分别采用在Cu基体添加0.1 wt%的Ti元素形成Cu-Ti合金和在Diamond颗粒表面镀钛(DiamondTi)的方法,制备了含Diamond体积分数为60%的Diamond/Cu-Ti复合材料和DiamondTi/Cu复合材料.对比分析了Ti元素对复合材料微观组织、界面结合及性能的影响规律.结果表明:添加0.1 wt%Ti元素能改善Diamond与Cu的界面结合,在界面处观察到明显的碳化物反应层;且以Cu-Ti合金的方式添加Ti元素改善界面的效果优于在Diamond颗粒表面镀Ti的方式.所制备的Diamond/Cu-Ti复合材料的热导率为621 W(m·K)-1,而DiamondTi/Cu复合材料的热导率仅为403.5 W(m·K)-1,但均高于未添加Ti制备的Diamond/Cu复合材料.
参考文献
[1] | 黄强,顾明元.电子封装用金属基复合材料的研究现状[J].电子与封装,2003,3(2):22-25.Huang Qiang,Gu Mingyuan.Status and prospects of metal matrix composites for electronic packaging[J].Electronics & Packaging,2003,3(2):22-25. |
[2] | 童震松,沈卓身.金属封装材料的现状及发展[J].电子与封装,2005,5(3):6-15.Tong Zhensong,Shen Zhuoshen.Status and development of materials for metal packaging[J].Electronics & Packaging,2005,5(3):6-15. |
[3] | Carl Zweben.Advances in composite materials for thermal management in electronic packaging[J].JOM,1998(6):47-51. |
[4] | Carl Zweben.Thermal materials solve power electronics challenges[J].Power Electronic Technology,2006(2):40-47. |
[5] | Carl Zweben.Electronic packaging:Heat sink materials[M]//Buschow K.H.J.Encyclopedia of Materials:Science and Technology.Oxford:Elsevier,Science,2001:2676-2683. |
[6] | Wildner H,Knippscheer S.Manufacturing and applications of diamond-composites for thermal management(Plansee 2006),EMPA,November 10,2006. |
[7] | Kerns J A,Colella N J,Makoiecki K.Dymalloy:A composite substrate for high power density electronic components[C]//Proceeding of 1 995 International Symposium on Microelectronics.Washington DC:USDOE.1995:66-72. |
[8] | SEI Thech Rev.Diamond-Copper composite materials forHigh Performance Heat Sink(DMCH).2003,56:76. |
[9] | Yasuyukii Agari,Kanryu Inoue.Thermal conductivity of copper composites dispersed with diamond particles prepared by spark plasma sintering[C]//The 27th Japan Symposium on Thermophysical Properties.Japan,2006:328-330. |
[10] | Weber L,Tavangar R.On the influence of active element content on the thermal conductivity and thermal expansion of Cu-X(X=Cr,B)diamond composites[J].Scripta Materialia,2007,57(11):988-991. |
[11] | Grujicic M,Zhao C L,Dusel E C.The effect of thermal contact resistance on heat management in the electronic packaging[J].Applied Surface Science,2005,246:290-302. |
[12] | Flaquer J,Rios A,Martin M A.Effect of diamond shapes and associated thermal boundary resistance on thermal conductivity of diamond-base composites[J].Computational Materials Scfence,2007,41:156-163. |
[13] | Kizikov (E),Lavrinenko I A.Investigation of Cu-Sn-Ti alloys used for bonding diamond abrasive tools[J].Nonferrous Metals and Alloys,1975(17):61-65. |
[14] | Li Wenchung,Liang Cheng,Lin Shuntian.Epitaxial interface of nanocrystalline TiC formed between Cu-10Sn-15Ti alloy and diamond[J].Diamond and Related Materials,2002,11(7):1366-1373. |
[15] | 董古民,KonaHb B C.金刚石-铜薄膜复合材料[J].功能材料,1999,30(4):40-41.Dong Zhanmin,Konaab B C.Diamond-Copper composite film[J].Journal of Functional Materials,1999,30(4):40-41. |
[16] | 马丙现,姚宁,杨仕娥,高关胤,张兵临.铜基体上CVD金刚石厚膜的制备[J].无机材料学报,2004,19(4):7-9.Ma Bingxian,Yao Ning,Yang Shie,Gao Guanyin,Zhang Binglin.Preparation of thick CVD diamond film on copper substrate[J].Journal of Inorganic Materials,2004,19(4):7-9 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%