聚物的玻璃化转变温度(Tg)为158.22 ℃. 由循环伏安法测得的电化学性质表明,共聚物具有可逆的氧化过程和较低的离子势(-5.47 eV,与三苯胺接近).","authors":[{"authorName":"肖海波","id":"0a278f2a-dbe2-4b3e-8065-d985a85f8579","originalAuthorName":"肖海波"},{"authorName":"冷冰","id":"9964fc9a-4ab0-4216-a2ca-6a7f3aee2fc0","originalAuthorName":"冷冰"},{"authorName":"田禾","id":"9eca37a6-1963-4b22-81e1-09d5b3af3369","originalAuthorName":"田禾"}],"doi":"10.3969/j.issn.1000-0518.2006.02.006","fpage":"140","id":"2630651c-aa84-46db-bb1d-eccca2e804e2","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"7d224f3d-37a7-49c7-8a22-a490e9448fe1","keyword":"螺硅芴","originalKeyword":"螺硅芴"},{"id":"f46224e0-04d2-4187-91c5-5421b45481ff","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"9f7c45e7-b357-48e2-8d17-6c0f95301b40","keyword":"共聚物","originalKeyword":"共聚物"},{"id":"02843218-be00-410b-bd3b-43f5afd0b0aa","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200602006","title":"三苯胺-螺硅芴共聚物的合成","volume":"23","year":"2006"},{"abstractinfo":"以钯催化反应得到的4,4'-二甲氧基三苯胺为原料,用BBr3/CH2Cl2脱去甲基,得到中间产物4,4 '-二羟基三苯胺;再以吡咯烷酮为溶剂,在无水碳酸钾的催化下,通过4,4'-二羟基三苯胺与双(四氟苯基)砜的亲核反应,合成三苯胺基聚醚醚砜(TPA-PEES)发光材料.其结构通过核磁氢谱、红外谱图、凝胶渗透色谱和X射线衍射(XRD)等方法进行表征,表征结果与目标产物相吻合且聚合物为无定型态,并具有较高的相对分子质量((M)w=3.12×104).利用差示扫描量热(DSC)、热重分析(TG)、紫外-可见光分度计和荧光光谱仪对其性能进行测试,测试结果表明,该聚合物具有较高的玻璃化转变温度(Tg＞ 200℃),良好的热稳定性(Td＞ 400℃).另外,所制备的聚合物在二甲基甲酰胺(DMF)中的UV-vis最大吸收波长为305 nm,最大荧光发射波长为426 nm和523 nm.","authors":[{"authorName":"孙海燕","id":"4aabaa8c-97cc-487b-9bb1-23203850ffb2","originalAuthorName":"孙海燕"},{"authorName":"孙尚飞","id":"e2a8c773-405c-4894-93e5-e823f06d82dd","originalAuthorName":"孙尚飞"},{"authorName":"常冠军","id":"75a366dc-44ab-49e7-82a2-38f74ee09d15","originalAuthorName":"常冠军"},{"authorName":"林润雄","id":"2963c35a-7136-4aff-a895-bbc7d5dd35ea","originalAuthorName":"林润雄"},{"authorName":"张林","id":"452846bc-8956-4976-b389-59f3d4d7fdea","originalAuthorName":"张林"}],"doi":"","fpage":"9","id":"e0322631-3ccc-4909-97c2-eb6856c1df22","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"9703cd56-cde6-486e-b2f5-0d7cb257ef19","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"93ef1702-1674-4832-bab4-ac95a2f9610a","keyword":"亲核反应","originalKeyword":"亲核反应"},{"id":"f6b045bf-a9b3-4c68-8aaf-7514dc469f73","keyword":"聚醚醚砜","originalKeyword":"聚醚醚砜"},{"id":"ced22269-8c3a-4eb8-9256-868627878335","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gfzclkxygc201308003","title":"三苯胺基聚醚醚砜的合成与性能","volume":"29","year":"2013"},{"abstractinfo":"本实验采用Wittig方法制得了未封端和封端的超支化聚三苯胺-对苯乙烯撑型聚合物,对两种共轭聚合物进行了表征和性能测试.聚合物溶液和固体膜在紫外光照射下均发出较强的绿光.首次对这类聚合物在硝基芳烃化合物荧光猝灭能力进行了初步研究,结果表明:与未封端产物相比,封端后的超支化共轭聚合物在邻硝基甲苯(α-NT)的荧光猝灭效率上有明显提高,当α-NT浓度为21.5×10-3 mol/L时,荧光猝灭效率达到97%.这类共轭聚合物不仅合成操作较为简便,猝灭效率也较高,是一种很有潜力的硝基芳烃化合物荧光检测材料.","authors":[{"authorName":"任韦华","id":"1ad8b294-0b2e-47bc-84b2-d22690b2e0f0","originalAuthorName":"任韦华"},{"authorName":"刘峰","id":"abeaeefb-8a27-4d69-8def-a253163bf6b0","originalAuthorName":"刘峰"},{"authorName":"胡军","id":"6a88befa-8fe5-439d-98ef-0669ba2cc5b0","originalAuthorName":"胡军"},{"authorName":"刘洪来","id":"fb10eb35-a8e1-4935-a8d2-3fc7dd2aaaa2","originalAuthorName":"刘洪来"}],"doi":"","fpage":"318","id":"767219a5-d973-46a3-9aa7-db33b6d6c2ea","issue":"4","journal":{"abbrevTitle":"YXKXYGHX","coverImgSrc":"journal/img/cover/YXKXYGHX.jpg","id":"74","issnPpub":"1674-0475","publisherId":"YXKXYGHX","title":"影像科学与光化学 "},"keywords":[{"id":"c60ce71d-5043-4a99-970e-300c04d91b3e","keyword":"超支化聚合物","originalKeyword":"超支化聚合物"},{"id":"43cceddd-434d-411c-99e3-2f479e5d01bb","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"f3b3c198-39ed-4e92-842d-2a4a23bcb6e8","keyword":"荧光猝灭","originalKeyword":"荧光猝灭"},{"id":"1da78047-bf6d-460b-9344-c7bd74019b20","keyword":"硝基化合物","originalKeyword":"硝基化合物"}],"language":"zh","publisherId":"ggkxyghx200804009","title":"含三苯胺单元的超支化共轭聚合物的合成、表征及应用","volume":"26","year":"2008"},{"abstractinfo":"通过Suzuki缩聚法合成了9,9-二辛基芴与4-(N,N-二苯胺)-3',5'-二溴联苯的一系列无规和交替共聚物.研究了其紫外可见光吸收、光致发光和电致发光性能.实验结果表明:当间苯连接的三苯胺(TPA)衍生物含量大于5%时,共聚物溶液和固态薄膜的紫外吸收光谱和光致发射光谱发生了不同程度的蓝移,并且随着TPA衍生物含量的增加,光谱的蓝移程度加大.间苯含量为10%时,以该共聚物PFO-TPA10为发光层的电致发光器件,在电压7V至13V之间光谱具有很好的稳定性,未观察到聚芴excimer发射.6V下的色坐标为(0.17,0.06),半峰宽为27nm,器件的最大外量子效率为0.72%.","authors":[{"authorName":"马刚","id":"e9dd43ce-700e-4a18-836b-184256759832","originalAuthorName":"马刚"},{"authorName":"王磊","id":"d2e09ee7-1617-4c6a-b3da-5a800555e383","originalAuthorName":"王磊"},{"authorName":"孙明亮","id":"be63dd44-e768-4a2e-b3d9-02cdb06ebef5","originalAuthorName":"孙明亮"}],"doi":"10.3969/j.issn.1671-5381.2007.04.002","fpage":"6","id":"5619aed1-de1a-4aa6-914a-9ffea8e68242","issue":"4","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"ddd37a01-88e6-457f-86f6-738ac5838c6f","keyword":"Suzuki","originalKeyword":"Suzuki"},{"id":"3aa063d9-d902-4c32-9781-36c6549a0ae8","keyword":"聚芴","originalKeyword":"聚芴"},{"id":"99ea12d1-ce67-42e6-95bf-a35f6250f67c","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"2349cd6a-f76b-4ada-9c38-dd57b5718895","keyword":"excimer","originalKeyword":"excimer"}],"language":"zh","publisherId":"hccllhyyy200704002","title":"基于芴与三苯胺取代间苯共聚物的稳定蓝光材料的合成及性能研究","volume":"36","year":"2007"},{"abstractinfo":"分别以2-氰基-3-(4-(二苯胺)苯基)丙烯酸(TPA-1)、2-氰基-3-(5-(4-(二苯胺)苯基)-噻吩-2-基)丙烯酸(TPA-2)和2-氰基-3-(5'-(4-(二苯胺)苯乙烯基)-[2,2'-联噻吩]-5-基)丙烯酸(TPA-3)为配体合成了3个稀土配合物Nd(L)3·2H2O(L=TPA-1,TPA-2,TPA-3).采用元素分析、核磁共振氢谱(1H NMR)、红外光谱(IR)对配合物的组成进行了确认.通过紫外-可见吸收光谱和荧光光谱的测定,研究了配体共轭链长度对配合物吸光和发光性能的影响.结果表明:配体共轭链长度的增加有效增大了配合物的摩尔吸光系数,拓宽了配合物的吸光范围.配合物固体粉末近红外发光测试表明,Nd(TPA-1)3·2H2O和Nd(TPA-2) 3·2H2O在889,1063和1339nm处有较强的发射峰,分别归属于Nd(Ⅲ) 4F3/2→4I9/2,4F3/2→4I11/2和4 F3/2→4I13/2的特征跃迁.","authors":[{"authorName":"尹硕","id":"f2a86a26-1531-401a-ab14-7050d90bc0da","originalAuthorName":"尹硕"},{"authorName":"安忠维","id":"4c51ff2f-506f-44d7-bfb9-8dd9a87d8d37","originalAuthorName":"安忠维"},{"authorName":"陈新兵","id":"67844da2-96be-4251-84b7-3f57f7524400","originalAuthorName":"陈新兵"},{"authorName":"陈沛","id":"7ee60385-3837-4fcb-840a-721510878c61","originalAuthorName":"陈沛"}],"doi":"10.11785/S1000-4343.20140312","fpage":"338","id":"2a715b1b-eabe-41d6-82a5-083a8ce24a41","issue":"3","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"9b0bccd0-5fa8-4371-a637-005d0eaedd31","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"b6022a1c-e90e-4b76-a31f-d4e46ee72ff8","keyword":"稀土配合物","originalKeyword":"稀土配合物"},{"id":"753f3814-f8fe-4321-8a48-98c37ea908e0","keyword":"近红外发光","originalKeyword":"近红外发光"},{"id":"0a4b8bbe-fecb-40e7-9f4b-749c6dc354c2","keyword":"能量传递","originalKeyword":"能量传递"}],"language":"zh","publisherId":"zgxtxb201403012","title":"三苯胺氰基丙烯酸类钕配合物的制备及发光性能","volume":"32","year":"2014"},{"abstractinfo":"合成了一种新型的空穴传输材料三苯胺二苯乙烯衍生物DPAVBi,并通过一系列手段对其进行了表征.DPAVBi具有较好的无定形成膜性及较高的热稳定性.以DPAVBi为电荷传输层,TiOPc为光生层制备的双层光电导体,其光敏性在762nm处达到1.67cm2·μJ-1,是一种优良的空穴传输材料.","authors":[{"authorName":"徐清","id":"b09d0f2d-0bc7-4cfb-8bd2-aac726405e0f","originalAuthorName":"徐清"},{"authorName":"陈红征","id":"845e3238-9bcb-4f20-a5cb-dbb5d602e995","originalAuthorName":"陈红征"},{"authorName":"孙景志","id":"4d616278-94c9-473c-9f04-ddacf18de94d","originalAuthorName":"孙景志"},{"authorName":"汪茫","id":"6f08bdd3-27fe-49cc-96e3-aea2ebd73d58","originalAuthorName":"汪茫"}],"doi":"","fpage":"595","id":"c6f0e7d3-b6fa-4456-a1d0-f30ee1bfd0bd","issue":"5","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"60071625-9a48-415f-8dca-dbe6034e7930","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"0007ab46-bf65-4d26-8c0b-7987b2026adf","keyword":"二苯乙烯","originalKeyword":"二苯乙烯"},{"id":"f322e0e0-c0ee-47ff-afa2-9e4607bc1b5b","keyword":"空穴传输材料","originalKeyword":"空穴传输材料"},{"id":"d2107367-d2c7-4b4d-b398-f7019aad569c","keyword":"光导性能","originalKeyword":"光导性能"}],"language":"zh","publisherId":"gncl200405022","title":"一种新型含三苯胺二苯乙烯衍生物的合成及性能研究","volume":"35","year":"2004"},{"abstractinfo":"以三苯胺基和苯并噻二唑基为电子给、受体,合成得\"D-A-D\"型红光分子(简称TZ2),研究了其在介质中(THF和PVK中)单光子荧光(OPL)、双光子荧光(TPL)和电致发光(EL)性能.分别在Xe灯(455nm)和飞秒钛宝石激光器(820nm)泵浦下,TZ2在THF介质中的单光子、双光子荧光峰位分别在650和635nm处;在9V电压下,TZ2掺杂在PVK介质中(ITO和FLi/Al分别正、负电极)开始发光,峰位在620nm处.与OPL相比,TPL和EL在发光峰位和光谱半高宽(FWHH)均较为相近,说明激子复合发光(EL)与强光辐照发光(TPL)有更多的相似性.","authors":[{"authorName":"王晓宏","id":"ffe84e33-b3f2-49f5-9845-1e0ac9a174b0","originalAuthorName":"王晓宏"},{"authorName":"王筱梅","id":"68ea5a7e-5ce0-45e9-bb00-68811be3cf3b","originalAuthorName":"王筱梅"},{"authorName":"杨兴淮","id":"55274cdf-b840-42f0-bb6f-9e73a5a11d3c","originalAuthorName":"杨兴淮"},{"authorName":"李瑞","id":"e794cada-51f2-41ad-b1d2-8ecfc24f5624","originalAuthorName":"李瑞"},{"authorName":"罗建芳","id":"b5305387-46e1-477b-99b7-b14489dcbe35","originalAuthorName":"罗建芳"}],"doi":"","fpage":"1211","id":"1d16593e-c872-4396-a360-4b9a90aa653a","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"e7db86ad-8d77-4dc5-8a60-1786c6753a25","keyword":"双光子荧光","originalKeyword":"双光子荧光"},{"id":"adde0112-98e3-4fb4-a090-ffa01dae438d","keyword":"有机电致发光","originalKeyword":"有机电致发光"},{"id":"e07f035f-02c4-4f9e-afbe-a369e5730bad","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"be715909-677c-478c-a2c4-e1a7f073cfb0","keyword":"苯并噻二唑","originalKeyword":"苯并噻二唑"}],"language":"zh","publisherId":"gncl201007028","title":"苯并噻二唑/三苯胺衍生物合成与双光子荧光、电致发光性能研究","volume":"41","year":"2010"},{"abstractinfo":"通过Suzuki偶联聚合反应,合成了一类新型低带隙交替共聚物-三苯胺-alt-4,7-二(3-己基噻吩)-[2,1,3]苯并噻二唑 (PTPADHDBT).聚合物数均分子量Mn=9420,分散系数Mw/Mn=3.2.PTPADHDBT溶液的两个吸收峰分别位于355nm与514nm, 光学带隙为2.02eV.而聚合物薄膜的吸收峰分别位于356nm与523nm,与溶液中的吸收峰相比红移了9nm;聚合物溶液和薄膜的荧光发射峰分别为677nm和683nm,与溶液的发射峰相比,薄膜的荧光发射峰红移了6nm.","authors":[{"authorName":"张斌","id":"88707196-3657-47f7-a07d-dca39bdc6f89","originalAuthorName":"张斌"},{"authorName":"刘杰","id":"6b6bd1e5-e232-41d4-934a-473e16dde0f7","originalAuthorName":"刘杰"},{"authorName":"杨伟","id":"e58c5d3d-4176-462a-a425-a403d3b3c76c","originalAuthorName":"杨伟"}],"doi":"10.3969/j.issn.1671-5381.2008.02.006","fpage":"20","id":"3509138a-939b-4750-acb7-61037a79f297","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"e08b8bf9-e20e-40da-956d-2637f93c26c0","keyword":"三苯胺","originalKeyword":"三苯胺"},{"id":"4f4ae5a9-035f-469a-98dc-a92345109bb5","keyword":"噻吩衍生物","originalKeyword":"噻吩衍生物"},{"id":"3d20f610-50dd-4f0f-940f-1bc28460ef48","keyword":"共聚物","originalKeyword":"共聚物"},{"id":"e44c0d70-84bf-40a7-a404-d0b55ea3497f","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"hccllhyyy200802006","title":"三苯胺-alt-4,7-二(3-己基噻吩)-[2,1,3]苯并噻二唑共聚物的合成及表征","volume":"37","year":"2008"}],"totalpage":2363,"totalrecord":23628}