欢迎登录材料期刊网

材料期刊网

高级检索

以2-异丙基硫杂蒽酮为原料,乙腈为溶剂经硝酸铈铵氧化得到中间体2-异丙基硫杂蒽酮亚砜,在硫酸存在的条件下,再与联苯反应得到锍盐中间体.最后以醇类和水为混合溶剂,锍盐中间体与六氟磷酸钾进行离子交换得到10-(4-联苯基)-2-异丙基噻吨酮硫(鎓)六氟磷酸.通过紫外光谱、红外光谱和核磁共振测定,对产物进行了结构确证.

参考文献

[1] Johan L D;Nigel P Hacker .Photochemistry of triarylsulfonium salts[J].Journal of the American Chemical Society,1990,112(16):6604-6015.
[2] Watt W R;Hoffman H T;Pobiner J R H;Schkolnick L J Yang L S .Anovel photoinitiator of cationic polymerization:Preparation and characterization of Bis[4-(diphenylsulfonio)phenyl]sulfide-Bis-Hexafluomphcaphate[J].Journal of Polymer Science Part A:Polymer Chemistry,1984,22:1789-1796.
[3] Grivello;James Vincent .Triaryl sulfonium photoinitiators[P].USpatent,5 012 001,1984-10-22.
[4] 杜西莹;王永林;闫庆金;赵文超,韩仕甸,姚丽秀 .10-(4-联苯基)-2-异丙基噻吨酮硫(鎓)六氟磷酸盐的制备方法[P].中国专利,101 153 037,2008-4-2.
[5] Shaun L H C;R0ber S D L;Brian R M .Novel fused ring compounds,and their use as cationic photoinitiators[P].US patent,176 969,2005-08-11.
[6] Davidson R S;Pratt J .Novel compounds for use as photolnitiators[P].WO patent,03 002 557,2003-09-01.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%