聚对苯撑苯并二噁唑是一类具有独特刚性结构的芳香族液晶高分子.因其具有高强度、高模量及耐高温性能而成为杂环聚合物中最有发展潜力的一类聚合物,并受到广泛关注.总结、分析了近年来制备聚对苯撑苯并二噁唑的方法,如对苯二甲酸法、对苯二甲酰氯法、DAR/TPA盐法等,并展望了聚对苯撑苯并二噁唑聚合物的发展方向和趋势.
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