复合改性剂对硫酸钙晶须的表面改性及溶解抑制研究

功能材料, 2012, 43(14): 1833-1836.

复合改性剂对硫酸钙晶须的表面改性及溶解抑制研究

王力 ^1, , 庄春艳 ^2, , 主曦曦 ^3, , 刘聪 ^4, , 孟德琴 ^5, , 方杰 ^6,

1.山东科技大学化学与环境工程学院,山东青岛266510

2.山东科技大学化学与环境工程学院,山东青岛266510

3.山东科技大学化学与环境工程学院,山东青岛266510

4.山东科技大学化学与环境工程学院,山东青岛266510

5.山东科技大学化学与环境工程学院,山东青岛266510

6.山东科技大学化学与环境工程学院,山东青岛266510

基金项目: 山东科技大学研究生创新基金资助项目(YCA100358)

关键词：硫酸钙晶须 , 表面改性 , 溶解抑制 , 改性剂 , 留着率

Research on the modification and dissolution-inhibiting of calcium sulfate whisker

Keywords： calcium sulfate whisker , surface modification , dissolution-Inhibiting , modify agent , retention

设计了一种LZ复合表面改性剂,旨在抑制硫酸钙晶须的溶解,提高其留着率。考察了不同因素对硫酸钙晶须留着率的影响,得出了最佳改性条件,使晶须留着率由60.50%提高为93.67%。对改性前后硫酸钙晶须的表面性质进行IR表征及SEM观察,结果表明晶须表面发生了多层包覆与吸附,在此基础上建立了改性模型。

A kind of hybrid modify agent LZ was designed to inhibit the dissolution of calcium sulfate whisker（CSW） and improve its retention.Different modification conditions were studied to get an optimal method,by which the retention of CSW was improved from 60.50% to 93.67%.The surface properties changes before/after the modification were analyzed and characterized by IR and SEM.It was found that the CSW was coated and adsorbed multiply by the hybrid agents,and a modification model was set up.

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