将二茂铁加入到舍金属Al的Mg0C材料基质中,经高温处理后,研究了二茂铁对基质物相组成和显微结构的影响.结果表明,从1300℃开始.基质中原位生成大量的富镁尖晶石纤维,纤维的数量、长度和直径随处理温度的升高而增大.推测尖晶石纤雏是在二茂铁热解产生的纳米铁粒子催化作用下,通过气-液-固(VCS)机制和气-固(VS)机制形成.同时二茂铁还可能起到催化MgO的碳热还原反应和Al4C3的分解反应的作用,使材料基质在较低温度下开始产生Mg、Al气相,促进纤维的生长.二茂铁的加入还使低碳MgO-C材料产品的物理性能得到提高.
参考文献
[1] | Lee W E;Zhang S;Li N.Microstructural characterisa tion of in situ matrix phase formation in refractories[A].FL:Orlando,2005:326. |
[2] | Ganesh I et al.An efficient MgAl2O4 spinel additive for improved slag erosion and penetration resistance of high-Al2O4 and MgO-C refractories[J].Ceramics International,2002,28(03):245. |
[3] | M. Bavand-Vandchali;F. Golestani-Fard;H. Sarpoolaky .The influence of in situ spinel formation on microstructure and phase evolution of MgO-C refractories[J].Journal of the European Ceramic Society,2008(3):563-569. |
[4] | M. Bavand-Vandchali;H. Sarpoolaky;F. Golestani-Fard .Atmosphere and carbon effects on microstructure and phase analysis of in situ spinel formation in MgO-C refractories matrix[J].CERAMICS INTERNATIONAL,2009(2):861-868. |
[5] | C.G. ANEZIRIS;J. HUBALKOVA;R. BARABAS .Microstructure evaluation of MgO-C refractories with TiO_2- and Al-additions[J].Journal of the European Ceramic Society,2007(1):73-78. |
[6] | 杨道媛,贾晓林,郭新荣,张海军,孙加林,钟香崇.六方柱状MgAl2O4纤维的合成机理初探[J].材料导报,2004(z1):311-313. |
[7] | 丁佩,梁二军,晁明举,郭新勇,张经纬.二茂铁催化制备CNx纳米管的研究[J].化学物理学报,2005(02):268-272. |
[8] | 石峰军,程春,丁晓夏,程筠,唐成春,祁守仁.用二茂铁催化生长竹节状碳纳米管[J].华中师范大学学报(自然科学版),2004(01):40-43. |
[9] | 刘景林;李连洲 .碳结合耐火材料中结合剂与石墨之间的反应特性[J].耐火与石灰,2008,33(02):44. |
[10] | Zhang S;Marriott N J;Lee W E .Thermochemistry and microstructures of MgO-C refractories containing various antioxidants[J].Journal of the European Ceramic Society,2001,21(08):1037. |
[11] | 山口明良.实用热力学及其在高温陶瓷中的应用[M].武汉:武汉理工大学出版社,1991:26. |
[12] | Guha J P;Smith J D.Reaction chemistry and microstructure development of MgO-C refractories containing metal antioxidants[A].FL:Orlando,2005:97. |
[13] | Bernhauer M et al.Kinetics of mesophase formation in a stirred tank reactor and properties of the products.V:Catalysis by ferrocene[J].CARBON,1994,32(06):1073. |
[14] | Li R;Wei P;Sano M et al.Catalytic reduction of magnesia by carbor[J].Thermochimica Acta,2003,398(1-2):265. |
[15] | 郝兆春 .MgO-C质耐火材料的热过程和机械性能[J].国外耐火材料,1997,22(03):18. |
[16] | Zhang S;Yamaguchi A .Effects of CaO and Al2O4 added to MgO-C refractories on MgO-C reaction[J].Journal of the Ceramic Society of Japan,1996,104(1206):84. |
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