采用脉冲激光沉积技术制备出了Ag掺杂的ZnO薄膜.研究了Ag含量、衬底温度及氧压对ZnO结构和光学性能的影响.结果表明:Ag以替位形式存在于ZnO晶格中,Ag掺杂浓度较低时,样品具有高度c轴择优取向.衬底温度越高,薄膜的结晶质量越好,光学带隙越接近纯ZnO的带隙,而其紫外荧光峰在衬底温度为300 ℃时最强.氧压为10 Pa时,薄膜的结晶质量最好,紫外峰最强,其带隙则随氧压的增大呈先变窄后加宽的趋势.
参考文献
| [1] | Camelia Matei Ghimbeu;Joop Schoonman;Martine Lumbreras;Maryam Siadat .Electrostatic spray deposited zinc oxide films for gas sensor applications[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(18):7483-7489. |
| [2] | 孙林林,刘宏玉,程文娟,马学鸣,石旺舟.在Si（100）上以AlN作过渡层低温外延生长ZnO薄膜[J].人工晶体学报,2005(06):1132-1136. |
| [3] | Fabrication Of Mg-doped Zno Thin Films By Laser Ablation Of Zn:mg Target[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(10):p.5264. |
| [4] | T. L. Yang;D. H. Zhang;J. Ma;H. L. Ma;Y. Chen .Transparent conducting ZnO: Al films deposited on organic substrates deposited by r.f. magnetron-sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1/2):60-62. |
| [5] | Buyanova, IA;Wang, XJ;Wang, WM;Tu, CW;Chen, WM .Effects of Ga doping on optical and structural properties of ZnO epilayers[J].Superlattices and microstructures,2009(4/5):413-420. |
| [6] | K.J. Chen;F.Y. Hung;S.J. Chang;Z.S. Hu .Microstructures, Optical And Electrical Properties Of In-doped Zno Thin Films Prepared By Sol-gel Method[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(12):6308-6312. |
| [7] | Fan J;Freer R .The Roles Played by Ag and Al Dopants in Controlling the Electrical Properties of ZnO Varistors[J].Appl.Phys,1995,77(09):4795-4800. |
| [8] | Gouvea C A K;Wypych F;Moraes S G .Semiconductor-assisted Photodegradation of Lignin,Dye,and Kraft Effiuent by Ag-doped ZnO[J].Chemosphere,2000,40(04):427-432. |
| [9] | Zhang Y;Zhang Z Y;Fu Z X .Effects of Ag Doping on the Photoluminescence of Films Grown on Si Substrates[J].Journal of Physical Chemistry B,2005,109(41):19200-19203. |
| [10] | 孙汪典,王英连.ZnO薄膜的掺Ag改性及其光催化降解苯酚性能研究[J].真空科学与技术学报,2007(04):309-311. |
| [11] | Charton C.;Fahland M. .Optical properties of thin Ag films deposited by magnetron sputtering[J].Surface & Coatings Technology,2003(0):181-186. |
| [12] | Grosse P;Hertling R;Muggenburg T .Design of low emissivity systems based on a three-layer coating[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1997(0):38-43. |
| [13] | Z.W. Liu;C.K. Ong .Synthesis and size control of ZnO nanorods by conventional pulsed-laser deposition without catalyst[J].Materials Letters,2007(16):3329-3333. |
| [14] | Latcheri S;Arnellini C;Rocca F et al.X-ray Studies on Optical and Structural Properties of ZnO Nanostrutured Thin Films[J].Superlattices and Microstructures,2006,39(1-4):267-281. |
| [15] | Yanfa Yan;M. M. Al-Jassim;Su-Huai Wei .Doping of ZnO by group-IB elements[J].Applied physics letters,2006(18):181912-1-181912-3-0. |
| [16] | Hong CS;Park HH;Moon J;Park HH .Effect of metal (Al, Ga, and In)-dopants and/or Ag-nanoparticles on the optical and electrical properties of ZnO thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(3):957-960. |
| [17] | Smith SL;Nissamudeen KM;Philip D;Gopchandran KG .Studies on surface plasmon resonance and photoluminescence of silver nanoparticles[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2008(1):186-190. |
| [18] | Duan L;Lin B X;Fu Z X .Enhancement of Ultraviolet Emissions from ZnO Films by Ag Doping[J].Applied Physics Letters,2006,88:232110-1-232110-232113. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%