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  4. 锂离子电池硅/碳复合负极材料的研究进展

材料导报, 2009, 23(19): 104-108.

锂离子电池硅/碳复合负极材料的研究进展

樊星 1, , 郑永平 2, , 沈万慈 3,

1.清华大学材料科学与工程系先进材料教育部重点实验室,北京100084

2.清华大学材料科学与工程系先进材料教育部重点实验室,北京100084

3.清华大学材料科学与工程系先进材料教育部重点实验室,北京100084

基金项目:   国家科技支撑计划(2008BAE60B00)  

关键词： 锂离子电池 , 负极材料 , 硅-碳复合材料 , 缓冲基体

Research Progress in Si/C Composites as Anodes for Lithium-ion Batteries

负极理论容量最大的硅在充放电过程中,体积过度膨胀粉化导致容量衰减快,成为其作为商用负极材料的最大障碍.碳材料不仅具有一定的电化学活性,结构也较稳定,可以作为硅电极的"缓冲基体";具有高容量和优良循环性能的硅-碳复合负极材料已经成为该领域的研究热点.按照碳材料的分类,评述了Si/C复合电极材料,并初步展望了该领域的研究方向.

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