基于萤石的晶体(表面)结构,研究并总结表面断裂键性质、解理及暴露面性质、表面(自由)能、润湿性、表面电性、吸附性等萤石表面物理化学性质的各向异性,讨论萤石晶体结构特征与表面性质之间的关系,分析不同表面性质之间的关联.结果表明:表面断裂键密度和表面能存在正相关性,表面断裂键密度可准确预测萤石的解理和暴露面性质,表面离子层结构差异、表面Ca质点及其断裂键差异可解释表面电性、润湿性、溶解性及吸附性的各向异性.
参考文献
[1] | 王文利;白志民.中国萤石资源及产业发展现状[J].金属矿山,2014(3):1-9. |
[2] | Pradip.;Rai B.;Rao TK.;Krishnamurthy S.;Vetrivel R.;Mielczarski J. Cases JM..Molecular modeling of interactions of alkyl hydroxamates with calcium minerals[J].Journal of Colloid and Interface Science,20021(1):106-113. |
[3] | 高志勇;孙伟;胡岳华.矿物的解理性质及表面能:各向异性的表面断裂因素[J].中国有色金属学报(英文版),2014(9):2930-2937. |
[4] | 高志勇;孙伟;胡岳华;刘晓文.方解石和萤石晶体表面断裂键性质和润湿性的各向异性[J].中国有色金属学报,2012(5):1203-1208. |
[5] | Saravanan R;Israel S.Bonding in fluorite compound CaF2 using MEM[J].Physica, B. Condensed Matter,20041/4(1/4):220-226. |
[6] | de Leeuw NH.;Rao KH.;Parker SC..Modeling the competitive adsorption of water and methanoic acid on calcite and fluorite surfaces[J].Langmuir: The ACS Journal of Surfaces and Colloids,199820(20):5900-5906. |
[7] | de Leeuw NH.;Cooper TG..A computational study of the surface structure and reactivity of calcium fluoride[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20031(1):93-101. |
[8] | P. Maldonado;J. R. A. Godinho;L Z. Evins.Ab Initio Prediction of Surface Stability of Fluorite Materials and Experimental Verification[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201313(13):6639-6650. |
[9] | Godinho, J.R.A.;Piazolo, S.;Evins, L.Z..Effect of surface orientation on dissolution rates and topography of CaF _2[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,2012:392-403. |
[10] | Drelich J.;Yalamanchili MR.;Miller JD.;Atia AA..FORMATION AND WETTING CHARACTERISTICS OF ADSORBED LAYERS OF UNSATURATED CARBOXYLIC ACIDS AT A FLUORITE SURFACE[J].Journal of Colloid and Interface Science,19962(2):720-732. |
[11] | 陆现彩;侯庆锋;尹琳;赵连泽;刘显东.几种常见矿物的接触角测定及其讨论[J].岩石矿物学杂志,2003(4):397-400. |
[12] | Keqing Fa;Anh V. Nguyen;Jan D. Miller.Interaction of calcium dioleate collector colloids with calcite and fluorite surfaces as revealed by AFM force measurements and molecular dynamics simulation[J].International Journal of Mineral Processing,20063(3):166-177. |
[13] | K.A.Becraft;G.L.Richmond.In Situ Vibrational Spectroscopic Studies of the CaF_2/H_2O Interface[J].Langmuir: The ACS Journal of Surfaces and Colloids,200125(25):7721-7724. |
[14] | Miller JD;Fa KQ;Calara JV;Paruchuri VK.The surface charge of fluorite in the absence of surface carbonation[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20041/3(1/3):91-97. |
[15] | Shoeleh Assemi;Jakub Nalaskowski;Jan D.Miller;William P.Johnson.Isoelectric Point of Fluorite by Direct Force Measurements Using Atomic Force Microscopy[J].Langmuir: The ACS Journal of Surfaces and Colloids,20064(4):1403-1405. |
[16] | Khenata R;Daoudi B;Sahnoun M;Baltache H;Rerat M;Reshak AH;Bouhafs B;Abid H;Driz M.Structural, electronic and optical properties of fluorite-type compounds[J].The European physical journal, B. Condensed matter physics,20051(1):63-70. |
[17] | Mielczarski E.;Mielczarski JA.;Cases JM.;Rai B.;Pradip..Influence of solution conditions and mineral surface structure on the formation of oleate adsorption layers on fluorite[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20021/2(1/2):73-84. |
[18] | Rai, B;Pradip.Design of highly selective industrial performance chemicals: a molecular modelling approach[J].Molecular Simulation,200810/15(10/15):1209-1214. |
[19] | Lu YQ.;Miller JD.;Drelich J..Oleate adsorption at an apatite surface studied by ex-situ FTIR internal reflection spectroscopy[J].Journal of Colloid and Interface Science,19982(2):462-476. |
[20] | Mielczarski E.;Cases JM.;Mielczarski JA..Molecular recognition effect in monolayer formation of oleate on fluorite[J].Langmuir: The ACS Journal of Surfaces and Colloids,19987(7):1739-1747. |
[21] | Sreedevi, P.;Chennakesavulu, K.;Kavitha, M.;Bhaskar Raju, G.;Prabhakar, S..Electrokinetic behavior of fluorite[J].Journal of Dispersion Science and Technology,20117/9(7/9):1306-1310. |
[22] | Kevin A.Becraft;Fred G.Moore;Geraldine L.Richmond.In-situ spectroscopic investigations of surfactant adsorption and water structure at the CaF_2/aqueous solution interface[J].Physical chemistry chemical physics: PCCP,20048(8):1880-1889. |
[23] | 张英;王毓华;胡岳华;文书明;王进明.白钨矿与萤石、方解石电子结构的第一性原理研究[J].稀有金属,2014(6):1106-1113. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%