固体恸硝酰硝酸钌不含卤素、硫、磷等惦愌起催化剂中毒的元素,是制备用于煤化工行惄的负载型钌催化剂的理想前驱体。惣水合三氯化钌为原料,通过愌入恸硝酰基、除去氯离子、萃取提纯制备了固体恸硝酰硝酸钌,适于固体恸硝酰硝酸钌的规模化合成生产。
Ruthenium(III) nitrosyl nitrate is a relatively ideal precursor for preparing supported ruthenium catalysts used in coal chemical industry. The compound is free of harmful elements to the catalysts such as halogens, sulfur, phosphorus. A process involves introduction of nitrosyl, removal of chloride ions and extraction of the ruthenium nitrosyl product from the reaction system. The process is acceptable for large-scale production of solid ruthenium nitrosyl nitrate.
参考文献
[1] | 高冬梅,祝一锋.负载型钌催化剂在化工中的应用[J].浙江化工,2004(01):20-22,15. |
[2] | 吴松,熊晓东,王胜国.钌催化剂在有机合成中的应用[J].稀有金属,2007(02):237-244. |
[3] | 华金铭,郑起,林性贻,魏可镁.水煤气变换催化剂研究新进展[J].分子催化,2004(01):68-80. |
[4] | 柴海芳,韩文锋,朱虹,刘化章.氯对钌基氨合成催化剂的影响[J].化学进展,2006(10):1262-1269. |
[5] | 魏启慧,候淑彬.亚硝酰钌硝酸基络合物和亚硝酰钌亚硝酸基络合物的制备和鉴定[J].原子能科学技术,1978(02):152. |
[6] | 俞誉福;何阿弟;郑志坚 等.亚硝酰钌硝酸盐的光解速率研究[J].科学通报,1985,30(21):1630-1632. |
[7] | 寇拴虎,郑志坚,郑成法.硝酸介质中亚硝酰钌配合物的光分解反应动力学研究[J].核化学与放射化学,1997(02):1. |
[8] | 胡震山.亚硝酰钌的状态变化及其某些萃取行为[J].原子能科学技术,1981(05):605. |
[9] | Fletcher J M;Jenkins I L;Lever F M et al.Nitrato and nitro complexes of nitrosylruthenium[J].Journal Inor-ganic and Nuclear Chemistry,1995,57(1):378-401. |
[10] | Fletcher J M;Brown P G M;Gardner E R et al.Nitrosyl-ruthenium nitrate complexes in aqueous nitric acid[J].Journal Inorganic and Nuclear Chemistry,1959,23(12):154-173. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%