铸锭中过高的杂质浓度是影响铸造多晶硅太阳电池效率的主要因素之一.铸锭生长过程中的杂质主要有C、N、O、金属离子及固体颗粒SiC和Si3 N4.这些杂质能够降低晶片中少数载流子的寿命及太阳电池的填充因子;同时固体颗粒会造成切片过程的断线和晶片表面产生划痕.设计了一种新的方法生长大晶粒多晶硅,对石墨垫板进行刻槽处理,并采用数值模拟的方法模拟了该生长过程杂质的传输.模拟结果表明,刻槽的深度明显影响着初始生长时结晶界面上O、C和N的分布;同时刻槽深度越大,生长速率越快,越能够抑制晶体中SiC和Si3N4的形成.
参考文献
[1] | Gu, X.;Yu, X.;Guo, K.;Chen, L.;Wang, D.;Yang, D..Seed-assisted cast quasi-single crystalline silicon for photovoltaic application: Towards high efficiency and low cost silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2012:95-101. |
[2] | Ma, W.;Zhong, G.;Sun, L.;Yu, Q.;Huang, X.;Liu, L..Influence of an insulation partition on a seeded directional solidification process for quasi-single crystalline silicon ingot for high-efficiency solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2012:231-238. |
[3] | 苏柳,郝秋艳,解新建,刘彩池,刘晓兵,Jin Hao.准单晶硅技术研究进展[J].硅酸盐通报,2012(03):609-612. |
[4] | 娄中士,左然,苏文佳,杨琳.大晶粒多晶硅铸锭生长的热场设计与模拟[J].人工晶体学报,2011(06):1602-1606. |
[5] | Wang TY;Hsu SL;Fei CC;Yei KM;Hsu WC;Lan CW .Grain control using spot cooling in multi-crystalline silicon crystal growth[J].Journal of Crystal Growth,2009(2):263-267. |
[6] | T.F. Li;K.M. Yeh;W.C. Hsu;C.W. Lan .High-quality multi-crystalline silicon (mc-Si) grown by directional solidification using notched crucibles[J].Journal of Crystal Growth,2011(1):219-223. |
[7] | Yang DR.;Ma XY.;Fan RX.;Que DL.;Moeller HJ.;Li LB. .Oxygen-related centers in multicrystalline silicon[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(1/2):37-42. |
[8] | O. Breitenstein;J. P. Rakotoniaina;M. H. Al Rifai .Shunt Types in Crystalline Silicon Solar Cells[J].Progress in photovoltaics,2004(7):529-538. |
[9] | 邓太平 .太阳能多晶硅锭中夹杂的分布特性及其成因[D].南昌大学,2007. |
[10] | Du GP;Chen N;Rossetto P .On-wafer investigation of SiC and Si3N4 inclusions in multicrystalline Si grown by directional solidification[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(9):1059-1066. |
[11] | Lili Zheng;Xu Ma;Dongli Hu;Hui Zhang;Tao Zhang;Yuepeng Wan .Mechanism and modeling of silicon carbide formation and engulfment in industrial silicon directional solidification growth[J].Journal of Crystal Growth,2011(1):313-317. |
[12] | Liu LJ;Nakano S;Kakimoto K .Dynamic simulation of temperature and iron distributions in a casting process for crystalline silicon solar cells with a global model[J].Journal of Crystal Growth,2006(2):515-518. |
[13] | About the formation and avoidance of C and N related precipitates during directional solidification of multi-crystalline silicon from contaminated feedstock[J].Journal of Crystal Growth,2010(9):p.1510. |
[14] | Modeling of incorporation of O, N, C and formation of related precipitates during directional solidification of silicon under consideration of variable processing parameters[J].Journal of Crystal Growth,2010(7):878. |
[15] | The influence of growth rate on the formation and avoidance of C and N related precipitates during directional solidification of multi crystalline silicon[J].Journal of Crystal Growth,2010(9):p.1517. |
[16] | The carbon distribution in multicrystalline silicon ingots grown using the directional solidification process[J].Journal of Crystal Growth,2010(8):p.1282. |
[17] | STR Group .Silicon growth modeling-description of the chemical model[EB/OL].http://www.semitech.us |
[18] | Liu LJ;Nakano S;Kakimoto K .Carbon concentration and particle precipitation during directional solidification of multicrystalline silicon for solar cells[J].Journal of Crystal Growth,2008(7/9):2192-2197. |
[19] | Rannveig Kvande;(O)yvind Mjos;Birgit Ryningen .Growth rate and impurity distribution in multi-crystalline silicon for solar cells[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2005,413-414:545. |
[20] | Wei, Jiuan;Zhang, Hui;Zheng, Lili;Wang, Chenlei;Zhao, Bo .Modeling and improvement of silicon ingot directional solidification for industrial production systems[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(9):1531-1539. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%