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The wetting behavior and interfaces of CuZr-based glassy alloys/W system were investigated by the sessile drop method. It was found that Cu(50)Zr(50)/W, Cu(47.5)Zr(47.5)Al(5)/W and Cu(40)Zr(44)Al(8)Ag(8)/W system had the final equilibrium contact angle around 18 degrees, 8 degrees and 3 degrees at corresponding experimental temperatures. Base on the scanning electron microscopy observing, no reaction product can be found at the interface of Cu(47.5)Zr(47.5)Al(5)/W and Cu(40)Zr(44)Al(8)Ag(8)/W, and some granular reaction products appeared along the interface of Cu(50)Zr(50)/W. The present work indicates that Cu(47.5)Zr(47.5)Al(5) and Cu(40)Zr(44)Al(8)Ag(8) bulk metallic glasses (BMGs) are appropriate for the fabrication of W reinforced BMGs matrix composite. (C) 2010 Elsevier B.V. All rights reserved.