<正> 利用电化学氢渗透曲线来计算室温附近氢在金属中的扩散系数是一种广为应用的方法。从理论上讲,在氢渗透曲线上的任何一点上都可以计算出氢在金属晶格中的扩散系数。但是从实际获得的氢渗透曲线各点算得的氢扩散系数并不一致。这是因为在金属中,一般都不可避免地存在一些氢的陷阱,如位错、晶界、杂质原子等,它们会不同程度地阻碍氢在金属晶格中的扩散过程。而理论推导本身并没有考虑到氢陷阱存在的影响,因此实际得
An improved calculating method has been developed to determine the diffusivityof hydrogen in lattice of metals through electrochemical permeation experiment. By employingthis method the hydrogen trapping effect can be eliminated completely and the diffusivity canbe measured more accurately. The permiation experiment of Armoc Fe was performed and thediffusivity of hydrogen in the lattice of α-Fe between 290K and 350K has been given asD_0=5.12×10~(-8)exp(-4320/RT) (m~2/s)
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| [1] | |
| [2] | |
| [3] | |
| [4] | |
| [5] | |
| [6] | |
| [7] | |
| [8] | |
| [9] | |
| [10] | |
| [11] |
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