固相合成铝掺杂高Ni系层状锂电池正极材料

材料导报, 2013, 27(23): 32-36.

固相合成铝掺杂高Ni系层状锂电池正极材料

夏书标 ^1, , 张英杰 ^2, , 董鹏 ^3, , 张雁南 ^4,

1.曲靖师范学院化学化工学院,曲靖655011;昆明理工大学材料科学与工程学院,昆明650093

2.昆明理工大学材料科学与工程学院,昆明650093

3.昆明理工大学材料科学与工程学院,昆明650093

4.昆明理工大学材料科学与工程学院,昆明650093

基金项目: 云南省自然科学基金(200680048M) 曲靖师范学院校级基金(2010003)

关键词：铝掺杂 , 高Ni系层状材料 , 锂离子电池 , 固相反应

Solid-phase Synthesis High-nickel Layer Cathode Materials with Aluminum Doped in LIB

XIA Shubiao ^1, , ZHANG Yingjie ^2, , DONG Peng ^3, , ZHANG Yannan ^4,

1.曲靖师范学院化学化工学院,曲靖655011;昆明理工大学材料科学与工程学院,昆明650093

2.昆明理工大学材料科学与工程学院,昆明650093

3.昆明理工大学材料科学与工程学院,昆明650093

4.昆明理工大学材料科学与工程学院,昆明650093

Keywords： aluminum doping , high nickel layer material , lithium ion batteries , solid phase reaction

高Ni系层状锂离子电池正极材料具有优越的质量比容量.综述了高Ni系层状材料在结构和性能方面的优缺点.重点介绍了固相法合成铝掺杂高Ni系层状材料的方法,并且对影响固相法合成铝掺杂高Ni系层状材料结构性能的烧结条件作了重点分析.

参考文献

[1]	Tsutomu Ohzuku;Atsushi Ueda;Masatashi Nagayama .Electrochemistry and structural chemistry of LiNiO2 (R-3m)for 4 volt secondary lithium cells[J].Journal of the Electrochemical Society,1993,140(07):1862.
[2]	Zhang Yingjie;Xia Shubiao;Zhang Yannan et al.The cedoped LiNi1/3 Co(1/3-x/3) Mn1/3 Cex/3O2 in cathode materials for lithium ion batteries[J].Chinese Science Bulletin,2012,57(27):4181.
[3]	Shi S J;Tu J P;Tang Y Y et al.Morphology and electrochemical performance of Li(Li0.2 Mn0.54 Ni0.13 Co0.13) O2 cathode materials treated in molten salts[J].Journal of Power Sources,2013,241(01):186.
[4]	Reddy M V;Tung B D;Yang L et al.Molten salt method of preparation and cathodic studies on layered-cathode materials Li(Co0.7Ni0.3)O2 and Li(Ni0.7Co0.3)O2 for Li-ion batteries[J].Journal of Power Sources,2013,225(01):374.
[5]	Liu W M;Hu G R;Du K et al.Enhanced storage property of LiNi0.8Co0.15 Al0.05 O2 coated with LiCoO2[J].Journal of Power Sources,2013,230(15):201.
[6]	C.H. Chen;J. Liu;M.E. Stoll;G. Henriksen;D.R. Vissers;K. Amine .Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries[J].Journal of Power Sources,2004(2):278-285.
[7]	Delmas C;Menertrier M;Croguennec L et al.An overiew of the Li(Ni,M)O2 systems:Syntheses structures and properties[J].Electrochimica Acta,1999,45(1-2):243.
[8]	Liu Wanmin;Hu Guorong;Peng Zhongdong .Synthesis of spherical LiNi0.8 Co0.15 Al0.05 O2 cathode materials for lithiumion batteries by a co-oxidation-controlled crystallization method[J].Chinese Chemical Letters,2011,22:1099.
[9]	Hu Guorong;Liu Wanmin;Peng Zhongdong et al.Synthesis and electrochemical properties of LiNi0.8 Co0.15 Al0.05 O2prepared from the precursor Ni0.8 Co0.15 Al0.05 OOH[J].Journal of Power Sources,2012,198:258.
[10]	肖启振,苏光耀,李朝晖,高德淑,李文,刘黎.LiNi0.75Co0.2Al0.05-xMgxO2的合成及性能研究[J].电池,2004(06):406-407.
[11]	Kalaiselvi N;Raajarajan A V;Sivagaminathan B et al.Synthesis of optimized LiNiO2 for lithium ion batteries[J].Int J Ionics,2003,9(05):382.
[12]	Wang G X;Zhong S;Bradhurst D H et al.LiAlNi1-xO2 solid solutions as cathode materials or rechargeable lithium batteries[J].Solid State Ionics,1999,16(02):71.
[13]	Lin SP.;Fung KZ.;Hon YM.;Hon MH. .Effect of Al addition on formation of layer-structured LiNiO2[J].International Journal of Quantum Chemistry,2002(1):97-106.
[14]	王子港;魏晓玲;杨朗 .锂离子电池正极材料LiNi0.8 Co0.15-Al0.05O2热失控机理研究[J].电源技术,2011,34(11):1130.
[15]	Kazutoshi Matsumoto;RYuichi Kuzuo;Kaname Takeya;Atsushi Yamanaka .Effects of CO_2 in air on Li deintercalation from LiNi_1-x-yCo_xAl_yO_2[J].Journal of Power Sources,1999(0):558-561.
[16]	Pyun S;Lee M .Cation mixing lithium intercalation into and deinter-calation from LiAlyNi1-yO2 (0～y≤0.25) electrodes[J].Mol Cryst Liq Cryst Sci Techn Sect,2000,341(03):163.
[17]	汤宏伟,陈宗璋,钟发平.LiNi1-xMxO2 （M =Co3+, Al3+）的制备与性能[J].中国有色金属学报,2003(04):859-863.
[18]	李晓干,仇卫华,林传刚,刘庆国.LiAlyNi1-yO2作为锂离子电池正极材料的研究[J].电化学,2000(03):357-362.
[19]	江卫军,其鲁,柯克,王银杰,晨晖.锂离子二次电池正极材料LiAlyCo0.2Ni0.8-yO2 的合成及其电化学性能研究[J].无机化学学报,2003(12):1280-1284.
[20]	杨长春;张爱珍;侯巧芝 .锂离子电池正极材料LiNi0.8-x-Co0.2AlxO的制备及性能[J].郑州大学学报理学报,2005,38(02):92.
[21]	叶乃清,沈上越.锂离子电池正极材料LiNi1-xAlxO2的低温燃烧合成[J].材料导报,2005(z2):271-273.
[22]	常照荣,齐霞,吴锋,汤宏伟,王蒋亮.低共熔混合锂盐合成Co和Al共掺杂的LiNiO2[J].化学工程,2006(12):50-53.
[23]	彭运吉,叶乃清,田华,刘斌昌.球形正极材料LiNi0.8-xCo0.2AlxO2的合成与表征[J].桂林工学院学报,2007(04):557-561.
[24]	闫芳,叶乃清,赵巧丽,钟卓洪.LiNi0.5Mn0.45Al0.05O2的低温燃烧合成[J].电池,2011(02):79-81.
[25]	Elumalai P;Vasan H N;Munichandraiah N .Microwave synthesis and electrochemical properties of LiCo1-x MxO2 (M=Al and Mg) cathodes for Li-ion rechargeable batteries[J].Journal of Power Sources,2004,125(01):77.
[26]	Rotraut Merkle;Joachim Maier .On the Tammann-rule[J].J Inorg Gener Chem,2005,631(6-7):1163.
[27]	ZHU Xianjun,ZHAN Hui,LIU Hanxing,ZHOU Yunhong.Synthesis and characterization of LiNi0.95-xCoxAl0.05O2 for lithium-ion batteries[J].稀有金属（英文版）,2006(04):303-308.
[28]	Shuji Yamada;Masashi Fujiwara;Motoya Kanda .Synthesis and properties of LiNiO2 as cathode material for secondary batteries[J].Journal of Power Sources,1995,54(02):209.
[29]	李辉,翟玉春,田彦文.锂离子电池正极材料LiNi1-yAlyO2的制备及性能[J].中国有色金属学报,2003(03):690-694.
[30]	Xiong X H;Wang Z X;Yue P et al.Washing effects on electrochemical performance and storage characteristics of LiNi0.8Co0.1Mn0.1O2 as cathode material for lithium-ion batteries[J].Journal of Power Sources,2013,222(54):318.
[31]	Tran H Y;Greco G;Taubert C et al.Influence of electrode preparation on the electrochemical performance of LiNi0.8-Co0.15 Al0.05O2 composite electrodes for lithium-ion batteries[J].Journal of Power Sources,2013,210(15):276.

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固相合成铝掺杂高Ni系层状锂电池正极材料

Solid-phase Synthesis High-nickel Layer Cathode Materials with Aluminum Doped in LIB

参考文献