工程热物理学报 , 2009, 30(8): 1357-1359.
组合式多壳程螺旋折流板管壳式换热器数值模拟研究
陈贵冬 1, , 陈秋炀 2, , 曾敏 3, , 王秋旺 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":3,"startPagecode":1},"records":[{"abstractinfo":"通过表面改性引入活性生物分子可以用来增强材料表面的生物相容性。采用静电自组装技术将明胶和聚乙烯亚胺引入羟基磷灰石/聚酰胺6（HA/PA6）材料表面,最终获得大分子修饰的复合材料。利用水接触角测量（WCA）、X射线光电子能谱（XPS）和原子力显微镜（AFM）测试手段对表面改性前后HA/PA6膜的表面化学、亲水性和表面形貌进行表征。并研究了其对细胞活性的影响。结果表明,改性后膜表面的亲水性增强,粗糙度增大。体外细胞实验表明,明胶涂层后的HA/PA6表面细胞更利粘附、铺展和生长。该固定方法模拟细胞外基质组成制备出的生物活性膜能进一步满足生物医学工程需求。","authors":[{"authorName":"沈娟","id":"a4106891-4a58-4063-be2f-95fe87193b38","originalAuthorName":"沈娟"},{"authorName":"左奕","id":"8a7b2dad-8bf4-4005-b2f4-39375122f53a","originalAuthorName":"左奕"},{"authorName":"李玉宝","id":"6e48e6d6-1237-41a8-a765-7e6a0f91b5ec","originalAuthorName":"李玉宝"},{"authorName":"邹琴","id":"63ae128a-25dd-4c24-976a-ecf4606d8416","originalAuthorName":"邹琴"},{"authorName":"程琳","id":"91acf463-3554-49cf-9044-d2965ba187f0","originalAuthorName":"程琳"},{"authorName":"龚梅","id":"467c78f5-bd48-4ebf-93d0-d6d151ef95e6","originalAuthorName":"龚梅"},{"authorName":"黄棣","id":"d5790aec-b7ec-4659-92fc-7f1d6ca3cbed","originalAuthorName":"黄棣"}],"doi":"","fpage":"1378","id":"81b0c034-bc7a-4c32-9fba-33eca184f727","issue":"11","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"aa55b69f-ab77-4e36-9c68-bfc304c28428","keyword":"羟基磷灰石/聚酰胺6","originalKeyword":"羟基磷灰石/聚酰胺6"},{"id":"4099d930-7f2d-43b0-80c1-a9ff1a6c3ee7","keyword":"表面修饰","originalKeyword":"表面修饰"},{"id":"e14f3ee1-d66c-4176-985b-19c94f797687","keyword":"自组装","originalKeyword":"自组装"},{"id":"490679d1-19f9-43d7-b183-7375580a0850","keyword":"细胞相容性","originalKeyword":"细胞相容性"}],"language":"zh","publisherId":"gncl201211005","title":"静电自组装表面修饰HA/PA6膜：表征及其细胞相容性研究","volume":"43","year":"2012"},{"abstractinfo":"生物材料可通过表面改性引入活性基团来增强其生物相容性.采用紫外辐照方法,以亚铁离子辅助引发接枝聚合,将羧基引入聚酰胺66(PA66)膜表面,再用水溶性碳化二亚胺(WSC)作为缩合剂,进一步将明胶固定在聚酰胺膜表面,最终获得大分子修饰的聚酰胺材料.利用衰减全反射-傅里叶红外光谱(ATR-FTIR)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和水接触角测量(WCA)等测试手段对PA66膜和表面改性PA66膜进行了表征.结果表明,在40℃条件下,光氧化的最佳时间为60min.接枝聚合后,膜的亲水性增强,水接触角由纯聚酰胺的67.5°变为固定明胶分子后的60°,并且膜表面的粗糙度增加.表面改性PA66膜可促进细胞活性,适用于组织工程中.","authors":[{"authorName":"沈娟","id":"7b4a618b-bd39-4d7c-af35-4015ebef6d1b","originalAuthorName":"沈娟"},{"authorName":"左奕","id":"48bd76a8-cb9d-4a19-bb26-53249d135fb1","originalAuthorName":"左奕"},{"authorName":"张利","id":"35e90a5c-9530-470a-895c-af48d15e61ac","originalAuthorName":"张利"},{"authorName":"邹琴","id":"f8a9fb95-8c14-414e-9d5a-98004c38dbd5","originalAuthorName":"邹琴"},{"authorName":"程琳","id":"09bea403-f138-46bb-8d60-0bd77f3c668c","originalAuthorName":"程琳"},{"authorName":"黄棣","id":"515bb9bb-bc4d-4c40-9d32-ea7132641324","originalAuthorName":"黄棣"},{"authorName":"李玉宝","id":"3619cf46-5b0c-4eff-9ae8-69cdea469438","originalAuthorName":"李玉宝"}],"doi":"","fpage":"1900","id":"ce2e8dc8-c567-4a12-af85-9d721df741c0","issue":"11","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"61e35199-7fd2-4ffe-b554-5c5c528efc2e","keyword":"接枝改性","originalKeyword":"接枝改性"},{"id":"e8e98fa8-d659-450d-9598-54edaee9316d","keyword":"聚酰胺66","originalKeyword":"聚酰胺66"},{"id":"32be18b9-c0ad-4b54-9fa5-daffb759616f","keyword":"固定化","originalKeyword":"固定化"},{"id":"13b15d9d-5690-4663-8fc5-53f9dd2401ff","keyword":"亲水性","originalKeyword":"亲水性"},{"id":"aa172842-7ebe-490d-88b1-a68bf6a458a2","keyword":"粗糙度","originalKeyword":"粗糙度"}],"language":"zh","publisherId":"gncl200911039","title":"聚酰胺66膜表面明胶固定化研究","volume":"40","year":"2009"},{"abstractinfo":"以聚乙烯醇和间硝基苯甲醛为原料,对甲苯磺酸为催化剂,合成了聚乙烯醇缩间硝基苯甲醛(PVMNB),探讨了反应物物料比、反应温度、反应时间对PVMNB缩醛度的影响,获得适宜的工艺条件为:PVA(-OH)和间硝基苯甲醛的物质的量比为2:1,反应温度100℃,反应时间9 h,此时PVMNB为86%.通过衰减全反射-傅里叶红外光谱、紫外可见光谱、核磁共振氢谱等测试手段对PVMNB结构进行了表征,利用差示扫描量热仪(DSC)测定了PVMNB的玻璃化转变温度(Tg),采用差热分析(DTA)和热重分析(TGA)对PVMNB的热稳定性进行了研究.DSC结果表明,PVMNB的玻璃化转变温度为131℃,DTA和TGA结果表明,PVMNB热稳定性良好,在空气中250℃未见分解.","authors":[{"authorName":"金波","id":"c91c5512-fe7e-451b-9f90-a84971bcaffe","originalAuthorName":"金波"},{"authorName":"董海山","id":"3d645c7b-f3d4-4751-b61e-074ef641fa42","originalAuthorName":"董海山"},{"authorName":"彭汝芳","id":"08b501f4-0f29-425a-8e45-59b35f3bf027","originalAuthorName":"彭汝芳"},{"authorName":"沈娟","id":"da32ceb9-6b35-428f-9f4e-ca82305c68a7","originalAuthorName":"沈娟"},{"authorName":"楚士晋","id":"8f7e7268-7d46-4eef-af24-81b33fa8b56a","originalAuthorName":"楚士晋"}],"doi":"","fpage":"4","id":"808ef87e-433e-48d8-be0b-91fa868ae6c6","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"cd9cf341-0e17-409f-92ce-1463ac159c7a","keyword":"聚乙烯醇","originalKeyword":"聚乙烯醇"},{"id":"d25118bf-4531-47d8-b2bd-5c4091ed7cd7","keyword":"聚乙烯醇缩间硝基苯甲醛","originalKeyword":"聚乙烯醇缩间硝基苯甲醛"},{"id":"3536b36e-bcd1-43a9-b740-52db5d652052","keyword":"结构表征","originalKeyword":"结构表征"},{"id":"c5bb5861-1901-492b-8e6f-47be0e69d0bb","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gfzclkxygc201106002","title":"聚乙烯醇缩间硝基苯甲醛的合成与热稳定性","volume":"27","year":"2011"},{"abstractinfo":"以聚乙烯醇（PVA）和苯甲醛为原料,二甲基亚砜为溶剂,对甲基苯磺酸为催化剂,采用均相工艺合成得到聚乙烯醇缩苯甲醛（PVB）。通过衰减全反射-傅里叶红外光谱（ATR-FT-IR）、紫外-可见光谱（UV-Vis）、核磁共振氢谱（1 H NMR）、核磁共振碳谱（13C NMR）等测试手段对聚乙烯醇缩苯甲醛结构进行了表征。利用差式扫描量热仪（DSC）测定了聚乙烯醇缩苯甲醛的玻璃化温度（Tg）。采用差热分析（DTA）和热重分析（TGA）对聚乙烯醇缩苯甲醛热稳定性进行了研究。DSC结果表明聚乙烯醇缩苯甲醛的玻璃化温度为106.0℃。DTA和TGA结果表明聚乙烯醇缩苯甲醛热稳定性良好,在空气中150℃仍未见分解。","authors":[{"authorName":"金波","id":"2cb8d76d-3caf-425c-a648-07225ce66412","originalAuthorName":"金波"},{"authorName":"彭汝芳","id":"e11bc140-fd68-4fef-ab48-f1a60b7f1edb","originalAuthorName":"彭汝芳"},{"authorName":"沈娟","id":"fc3025e2-8c9f-4d63-a3c2-9fd07d0fc20f","originalAuthorName":"沈娟"},{"authorName":"谭碧生","id":"bd663cec-c4be-429d-9404-467927c8e052","originalAuthorName":"谭碧生"},{"authorName":"楚士晋","id":"f929b689-f43a-4df7-82f9-6cc0211b7306","originalAuthorName":"楚士晋"},{"authorName":"董海山","id":"99f0857a-0c78-4f2c-a33c-2aa33c4b78f6","originalAuthorName":"董海山"}],"doi":"","fpage":"1269","id":"85f55bf9-2092-4c53-bc35-beb42d741b61","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d5fc0b40-25cd-4045-8b79-5da18ba344b4","keyword":"聚乙烯醇","originalKeyword":"聚乙烯醇"},{"id":"f1974ed2-4caa-45a4-927a-c071517455d9","keyword":"聚乙烯醇苯甲醛","originalKeyword":"聚乙烯醇苯甲醛"},{"id":"f3ae411a-29bd-4067-8ba7-da024a9b250e","keyword":"合成","originalKeyword":"合成"},{"id":"68baf82e-c11f-4beb-979b-9fdab92d5ff1","keyword":"结构表征","originalKeyword":"结构表征"},{"id":"c684fc8f-588f-46c2-81d9-d88112ad20e0","keyword":"热稳定性","originalKeyword":"热稳定性"}],"language":"zh","publisherId":"gncl201107029","title":"聚乙烯醇缩苯甲醛的合成与热稳定性研究","volume":"42","year":"2011"},{"abstractinfo":"以多氨羧酸为配体,在水溶液中合成了两个同时含Bi3+和Eu3+两种金属的晶态配合物BiEu(edta)(NO3)2·6.5H2O和非晶态配合物BiEu(dtpa)(NO3)·4(H2O).采用元素分析仪、红外光谱仪、X射线粉末衍射仪等手段对产物进行表征.采用热分析仪对产物的热稳定性进行了研究.室温下采用紫外可见光度计和荧光光谱仪对固态产物的光学性质进行测试,结果显示产物既发Eu3+的线状特征荧光,又发Bi3+的带状荧光.","authors":[{"authorName":"邓洪权","id":"858da6f2-19c2-42fe-be73-8185b860ea97","originalAuthorName":"邓洪权"},{"authorName":"蒋琪英","id":"b8e14e4a-da07-43f8-bbd0-0a862f4b9657","originalAuthorName":"蒋琪英"},{"authorName":"胡亚敏","id":"22cce97a-3795-4e57-8764-4415c6e822e0","originalAuthorName":"胡亚敏"},{"authorName":"沈娟","id":"7dd654e9-a552-4916-97df-d4e6d7e5f589","originalAuthorName":"沈娟"},{"authorName":"钟国清","id":"af12a4c4-d855-42b6-b490-dd54935337c7","originalAuthorName":"钟国清"}],"doi":"","fpage":"655","id":"fef24d3c-a428-4adb-a7ec-0ce86e060f2a","issue":"6","journal":{"abbrevTitle":"ZGXTXB","coverImgSrc":"journal/img/cover/ZGXTXB.jpg","id":"86","issnPpub":"1000-4343","publisherId":"ZGXTXB","title":"中国稀土学报"},"keywords":[{"id":"269bc909-56c1-438f-81e1-4e88cdae9fd7","keyword":"双金属配合物","originalKeyword":"双金属配合物"},{"id":"41f4d204-59a9-429b-8e7f-4bd95e9e5bda","keyword":"Eu(Ⅲ)","originalKeyword":"Eu(Ⅲ)"},{"id":"0b48014a-5383-4c0c-93c0-3e60fdc4c18d","keyword":"Bi(Ⅲ)","originalKeyword":"Bi(Ⅲ)"},{"id":"da039798-01ac-4abb-9a0e-0a35d0c14b62","keyword":"合成","originalKeyword":"合成"},{"id":"d5e4ba4d-c174-4a86-b126-b7cd2ff8990b","keyword":"光谱性质","originalKeyword":"光谱性质"}],"language":"zh","publisherId":"zgxtxb201106002","title":"异金属配合物的合成、表征与光谱性质","volume":"29","year":"2011"},{"abstractinfo":"采用NH4Bi(edta)·2H2O和硝酸镨为原料,二者按摩尔比为1∶1在水溶液中合成了含铋(Ⅲ)和镨(Ⅲ)的双金属配合物PrBi(edta)(NO3)2·6.5H2O,产率为45%,该配合物在空气中稳定,不吸湿.用元素分析、FT-IR、XRD和TG-DSC测试技术对产物进行了组成和结构表征.结果表明,配合物属于单斜晶系,相应晶胞参数为a=0.988 5 nm,b=2.347 2 nm,c=1.375 6 nm,β=93.375°.通过红外光谱和热分析共同研究了热分解过程.配合物在热分解时,经过脱水、配体热分解、金属盐分解,最后在600℃失重恒定,残余物为BiPrO3.","authors":[{"authorName":"蒋琪英","id":"c99eea63-8c50-4ee5-a3c6-81e71f344a7b","originalAuthorName":"蒋琪英"},{"authorName":"DENG Hong-Quan","id":"6293c3f4-1ef0-4fd9-8e17-4df363288169","originalAuthorName":"DENG Hong-Quan"},{"authorName":"沈娟","id":"35da70e3-24c0-4a69-8248-431e17e1dbeb","originalAuthorName":"沈娟"},{"authorName":"ZHONG Guo-Qing","id":"75b648d0-5047-44b4-9ee4-49caf363dd68","originalAuthorName":"ZHONG Guo-Qing"}],"doi":"10.3969/j.issn.1000-0518.2008.08.025","fpage":"983","id":"42e24afd-9666-4a81-a396-bb9ef36731cc","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"3e8a50cc-59c1-4f70-9cbf-f8df461ab5d8","keyword":"双金属配合物","originalKeyword":"双金属配合物"},{"id":"d035df5d-45e2-4b81-b515-ae60b7e0c3c5","keyword":"铋(Ⅲ)","originalKeyword":"铋(Ⅲ)"},{"id":"e59a1538-ac31-47c3-8d00-39c10b0ead08","keyword":"镨(Ⅲ)","originalKeyword":"镨(Ⅲ)"},{"id":"35c7a86c-938a-40b8-b4dc-51f6caa9b8be","keyword":"热分解","originalKeyword":"热分解"}],"language":"zh","publisherId":"yyhx200808025","title":"双金属配合物PrBi(edta)(NO3)2·6.5H2O的合成、表征与热分解","volume":"25","year":"2008"},{"abstractinfo":"以碳酸钙为模板和钙源，与磷酸氢二铵通过水热反应，制备出尺寸均匀、形态规则的空心羟基磷灰石微球。采用X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)、透射电镜(TEM)测试制备的样品，结果显示，制备的空心羟基磷灰石微球具有与碳酸钙微球模板相似的形貌，空心，尺寸均匀且形貌规则。并通过改变水热反应时间探索了羟基磷灰石微球的形成机理。此羟基磷灰石空心微球在生物医学领域具有较大的应用前景。","authors":[{"authorName":"陈继伟","id":"86e7073a-22b2-44ff-ae0a-302eb9de6d45","originalAuthorName":"陈继伟"},{"authorName":"沈娟","id":"38790c12-6033-48b4-a701-35650e2b4cdf","originalAuthorName":"沈娟"},{"authorName":"胡文远","id":"80341a8e-aec1-41f6-901d-53f8853ea69b","originalAuthorName":"胡文远"},{"authorName":"齐永成","id":"ea7abf89-7e04-4690-a2da-b537f7d3a183","originalAuthorName":"齐永成"}],"doi":"10.3969/j.issn.1001-9731.2016.04.034","fpage":"4169","id":"62dc6fae-837c-46f1-ac60-5e1f080dafcf","issue":"4","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"552ddca9-b90f-4dcb-bf1d-320edfab30ba","keyword":"羟基磷灰石","originalKeyword":"羟基磷灰石"},{"id":"3cbc8369-2cc2-4a02-be2a-7eafbc644450","keyword":"空心微球","originalKeyword":"空心微球"},{"id":"27bc2447-7940-4957-815a-af28bf46cb6e","keyword":"碳酸钙","originalKeyword":"碳酸钙"},{"id":"af3d3ad1-b797-4cf3-b727-9bc2188a3dac","keyword":"水热法","originalKeyword":"水热法"},{"id":"48a8d016-bcbd-408f-9fa9-5932ffddcb26","keyword":"形成机理","originalKeyword":"形成机理"}],"language":"zh","publisherId":"gncl201604034","title":"以碳酸钙为模板制备空心羟基磷灰石微球及其表征","volume":"47","year":"2016"},{"abstractinfo":"形状记忆合金因其独特的应力自适应特性,在多功能和机敏复合材料领域被广泛应用.对TiNi形状记忆合金增强金属基复合材料的研究进展进行了概括总结,着重介绍了形状记忆合金增强金属基复合材料的制备方法、增强机理、性能及其约束态下记忆合金相变等方面的研究现状,并对其发展前景进行了展望.","authors":[{"authorName":"杨素媛","id":"4fa9d1fc-db41-44f2-8bab-021527cbb3eb","originalAuthorName":"杨素媛"},{"authorName":"杨胜男","id":"934cc2a8-0fb8-4964-9008-bfd3cf1fd187","originalAuthorName":"杨胜男"},{"authorName":"沈娟","id":"e172ced8-0b7c-49bc-95fc-7ca53e4898b8","originalAuthorName":"沈娟"},{"authorName":"郭丹","id":"747765c9-3e7d-4222-bee9-8e6d6057a1d7","originalAuthorName":"郭丹"}],"doi":"10.13228/j.boyuan.issn1005-8192.2016026","fpage":"1","id":"a0c39a69-a14a-4e7f-b6d2-1d8bf3f10435","issue":"4","journal":{"abbrevTitle":"JSGNCL","coverImgSrc":"journal/img/cover/JSGNCL.jpg","id":"46","issnPpub":"1005-8192","publisherId":"JSGNCL","title":"金属功能材料"},"keywords":[{"id":"10655730-4ad2-4eec-8513-930dee33e3f9","keyword":"TiNi形状记忆合金","originalKeyword":"TiNi形状记忆合金"},{"id":"d0cbe57c-3b74-402b-a844-d834c3c5440a","keyword":"复合材料","originalKeyword":"复合材料"},{"id":"42c8df35-fa55-4d7a-a67d-1665d3f268bb","keyword":"制备方法","originalKeyword":"制备方法"},{"id":"6e5c60e0-e815-4e58-92ab-b8947831b084","keyword":"研究进展","originalKeyword":"研究进展"}],"language":"zh","publisherId":"jsgncl201604001","title":"形状记忆合金增强金属基复合材料的研究进展","volume":"23","year":"2016"},{"abstractinfo":"随着有机电致发光器件(OELD)的发展,有机电子传输材料研究逐渐引起人们广泛兴趣.制备了3种不同长共轭结构的新型2,5-二芳基-1,3,4-噁二唑类衍生物(4a～4c),以FTIR、1HNMR、TGA、C-V、UV-vis、FL对化合物的结构与性能进行了表征和研究.结果显示,噁二唑类衍生物分子结构对其热稳定性和分子的能级结构明显产生影响,分子中π电子共轭程度提高可有效地提高电子亲和势,分子极性和分子共轭度提高均有利于提高噁二唑衍生物(4c)的热稳定性.","authors":[{"authorName":"汪新","id":"22d30f1e-21c8-40bc-a732-0d2f694c7866","originalAuthorName":"汪新"},{"authorName":"沈娟","id":"ca0b7a10-9a48-4f89-b44e-bdb509d55a64","originalAuthorName":"沈娟"},{"authorName":"徐洪耀","id":"72a34909-e203-408c-8e03-2ced951043fa","originalAuthorName":"徐洪耀"}],"doi":"","fpage":"1555","id":"3c696ac4-019c-4d34-bd0c-c247d311b974","issue":"9","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"739b1d11-2480-483a-a225-fe42b8b2f7b7","keyword":"噁二唑衍生物","originalKeyword":"噁二唑衍生物"},{"id":"6a95f186-2799-4fe8-ba96-b75698252650","keyword":"合成","originalKeyword":"合成"},{"id":"a79dff68-2daf-4104-b42d-d7bcdbdd7280","keyword":"热性能","originalKeyword":"热性能"},{"id":"a50b67d4-6d61-48f3-a0a0-1f2b543ec9a8","keyword":"电子亲和能","originalKeyword":"电子亲和能"}],"language":"zh","publisherId":"gncl200809041","title":"新型噁二唑电子传输材料的分子设计合成、结构与性能关系研究","volume":"39","year":"2008"},{"abstractinfo":"沈家垭金矿床位于雪峰弧形隆起带转折部位,含金蚀变带赋存于板溪群马底驿组中上部粉砂质板岩中,受层间破碎带控制,官庄-黄土铺逆掩断层、陈家-香草湾逆掩断层呈NE45°～80°走向贯穿矿区中北部,控制了金矿(化)体的产出,已发现了3条矿脉,延伸长,厚度大,品位高,矿石矿物主要是自然金.次有少量辉锑矿、毒砂、黄铁矿等.脉石矿物主要是石英、绢云母、绿泥石等.围岩蚀变发育,类型多样,其中绢云母化、黄铁矿化、硅化是重要的找矿标志.","authors":[{"authorName":"谢新泉","id":"279b9c6f-e128-4ca3-bc9f-b68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