当液一固反应为流体扩散控制时,以缩核模型为基础,得到了单颗粒消溶时粒径的变化规律,满足平方反比定律;在单颗粒消溶的基础上,建立了颗粒群消溶模型,得到了单颗粒微观反应模型和颗粒群宏观反应特征的关联关系.以不同种类的石灰石在不同温度和pH值下的消溶过程为例,对液固反应的微观-宏观关联模型进行了实验验证,实验和数学模型吻合较好.该关联模型对完善液固反应理论体系,实现宏观实验数据反推微观化学反应参数的测量技术具有重要意义.
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