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用稳态极化法、阳极动电位快速扫描法和交流阻抗法研究了 N80#钢在含H2SO3酸性溶液中的腐蚀行为.结果表明:酸性溶液中H2SO3的加入, 一方面因增大了溶液的酸度而促进N80#钢的腐蚀,另一方面因一种新的吸附性中间产物的 生成而加快腐蚀.当溶液中没有H2SO3时,N80#钢腐蚀反应阳极过程生成的吸附性中间 产物是Fe(OH)ad,而加入H2SO3后,则生成另一种吸附性中间产物Fe(HSO3 )ad.

The behavior of N80# steel in acid solution at va rious pH values and with various CH2SO3 was studied by means of stable polarization,anodic linear potential sweep and a.c.impedance.The result showed that the addition of H2SO3 could increase the corrosion rate of N80# steel for two reasons;one is the decrease of solution's pH value,the other is the pro duction of an new mid adsorptive matter.The adsorption intermediate product was F e(OH)ad in process of the corrosion reaction of N80# steel in HAc-NaAc wit hout H2SO3.When H2SO3 was added to the acid solution,the adsorptive inte rmediate product was Fe(HSO3)ad.

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