氢是一种清洁的燃料,氢能是未来有发展前景的新型能源之一.氢的储存是氢能现阶段开发和利用的瓶颈.氢的储存方法有高压气态储存、低温液态储存和固态储存等3种,其中高压气态储存或低温液态储存不能满足将来的储氢目标.固态储氢是通过化学或物理吸附将氢气储存于固态材料中,其能量密度高且安全性好,被认为是最有发展前景的一种氢气储存方式.高密度储氢材料由轻元素构成,包括铝氢化物、硼氢化物、氨基氢化物、氨硼烷等,理论储氢质量分数均达到5%以上.综述了高密度储氢材料的研究进展,认为高储氢容量、近室温操作、可控吸/放氢、长寿命的轻质氢化物材料有希望达到燃料电池和移动氢源应用的目标.
参考文献
| [1] | Schlabach L;Züttel A .Hydrogen-Storage Materials for Mobile Applications[J].Nature,2001,414:353-358. |
| [2] | 江泽民.对中国能源问题的思考[J].上海交通大学学报,2008(03):345-359. |
| [3] | IEA Hydrogen Co-Ordination Group .Hydrogen Production and Storage[OL].http://www.iea.org/Textbase/papers/2006/hydrogen.pdf |
| [4] | Multi-Year Research .Development and Demonstration Plan:Planned Program Activities for 2005-2015[OL].http://www1.eere.energy.gov/hydrogenandfuelcells/mypp/ |
| [5] | Züttel A.Materials for Hydrogen Storage[J].Materials Today,2003(06):24-33. |
| [6] | 许炜,陶占良,陈军.储氢研究进展[J].化学进展,2006(02):200-210. |
| [7] | 浙大新闻办 .浙大研制成功世界最大的固定储氢罐[OL].http://www.zju.edu.cn/zdxw/jd/read.php?recid=22839 |
| [8] | Crabtree R H.Hydrogen Storage in Liquid Organic Heterocycles[J].Energ Environ Sci,2008(01):134-138. |
| [9] | M. Fichtner .Nanotechnological Aspects in Materials for Hydrogen Storage[J].Advanced Engineering Materials,2005(6):443-455. |
| [10] | Billur Sakintuna;Farida Lamari-Darkrim;Michael Hirscher .Metal hydride materials for solid hydrogen storage: A review[J].International journal of hydrogen energy,2007(9):1121-1140. |
| [11] | T.Kuriiwa;T.Tamura .New V-based alloys with high protium absorption and desorption capacity[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):433-436. |
| [12] | X.B. Yu;Z. Wu;B.J. Xia .Enhancement of hydrogen storage capacity of Ti-V-Cr-Mn BCC phase alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2004(1/2):272-277. |
| [13] | A.Zaluska;L.Zaluski;J.O.Strom-olsen .Structure,catalysis and atomic reactions on the nano-scale:a systematic approach to metal hydrides for hydrogen storage[J].Applied physics, A. Materials science & processing,2001(2):157-165. |
| [14] | H.Reule;M.Hirscher .Hydrogen desorption properties of mechanically alloyed Mgh_2 composite materials[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):246-252. |
| [15] | Huot J;Liang G;Boily S et al.Strutural Study and Hydrogen Sorption Kinetics of Ball-Milled Magnesium Hydride[J].Journal of Alloys and Compounds,1999,293/295:495-500. |
| [16] | Zaluska A;Zaluski L;Strm-Olsen J O .Nanocrystalline Metal Hydrides[J].Journal of Alloys and Compounds,1997,253:70-79. |
| [17] | Li WY;Li CS;Ma H;Chen J .Magnesium nanowires: Enhanced kinetics for hydrogen absorption and desorption[J].Journal of the American Chemical Society,2007(21):6710-6711. |
| [18] | Ouyang L Z;Ye S Y;Dong H W et al.Effect of Interfacial Free Energy on Hydriding Reaction of Mg-Ni Thin Films[J].Applied Physics Letters,2007,90:021917. |
| [19] | Andreasen A;Vegge T;Pedersen A S .Compensation Effect in the Hydrogenation/Dehydrogenation Kinetics of Metal Hydrides[J].Journal of Physical Chemistry B,2005,109:3340-3344. |
| [20] | Gross KJ.;Leroy E.;Zuttel A.;Schlapbach L.;Chartouni D. .Mechanically milled Mg composites for hydrogen storage: The relationship between morphology and kinetics[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):259-270. |
| [21] | M. Zhu;Y. Gao;X.Z. Che .Hydriding kinetics of nano-phase composite hydrogen storage alloys prepared by mechanical alloying of Mg and MmNi_(5-x) (CoAlMn)_x[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(0):708-713. |
| [22] | K. Higuchi;K. Yamamoto;H. Kajioka .Remarkable hydrogen storage properties in three-layered Pd/Mg/Pd thin films[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(0):526-530. |
| [23] | Bogdanovic B;Schwichardi M .Ti-Doped Alkali Metal Alminum Hydrides as Potential Novel Reversible Hydrogen Storage Materials[J].Journal of Alloys and Compounds,1997,253:1-9. |
| [24] | Schuth F;Bogdanovic B;Felderhoff M.Light Metal Hydrides and Complex Hydrides for Hydrogen Storage[J].Chemical Communications,2004:2249-2258. |
| [25] | Wang P;Kang X D;Cheng H M .Exploration of the Nature of Active Ti Species in Metallic Ti-Doped NaAlH4[J].Journal of Physical Chemistry B,2005,109:20131-20136. |
| [26] | Maximilian Fichtner;Olaf Fuhr;Oliver Kircher .Small Ti clusters for catalysis of hydrogen exchange in NaAlH_4[J].Nanotechnology,2003(7):778-785. |
| [27] | Bogdanovic B;Felderhoff M;Pommerin A;Schuth T;Spielkamp N .Advanced hydrogen-storage materials based on Sc-, Ce-, and Pr-doped NaAlH4[J].Advanced Materials,2006(9):1198-1201. |
| [28] | Andreasen A;Vegge T;Pedersen AS .Dehydrogenation kinetics of as-received and ball-milled LiAlH4[J].International Journal of Quantum Chemistry,2005(12):3672-3678. |
| [29] | Chen J;Kuriyama N;Xu Q et al.Reversible Hydrogen Storage via Titanium-Catalyzed LiAlH4 and Li3AlH6[J].Journal of Physical Chemistry B,2001,105:11214-11220. |
| [30] | Gross K.J.;Gutlirie S. .In-situ X-ray diffraction study of the decomposition of NaA1H_4[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):270-281. |
| [31] | K. J. Gross;E. H. Majzoub;S. W. Spangler .The effects of titanium precursors on hydriding properties of alanates[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(0):423-428. |
| [32] | Balema VP;Balema L .Missing pieces of the puzzle or about some unresolved issues in solid state chemistry of alkali metal aluminohydrides[J].Physical chemistry chemical physics: PCCP,2005(6):1310-1314. |
| [33] | Sun D;Kiyobayashi T;Takeshita H T et al.X-ray Diffraction Studies of Titanium and Zirconium Doped NaAlH4 Elucidation of Doping Induced Structural Changes and Their Relationship to Enhanced Hydrogen Storage Properties[J].Journal of Alloys and Compounds,2002,337:L8-L11. |
| [34] | Tetsu Kiyobayashi;Sesha S. Srinivasan;Dalin Sun;Craig M. Jensen .Kinetic Study and Determination of the Enthalpies of Activation of the Dehydrogenation of Titanium- and Zirconium-Doped NaAlH_4 and Na_3AlH_6[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2003(39):7671-7674. |
| [35] | Gunaydin, H;Houk, KN;Ozolins, V .Vacancy-mediated dehydrogenation of sodium alanate[J].Proceedings of the National Academy of Sciences of the United States of America,2008(10):3673-3677. |
| [36] | Shin-ichi Orimo;Yuko Nakamori;Jennifer R.Eliseo .Complex Hydrides for Hydrogen Storage[J].Chemical Reviews,2007(10):4111-4132. |
| [37] | A. Zuttel;S. Rentsch;P. Fischer .Hydrogen storage properties of LiBH_4[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(0):515-520. |
| [38] | Züttel A;Borgschulte A;Orimo S et al.Tetrahydroborates as New Hydrogen Storage Meterials[J].Scripta Materialia,2007,56:823-828. |
| [39] | Orimo S;Nakamori Y;Ohba N et al.Experimental Studies on Intermediate Compound of LiBH4[J].Applied Physics Letters,2006,89:021920. |
| [40] | Vajo J J;Skeith S L;Mertens F .Reversible Storage of Hydrogen in Destabilized LiBH4[J].Journal of Physical Chemistry B,2005,109:3719-3722. |
| [41] | Rudy W. P. Wagemans;Joop H. van Lenthe;Petra E. de Jongh;A. Jos van Dillen;Krijn P. de Jong .Hydrogen Storage in Magnesium Clusters: Quantum Chemical Study[J].Journal of the American Chemical Society,2005(47):16675-16680. |
| [42] | Vajo J J;Olson G L .Hydrogen Storage in Destabilized Chemical Systems[J].Scripta Materialia,2007,56:829-834. |
| [43] | Nakamori Y;Miwa K;Ninomiya A et al.Correlation between Thermodynamical Stabilities of Metal Borohydrides and Cation Electronegativities:First-Principles Calculations and Experiments[J].Physical Review B:Condensed Matter,2006,74:045126. |
| [44] | Y. Nakamori;H.-W. Li;K. Kikuchi .Thermodynamical stabilities of metal-borohydrides[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(0):296-300. |
| [45] | Yin, LC;Wang, P;Fang, ZZ;Cheng, HM .Thermodynamically tuning LiBH4 by fluorine anion doping for hydrogen storage: A density functional study[J].Chemical Physics Letters,2008(4/6):318-321. |
| [46] | Pena-Alonso R;Sicurelli A;Callone E et al.A Picoscale Catalyst for Hydrogen Generation from NaBH4 for Fuel Cell[J].Journal of Power Sources,2007,165:315-323. |
| [47] | Kim S J;Lee J;Kong K Y et al.Hydrogen Generation System using Sodium Borohydride for Operation of a 400 W-Scale Polymer Electrolyte Fuel Cell Stack[J].Journal of Power Sources,2007,170:412-418. |
| [48] | N. Patel;G. Guella;A. Kale;A. Miotello;B. Patton;C. Zanchetta;L. Mirenghi;P. Rotolo .Thin films of Co–B prepared by pulsed laser deposition as efficient catalysts in hydrogen producing reactions[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(0):18-24. |
| [49] | Hong-Bin Dai;Yan Liang;Ping Wang;Hui-Ming Cheng .Amorphous cobalt-boron/nickel foam as an effective catalyst for hydrogen generation from alkaline sodium borohydride solution[J].Journal of Power Sources,2008(1):17-23. |
| [50] | Zhao J Z;Ma H;Chen J .Improved Hydrogen Generation from Alkaline NaBH4 Solution Using Carbon-Supported Co-B as Catalysts[J].International Journal of Hydrogen Energy,2007,32:4711-4716. |
| [51] | Bin Hong Liu;Qian Li .A Highly Active Co-b Catalyst For Hydrogen Generation From Sodium Borohydride Hydrolysis[J].International journal of hydrogen energy,2008(24):7385-7391. |
| [52] | Zahmakiran M;Ozkar S .Water dispersible acetate stabilized ruthenium(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohyride[J].Journal of molecular catalysis, A. Chemical,2006(1/2):95-103. |
| [53] | Holbrook K A;Twist P J.Hydrolysis of the Borohydride Ion Catalysed by Metal-Boron Alloys[J].Journal of the Chemical Society,1971:890-894. |
| [54] | G.Guella;B.Patton;A.Miotello .Kinetic Features of the Platinum Catalyzed Hydrolysis of Sodium Borohydride from ~(11)B NMR Measurements[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(50):18744-18750. |
| [55] | Liu B H;Li Z P;Morigasaki N et al.Kinetic Characteristics of Sodium Borohydride Formation when Sodium Metal-Borate Reacts with Magnesium and Hydrogen[J].International Journal of Hydrogen Energy,2008,33:1323-1328. |
| [56] | Chen P;Xiong ZT;Luo JZ;Lin JY;Tan KL .Interaction of hydrogen with metal nitrides and imides[J].Nature,2002(6913):302-304. |
| [57] | T. Ichikawa;N. Hanada;S. Isobe .Hydrogen storage properties in Ti catalyzed Li-N-H system[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(0):435-438. |
| [58] | Orimo S;Nakamori Y;Kitahara G;Miwa K;Ohba N;Noritake T;Towata S .Destabilization and enhanced dehydriding reaction of LiNH2: an electronic structure viewpoint[J].Applied physics, A. Materials science & processing,2004(7):1765-1767. |
| [59] | Leng H Y;Ichikawa T;Hino S .Synthesis and Decomposition Reactions of Metal Amides Inmetal-N-H Hydrogen Storage System[J].Journal of Power Sources,2006,156:166-170. |
| [60] | Yun Hang;Eli Ruckenstein .Ultrafast Reaction between LiH and NH_3 during H_2 Storage in Li_3N[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2003(46):9737-9739. |
| [61] | Chen P;Xiong Z T;Luo J Z et al.Interaction between Lithium Amide and Lithium Hydride[J].Journal of Physical Chemistry B,2003,107:10967-10970. |
| [62] | Lu J;Fang ZGZ;Sohn HY .A dehydrogenation mechanism of metal hydrides based on interactions between H delta+ and H-[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2006(21):8749-8754. |
| [63] | Sit V;Geanangel R A;Wendlandt W W .The Thermal Dissociation of NH3BH3[J].Thermochimica Acta,1987,113:379-382. |
| [64] | Baitalow F.;Baumann J.;Wolf G.;Jaenicke-Rossler K.;Leitner G. .Thermal decomposition of B-N-H compounds investigated by using combined thermoanalytical methods[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2002(1/2):159-168. |
| [65] | Stephens FH;Pons V;Baker RT .Ammonia - borane: the hydrogen source par excellence?[J].Dalton transactions: An international journal of inorganic chemistry,2007(25):2613-2626. |
| [66] | Ashley C.Stowe;Wendy J.Shaw;John C.Linehan .In situ solid state ~(11)B MAS-NMR studies of the thermal decomposition of ammonia borane:mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material[J].Physical chemistry chemical physics: PCCP,2007(15):1831-1836. |
| [67] | Nguyen VS;Matus MH;Grant DJ;Nguyen MT;Dixon DA .Computational study of the release of H-2 from ammonia borane dimer (BH3NH3)(2) and its ion pair isomers[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2007(36):8844-8856. |
| [68] | Anna Gutowska;Liyu Li;Yongsoon Shin;Chongmin M. Wang;Xiaohong S. Li;John C. Linehan;R. Scott Smith;Bruce D. Kay;Benjamin Schmid;Wendy Shaw .Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane[J].Angewandte Chemie,2005(23):3578-3582. |
| [69] | ZHITAO XIONG;CHAW KEONG YONG;GUOTAO WU .High-capacity hydrogen storage in lithium and sodium amidoboranes[J].Nature materials,2008(2):138-141. |
| [70] | Xiangdong Kang;Zhanzhao Fang;Lingyan Kong;Huiming Cheng;Xiangdong Yao;Gaoqing Lu;Ping Wang .Ammonia Borane Destabilized by Lithium Hydride: An Advanced On-Board Hydrogen Storage Material[J].Advanced Materials,2008(14):2756-2759. |
| [71] | H. V. K. Diyabalanage;R. P. Shrestha;T. A. Semelsberger .Calcium Amidotrihydroborate: A Hydrogen Storage Material[J].Angewandte Chemie,2007(47):8995-8997. |
| [72] | Keaton RJ;Blacquiere JM;Baker RT .Base metal catalyzed dehydrogenation of ammonia-borane for chemical hydrogen storage[J].Journal of the American Chemical Society,2007(7):1844-1845. |
| [73] | Frances H.Stephens;R.Tom Baker;Myrna H.Matus .Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage[J].Angewandte Chemie,2007(5):746-749. |
| [74] | Martin E.Bluhm;Mark G.Bradley;Robert Butterick III;Upal Kusari;Larry G.Sneddon .Amineborane-Based Chemical Hydrogen Storage:Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids[J].Journal of the American Chemical Society,2006(24):7748-7749. |
| [75] | Chandra M;Xu Q .Room Temperature Hydrogen Generation from Aqueous Ammonia-Borane Using Noble Metal Nano-Clusters as Highly Active Catalysts[J].Journal of Power Sources,2007,168:135-142. |
| [76] | Timothy J.Clark;George R.Whittell;Ian Manners .Highly Efficient Colloidal Cobalt-and Rhodium-Catalyzed Hydrolysis of H3N-BH3 in Air[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(18):7522-7527. |
| [77] | Cheng FY;Ma H;Li YM;Chen J .Ni1-xPtx (x=0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia borane[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(3):788-794. |
| [78] | Jun-Min Yan;Xin-Bo Zhang;Song Han .Iron-Nanoparticle-Catalyzed Hydrolytic Dehydrogenation of Ammonia Borane for Chemical Hydrogen Storage[J].Angewandte Chemie,2008(12):2287-2289. |
| [79] | Chambers A;Park C;Baker R T K et al.Hydrogen Storage in Graphite Nanofibers[J].Journal of Physical Chemistry B,1998,102:4253-4256. |
| [80] | M. Hirscher;M. Becher .Hydrogen Storage In Carbon Nanotubes[J].Journal of nanoscience and nanotechnology,2003(1/2):3-17. |
| [81] | Nijkamp MG.;van Dillen AJ.;de Jong KP.;Raaymakers JEMJ. .Hydrogen storage using physisorption - materials demands[J].Applied physics, A. Materials science & processing,2001(5):619-623. |
| [82] | A. Zuttel;O. Sudan;Ph. Mauron .Hydrogen storage in carbon nanostructures[J].International journal of hydrogen energy,2002(2):203-212. |
| [83] | H.Gijs Schimmel;Gordon J.Kearley;Marije G.Nijkamp;Cornelis T.Visser;Krijn P.de Jong;Fokko M.Mulder .Hydrogen Adsorption in Carbon Nanostructures:Comparison of Nanotubes,Fibers,and Coals[J].Chemistry: A European journal,2003(19):4764-4770. |
| [84] | Ma R Z;Bando Y;Zhu H W .Hydrogen Uptake in Boron Nitride Nanotubes at Room Temperature[J].Journal of the American Chemical Society,2002,124:7672-7673. |
| [85] | Jun Chen;Nobuhiro Kuriyama;Huatang Yuan;HiroyukiT.Takeshita;Tetsuo Sakai .Electrochemical Hydrogen Storage in MoS_2 Nanotubes[J].Journal of the American Chemical Society,2001(47):11813-11814. |
| [86] | Chen J;Li S L;Tao Z L et al.Titanium Disulfide Nanotubes as Hydrogen-Storage Materials[J].Journal of the American Chemical Society,2003,125:5284-5285. |
| [87] | Weitkamp J;Fritz M;Ernst S .Zeolites as Media for Hydrogen Storage[J].International Journal of Hydrogen Energy,1995,20:967-970. |
| [88] | Rosi NL.;Eckert J.;Eddaoudi M.;Vodak DT.;Kim J.;O'Keeffe M.;Yaghi OM. .Hydrogen storage in microporous metal-organic frameworks[J].Science,2003(5622):1127-1129. |
| [89] | Mircea Dined;Jeffrey R.Long .Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites[J].Angewandte Chemie,2008(36):6766-6779. |
| [90] | Viktor V.Struzhkin;Burkhard Militzer;Wendy L.Mao .Hydrogen Storage in Molecular Clathrates[J].Chemical Reviews,2007(10):4133-4151. |
| [91] | Serguei Patchkovskii;John S. Tse .Thermodynamic stability of hydrogen clathrates[J].Proceedings of the National Academy of Sciences of the United States of America,2003(25):14645-14650. |
| [92] | Florusse LJ;Peters CJ;Schoonman J;Hester KC;Koh CA;Dec SF .Stable low-pressure hydrogen clusters stored in a binary clathrate hydrate[J].Science,2004(5695):469-471. |
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