改进传统的合成六方介孔材料的工艺,合成具有双纳米效应的掺镧介孔纳米球,以此作为卷烟添加剂,研究了其对红塔山经典1956卷烟主流烟气中含有的低分子醛酮化合物的吸附行为.结果表明在过滤嘴中加入了添加剂的烟样中8种低分子醛酮的含量明显低于没有加入添加剂的烟样,且测定结果的相对偏差小于0.3%.其中,甲醛的含量由186.0721μg/支减少到103.698μg/支,说明该掺镧介孔纳米球添加剂对甲醛的吸附具有较好的选择性.
参考文献
[1] | 谢兰英;刘淇;吴名剑 等.纳米催化材料降低卷烟烟气一氧化碳实验研究[J].现代化工,2007,27(02):231-233. |
[2] | 吕功煊,聂聪,赵明月,刘建福,丁彦.应用含纳米贵金属催化材料降低卷烟烟气中CO技术研究[J].中国烟草学报,2003(03):18-27. |
[3] | Ping Li;Donald E.Miser;Shahryar Rabiei;Ramkuber T.Yadav;Mohammad R.Hajaligol .The removal of carbon monoxide by iron oxide nanoparticles[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(2):151-162. |
[4] | 姜绍通,罗建平,潘丽军,黄静.茶多酚降低卷烟烟气毒性的研究[J].食品科学,2001(11):60-62. |
[5] | 张悠金,杨俊,李婉,方智勇.纳米材料降低卷烟烟气粒相有害成分的研究靠[J].化学研究与应用,2001(06):709-711. |
[6] | 周仕禄,王英,徐佳卉,徐杨,曹毅,朱建华,何新伟,张艳,王辉.用纳米孔材料去除卷烟烟气里的亚硝胺和多环芳烃[J].江苏化工,2004(03):29-31,40. |
[7] | 陈志钢,宋丹丹,贾志杰,唐一文,余颖,詹雪艳.碳纳米管对香烟烟气中总粒相物的去除[J].应用化学,2004(04):365-368. |
[8] | BRIAN G.TREWYN;IGOR I.SLOWING;SUPRATIM GIRI .Synthesis and Functionalization of a Mesoporous Silica Nanoparticle Based on the Sol-Gel Process and Applications in Controlled Release[J].Accounts of Chemical Research,2007(9):846-853. |
[9] | Torney F;Trewyn BG;Lin VSY;Wang K .Mesoporous silica nanoparticles deliver DNA and chemicals into plants[J].Nature nanotechnology,2007(5):295-300. |
[10] | Rosenholm JM;Duchanoy A;Linden M .Hyperbranching surface polymerization as a tool for preferential functionalization of the outer surface of mesoporous silica[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(3):1126-1133. |
[11] | A. Montesinos-Castellanos;T.A. Zepeda .High hydrogenation performance of the mesoporous NiMo/Al(Ti, Zr)-HMS catalysts[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2008(1/3):146-162. |
[12] | Shohei Imachi;Kisho Owada;Makoto Onaka .Intramolecular carbonyl-ene reaction of citronellal to isopulegol over ZnBr2-loading mesoporous silica catalysts[J].Journal of molecular catalysis, A. Chemical,2007(1/2):174-181. |
[13] | Shrikant S;Bhoware S;Shylesh K R et al.Cobalt-containing hexagonal mesoporous molecular sieves(Co-HMS):synthesis,characterization and catalytic activity in the oxidation reaction of ethylhenzene[J].Journal of Molecular Catalysis A:Chemical,2006,255:123-130. |
[14] | Anyuan Yin;Xiuying Guo;Wei-Lin Dai .Highly active and selective copper-containing HMS catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2008(1/2):91-99. |
[15] | Wei K;Guo W;Du C et al.Preparation of PrxZn1-xO nanopowder with UV-Visible light response[J].Materials Letters,2009,63:1781-1784. |
[16] | K. Wei;Wusheng Guo;Chen Lai .Molecular self-assembly synthesis of nano-sphere of La-containing hexagonal mesoporous solid[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):841-845. |
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