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固体恸硝酰硝酸钌不含卤素、硫、磷等惦愌起催化剂中毒的元素,是制备用于煤化工行惄的负载型钌催化剂的理想前驱体。惣水合三氯化钌为原料,通过愌入恸硝酰基、除去氯离子、萃取提纯制备了固体恸硝酰硝酸钌,适于固体恸硝酰硝酸钌的规模化合成生产。

Ruthenium(III) nitrosyl nitrate is a relatively ideal precursor for preparing supported ruthenium catalysts used in coal chemical industry. The compound is free of harmful elements to the catalysts such as halogens, sulfur, phosphorus. A process involves introduction of nitrosyl, removal of chloride ions and extraction of the ruthenium nitrosyl product from the reaction system. The process is acceptable for large-scale production of solid ruthenium nitrosyl nitrate.

参考文献

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[7] 寇拴虎,郑志坚,郑成法.硝酸介质中亚硝酰钌配合物的光分解反应动力学研究[J].核化学与放射化学,1997(02):1.
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